ChemicalBook > CAS DataBase List > 2-(CHLOROMETHYL)-1,3-BENZOXAZOLE

2-(CHLOROMETHYL)-1,3-BENZOXAZOLE

Product Name
2-(CHLOROMETHYL)-1,3-BENZOXAZOLE
CAS No.
41014-43-1
Chemical Name
2-(CHLOROMETHYL)-1,3-BENZOXAZOLE
Synonyms
BUTTPARK 77\06-47;2-CHLOROMETHYLBENZOXAZOLE;2-Chloromethyl-benzooxazole;Benzoxazole, 2-(chloroMethyl)-;2-(chlormethyl)-1,3-benzoxazole;2-(CHLOROMETHYL)BENZO[D]OXAZOLE;2-(CHLOROMETHYL)-1,3-BENZOXAZOLE
CBNumber
CB7261178
Molecular Formula
C8H6ClNO
Formula Weight
167.59
MOL File
41014-43-1.mol
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2-(CHLOROMETHYL)-1,3-BENZOXAZOLE Property

Boiling point:
75/0.15mm
Density 
1.316±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
0.95±0.10(Predicted)
form 
liquid
color 
Clear, very pale yellow
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Safety

Hazard Codes 
Xi
Risk Statements 
43
Safety Statements 
36/37
HazardClass 
IRRITANT
HS Code 
2934999090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
C587913
Product name
2-(Chloromethyl)-1,3-benzoxazole
Packaging
50mg
Price
$45
Updated
2021/12/16
Biosynth Carbosynth
Product number
FC134035
Product name
2-(Chloromethyl)-1,3-benzoxazole
Packaging
100mg
Price
$70
Updated
2021/12/16
Matrix Scientific
Product number
043377
Product name
2-(Chloromethyl)-1,3-benzoxazole
Purity
95+%
Packaging
1g
Price
$75
Updated
2021/12/16
Apolloscientific
Product number
OR103007
Product name
2-(Chloromethyl)-1,3-benzoxazole
Packaging
1g
Price
$79
Updated
2021/12/16
SynQuest Laboratories
Product number
4H56-5-L5
Product name
2-(Chloromethyl)-1,3-benzoxazole
Packaging
1g
Price
$87
Updated
2021/12/16
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2-(CHLOROMETHYL)-1,3-BENZOXAZOLE Chemical Properties,Usage,Production

Synthesis

36743-66-5

95-55-6

41014-43-1

B. To a stirred suspension of o-aminophenol (365 mg, 3.35 mmol) in dichloromethane (7 mL) was added ethyl 2-chloroacetimidate hydrochloride (798 mg, 5.05 mmol) in one batch at 0 °C. After 1 hour and 25 minutes of reaction, the mixture was raised from 0°C to ambient temperature and stirring was continued overnight. After completion of the reaction, the mixture was filtered through diatomaceous earth and the filtrate was concentrated. The residue was purified by column chromatography (eluent: hexane/ethyl acetate, 7/3) to afford 2-chloromethyl-1,3-benzoxazole as a light-colored oil (533 mg, 95% yield).

References

[1] European Journal of Medicinal Chemistry, 2011, vol. 46, # 5, p. 1706 - 1712
[2] Patent: WO2008/110793, 2008, A1. Location in patent: Page/Page column 103-104
[3] Molecules, 2018, vol. 23, # 10,
[4] Journal of Medicinal Chemistry, 2012, vol. 55, # 7, p. 3066 - 3075
[5] Synthesis, 1979, p. 102 - 103

2-(CHLOROMETHYL)-1,3-BENZOXAZOLE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-(CHLOROMETHYL)-1,3-BENZOXAZOLE Suppliers

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View Lastest Price from 2-(CHLOROMETHYL)-1,3-BENZOXAZOLE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
2-(chlormethyl)-1,3-benzoxazole 41014-43-1
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10
Zhuozhou Wenxi import and Export Co., Ltd
Product
2-(chlormethyl)-1,3-benzoxazole 41014-43-1
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-09
Career Henan Chemical Co
Product
2-(CHLOROMETHYL)-1,3-BENZOXAZOLE 41014-43-1
Price
US $3.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
200KG
Release date
2020-01-12