TRANS-3-(TRIMETHYLSILYL)ALLYL ALCOHOL
- Product Name
- TRANS-3-(TRIMETHYLSILYL)ALLYL ALCOHOL
- CAS No.
- 59376-64-6
- Chemical Name
- TRANS-3-(TRIMETHYLSILYL)ALLYL ALCOHOL
- Synonyms
- trans-(3-Hydro;-3-(Trimethylsilyl);methylsilylprop-2-enol;(E)-3-(Trimethylsilyl)prop-2-en-1-ol;(E)-3-(Trimethylsilyl)-2-propen-1-ol;TRANS-3-(TRIMETHYLSILYL)ALLYL ALCOHOL;(2E)-3-(TRIMETHYLSILYL)-2-PROPEN-1-OL;TRANS-3-(TRIMETHYLSILYL)-2-PROPEN-1-OL;2-Propen-1-ol,3-(trimethylsilyl)-, (2E)-;TRANS-3-(TRIMETHYLSILYL)ALLYL ALCOHOL, 9 7%
- CBNumber
- CB7265484
- Molecular Formula
- C6H14OSi
- Formula Weight
- 130.26
- MOL File
- 59376-64-6.mol
TRANS-3-(TRIMETHYLSILYL)ALLYL ALCOHOL Property
- Boiling point:
- 166-168 °C(lit.)
- Density
- 0.848 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.444(lit.)
- Flash point:
- 146 °F
- storage temp.
- -20°C
- pka
- 14.67±0.10(Predicted)
- form
- liquid
- BRN
- 1902497
- InChI
- InChI=1S/C6H14OSi/c1-8(2,3)6-4-5-7/h4,6-7H,5H2,1-3H3/b6-4+
- InChIKey
- BRTBTJVSPJZQIT-GQCTYLIASA-N
- SMILES
- C(O)/C=C/[Si](C)(C)C
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H226Flammable liquid and vapour
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 376310
- Product name
- trans-3-(Trimethylsilyl)allyl alcohol
- Purity
- 96%
- Packaging
- 1g
- Price
- $180.96
- Updated
- 2025/07/31
- Product number
- T705118
- Product name
- trans-3-(Trimethylsilyl)allyl alcohol
- Packaging
- 500mg
- Price
- $130
- Updated
- 2021/12/16
- Product number
- X7191
- Product name
- trans-3-(Trimethylsilyl)allyl alcohol
- Packaging
- 1g
- Price
- $271
- Updated
- 2021/12/16
- Product number
- CM138004
- Product name
- trans-3-(Trimethylsilyl)allyl alcohol
- Purity
- 95%
- Packaging
- 5g
- Price
- $196
- Updated
- 2021/12/16
- Product number
- CM138004
- Product name
- trans-3-(Trimethylsilyl)allyl alcohol
- Purity
- 95%
- Packaging
- 10g
- Price
- $314
- Updated
- 2021/12/16
TRANS-3-(TRIMETHYLSILYL)ALLYL ALCOHOL Chemical Properties,Usage,Production
Uses
trans-3-(Trimethylsilyl)allyl alcohol is suitable for use in the preparation of 1-iodo-3-trimethylsilyl-2-propene, via mesylation followed by iodide displacement.
General Description
trans-3-(Trimethylsilyl)allyl alcohol is a 3-silyl allyl alcohol.
Synthesis
5272-36-6
59376-64-6
General procedure for the synthesis of trans-3-(trimethylsilyl)allylpropanol from trimethylsilylpropargyl alcohol: The alcohol prepared in Example 40 (1.54 g, 12 mmol, 1 eq.) was dissolved in anhydrous THF (12 mL) under argon protection and slowly added dropwise to a suspension of LiAlH4 (0.7 g, 18 mmol, 1.5 eq.) in THF (15 mL) , stirred at room temperature. Subsequently, the reaction mixture was heated to reflux for 4 hours. Upon completion of the reaction, the reaction was quenched with saturated aqueous NaHCO3 and aqueous NH4Cl. The reaction mixture was extracted with Et2O (3 × 50 mL) and the organic layers were combined, washed with brine and dried over MgSO4. The solvent was removed by concentration under reduced pressure to give the target product (1.39 g, 10.6 mmol, 89% yield) as a colorless liquid. The structure of the product was determined by 1H NMR (400 MHz, CDCl3) δ 6.19 (1H, m, H-3), 5.93 (1H, dt, J2-3 = 18.8 Hz, J2-4 = 1.45 Hz, H-2), 4.18 (2H, dd, J4-3 = 2.72, J4-2 = 1.45, H-4), 1.56 (1H, s, H-5) , 0.09 (9H, s, H-1); 13C NMR (100 MHz, CDCl3) δ 144.8 (C-3), 129.5 (C-2), 65.5 (C-4), -1.37 (C-5); confirmed by IR (pure, cm-1) 3331 (b, OH), 1622 (s, C=C).
References
[1] Journal of Organic Chemistry, 1988, vol. 53, # 20, p. 4682 - 4693
[2] Journal of the American Chemical Society, 1989, vol. 111, # 24, p. 8834 - 8841
[3] Tetrahedron, 1996, vol. 52, # 21, p. 7487 - 7510
[4] Chinese Journal of Chemistry, 2018, vol. 36, # 10, p. 916 - 920
[5] Patent: US2007/142632, 2007, A1. Location in patent: Page/Page column 26
TRANS-3-(TRIMETHYLSILYL)ALLYL ALCOHOL Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from TRANS-3-(TRIMETHYLSILYL)ALLYL ALCOHOL manufacturers
- Product
- TRANS-3-(TRIMETHYLSILYL)ALLYL ALCOHOL 59376-64-6
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-09-16
- Product
- TRANS-3-(TRIMETHYLSILYL)ALLYL ALCOHOL 59376-64-6
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98% HPLC
- Supply Ability
- 10 tons/month
- Release date
- 2020-01-08