ALLYLIDENE DIACETATE
- Product Name
- ALLYLIDENE DIACETATE
- CAS No.
- 869-29-4
- Chemical Name
- ALLYLIDENE DIACETATE
- Synonyms
- SD-345;shell345;diacetoxy;Shell 345;shellsd345;Shell SD 345;SD 345 (Ester);Diacetoxypropene;allylideneacetate;crolein diacetate
- CBNumber
- CB7260131
- Molecular Formula
- C7H10O4
- Formula Weight
- 158.15
- MOL File
- 869-29-4.mol
ALLYLIDENE DIACETATE Property
- Melting point:
- -37.6°C
- Boiling point:
- 180°C (estimate)
- Density
- 1.0760
- refractive index
- 1.4193 (estimate)
- CAS DataBase Reference
- 869-29-4(CAS DataBase Reference)
- EPA Substance Registry System
- 2-Propene-1,1-diol diacetate (869-29-4)
Safety
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39
- RIDADR
- 2810
- HazardClass
- 6.1(a)
- PackingGroup
- II
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H300Fatal if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H331Toxic if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P311Call a POISON CENTER or doctor/physician.
P321Specific treatment (see … on this label).
P330Rinse mouth.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
P403+P233Store in a well-ventilated place. Keep container tightly closed.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- A544513
- Product name
- AllylideneDiacetate
- Packaging
- 2.5g
- Price
- $330
- Updated
- 2021/12/16
- Product number
- CHM0005591
- Product name
- 1,1-DIACETOXY-2-PROPENE
- Purity
- 95.00%
- Packaging
- 100G
- Price
- $3396.65
- Updated
- 2021/12/16
- Product number
- CHM0005591
- Product name
- 1,1-DIACETOXY-2-PROPENE
- Purity
- 95.00%
- Packaging
- 250G
- Price
- $6422.58
- Updated
- 2021/12/16
- Product number
- CHM0005591
- Product name
- 1,1-DIACETOXY-2-PROPENE
- Purity
- 95.00%
- Packaging
- 500G
- Price
- $8154.27
- Updated
- 2021/12/16
ALLYLIDENE DIACETATE Chemical Properties,Usage,Production
Uses
Allylidene Diacetate is a fungicide useful for the control of pea root rot and effective against Phytophthora palmivora. It may also be useful in the formation of vitamin C conjugate of acrolein.
Synthesis Reference(s)
The Journal of Organic Chemistry, 48, p. 1765, 1983 DOI: 10.1021/jo00158a036
Purification Methods
Check the NMR spectrum. If it is not satisfactory, then add Ac2O and a drop of conc H2SO4 and heat at 50o for 10minutes. Then add anhydrous NaOAc (ca 3g/ 100g of liquid) and fractionate. Note that it forms an azeotrope with H2O, so do not add H2O at any time. It is a highly flammable and TOXIC liquid; keep away from the skin. [Smith et al. J Am Chem Soc 73 5282 1951, Beilstein 2 H 154, 2 I 72, 2 III 356, 2 IV 291.]
ALLYLIDENE DIACETATE Preparation Products And Raw materials
Raw materials
Preparation Products
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