ChemicalBook > CAS DataBase List > 4,4-di(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b]dithiophene

4,4-di(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b]dithiophene

Product Name
4,4-di(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b]dithiophene
CAS No.
365547-20-2
Chemical Name
4,4-di(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b]dithiophene
Synonyms
DTC26;S1372;4,4-Di-2-ethylhexyl;4,4-di(2-ethylhexyl)-4H-cyclopenta[2,1-b;4,4-bis (2-ethylhexyl) - dithiophene-cyclopentadiene);4,4-Di-2-ethylhexyl-cyclopenta[2,1-b:3,4-b']dithiophene;4,4-di(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b]dithiophene;4,4-Bis(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b']dithiophene;4,4-Bis(2-ethylhexyl)-4H-cyclopenta[1,2-b:5,4-b']dithiophene;4H-Cyclopenta[2,1-b:3,4-b']dithiophene, 4,4-bis(2-ethylhexyl)-
CBNumber
CB72660076
Molecular Formula
C25H38S2
Formula Weight
402.7
MOL File
365547-20-2.mol
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4,4-di(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b]dithiophene Property

Boiling point:
490.0±25.0 °C(Predicted)
Density 
1.007±0.06 g/cm3(Predicted)
refractive index 
1.5430 to 1.5470
Flash point:
189.00°C
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
clear liquid
color 
Colorless to Red to Green
InChI
InChI=1S/C25H38S2/c1-5-9-11-19(7-3)17-25(18-20(8-4)12-10-6-2)21-13-15-26-23(21)24-22(25)14-16-27-24/h13-16,19-20H,5-12,17-18H2,1-4H3
InChIKey
NUCIQEWGTLOQTR-UHFFFAOYSA-N
SMILES
C12C3SC=CC=3C(CC(CC)CCCC)(CC(CC)CCCC)C=1C=CS2
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Safety

HS Code 
2934.99.4400
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
B4102
Product name
4,4-Bis(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b']dithiophene
Purity
>98.0%(GC)
Packaging
1g
Price
$491
Updated
2025/07/31
TCI Chemical
Product number
B4102
Product name
4,4-Bis(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b']dithiophene
Purity
>98.0%(GC)
Packaging
5g
Price
$1706
Updated
2025/07/31
Crysdot
Product number
CD11134907
Product name
4,4-Bis(2-ethylhexyl)-4H-cyclopenta[1,2-b:5,4-b']dithiophene
Purity
95+%
Packaging
25g
Price
$2030
Updated
2021/12/16
Alichem
Product number
365547202
Product name
4,4-Bis(2-ethylhexyl)-4H-cyclopenta[1,2-b:5,4-b']dithiophene
Packaging
25g
Price
$2050
Updated
2021/12/16
Crysdot
Product number
CD11134907
Product name
4,4-Bis(2-ethylhexyl)-4H-cyclopenta[1,2-b:5,4-b']dithiophene
Purity
95+%
Packaging
5g
Price
$594
Updated
2021/12/16
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4,4-di(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b]dithiophene Chemical Properties,Usage,Production

Synthesis

18908-66-2

389-58-2

365547-20-2

Example 5 Synthesis of 4,4-bis-(2-ethylhexyl)-4H-cyclopenta[2,1-b;3,4-b']dithiophene: Cyclopentylbithiophene (1.5 g, 0.00843 mol) was dissolved in DMSO (50 mL). KOH (1.89 g, 0.0337 mol), sodium iodide (50 mg) and 2-ethylhexyl bromide (3.25 g, 0.0169 mol) were sequentially added to the solution under nitrogen protection. The reaction mixture was stirred under nitrogen atmosphere for 16 hours. After completion of the reaction, water was added and the reaction mixture was extracted with tert-butyl methyl ether. The organic layer was separated, dried with magnesium sulfate and concentrated. The residue was purified by column chromatography using hexane as eluent. The grades containing pure 4,4-bis-(2-ethylhexyl)-4H-cyclopenta[2,1-b;3,4-b']dithiophene were combined and concentrated. After vacuum drying, a colorless oily product was obtained in a yield of 2.68 g (79%).1H NMR (CDCl3, 250 MHz): δ 7.13 (m, 2H), 6.94 (m, 2H), 1.88 (m, 4H), 0.94 (m, 16H), 0.78 (t, J=6.4 Hz, 6H), 0.61 (t, J=7.3 Hz, 6H).

References

[1] Journal of Polymer Science, Part A: Polymer Chemistry, 2012, vol. 50, # 8, p. 1622 - 1635
[2] RSC Advances, 2014, vol. 4, # 71, p. 37738 - 37745
[3] RSC Advances, 2014, vol. 40, # 71, p. 37738 - 37745
[4] Macromolecules, 2010, vol. 43, # 2, p. 697 - 708
[5] Patent: US7772485, 2010, B2. Location in patent: Page/Page column 11-12

4,4-di(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b]dithiophene Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 4,4-di(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b]dithiophene manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
4,4-di(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b]dithiophene 365547-20-2
Price
US $3.00-9.00/kg
Min. Order
1kg
Purity
99%min
Supply Ability
50kg
Release date
2025-07-29
Career Henan Chemical Co
Product
4,4-di(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b]dithiophene 365547-20-2
Price
US $1.00/KG
Min. Order
1KG
Purity
98% HPLC
Supply Ability
10 tons/month
Release date
2020-01-09

365547-20-2, 4,4-di(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b]dithiopheneRelated Search:


  • 4,4-Bis(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b']dithiophene
  • 4,4-Di-2-ethylhexyl-cyclopenta[2,1-b:3,4-b']dithiophene
  • 4,4-di(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b]dithiophene
  • 4,4-Bis(2-ethylhexyl)-4<i>H</i>-cyclopenta[2,1-<i>b</i>:3,4-<i>b</i>']dithiophene
  • DTC26
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  • 4,4-Di-2-ethylhexyl
  • 4,4-Bis(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b']dithiophene &gt
  • 4H-Cyclopenta[2,1-b:3,4-b']dithiophene, 4,4-bis(2-ethylhexyl)-
  • S1372
  • 4,4-bis (2-ethylhexyl) - dithiophene-cyclopentadiene)
  • 4,4-Bis(2-ethylhexyl)-4H-cyclopenta[1,2-b:5,4-b']dithiophene
  • 365547-20-2
  • C25H38S2