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1,3-dibroMo-2-fluorobenzene

Product Name
1,3-dibroMo-2-fluorobenzene
CAS No.
1435-54-7
Chemical Name
1,3-dibroMo-2-fluorobenzene
Synonyms
1,3-dibroMo-2-fluorobenzene;Benzene, 1,3-dibromo-2-fluoro-
CBNumber
CB72609389
Molecular Formula
C6H3Br2F
Formula Weight
253.89
MOL File
1435-54-7.mol
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1,3-dibroMo-2-fluorobenzene Property

Melting point:
53 °C(Solv: acetone (67-64-1))
Boiling point:
214.2±20.0 °C(Predicted)
Density 
2.014±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
Appearance
White to off-white Solid
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P321Specific treatment (see … on this label).

P330Rinse mouth.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
D426288
Product name
1,3-Dibromo-2-fluorobenzene
Packaging
500mg
Price
$110
Updated
2021/12/16
AK Scientific
Product number
7048AA
Product name
1,3-Dibromo-2-fluorobenzene
Packaging
1g
Price
$117
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD141488
Product name
1,3-Dibromo-2-fluorobenzene
Packaging
500mg
Price
$275
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD141488
Product name
1,3-Dibromo-2-fluorobenzene
Packaging
1g
Price
$481.25
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0361896
Product name
1,3-DIBROMO-2-FLUOROBENZENE
Purity
95.00%
Packaging
5MG
Price
$501.92
Updated
2021/12/16
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1,3-dibroMo-2-fluorobenzene Chemical Properties,Usage,Production

Synthesis

608-30-0

1435-54-7

Step 1: To a mixture of 2,6-dibromoaniline (5.0 g, 20 mmol) and concentrated hydrochloric acid (12 N, 10 mL) was slowly added sodium nitrite (NaNO2, 2.1 g, 30 mmol) at 0 °C. The reaction mixture was stirred at 0-10°C for 1 h, followed by dropwise addition of an aqueous solution of ammonium tetrafluoroborate (NH4BF4, 4.2 g, 40 mmol). Stirring was continued at 0-10°C for 1 hour. After completion of the reaction, the precipitate was collected by filtration and dried. The dried residue was heated to 220°C and maintained for 2 hours for thermal decomposition. After cooling to room temperature, the product was dissolved with ethyl acetate (EA, 150 mL) and subsequently washed with sodium hydroxide solution (2N, 200 mL). The organic layer was dried over anhydrous sodium sulfate (Na2SO4), filtered and concentrated under reduced pressure to give 1,3-dibromo-2-fluorobenzene (1.45 g, 29% yield).

References

[1] Patent: US2013/131016, 2013, A1. Location in patent: Paragraph 0352; 0353
[2] Acta Chimica Academiae Scientiarum Hungaricae, 1957, vol. 10, p. 227,229

1,3-dibroMo-2-fluorobenzene Preparation Products And Raw materials

Raw materials

Preparation Products

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1,3-dibroMo-2-fluorobenzene Suppliers

Carbosynth
Tel
--
Fax
--
Email
sales@carbosynth.com
Country
United Kingdom
ProdList
6005
Advantage
58
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View Lastest Price from 1,3-dibroMo-2-fluorobenzene manufacturers

Career Henan Chemical Co
Product
1,3-dibroMo-2-fluorobenzene 1435-54-7
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-01-02

1435-54-7, 1,3-dibroMo-2-fluorobenzeneRelated Search:


  • 1,3-dibroMo-2-fluorobenzene
  • Benzene, 1,3-dibromo-2-fluoro-
  • 1435-54-7