4,4-di(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b]dithiophene
- Product Name
- 4,4-di(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b]dithiophene
- CAS No.
- 365547-20-2
- Chemical Name
- 4,4-di(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b]dithiophene
- Synonyms
- DTC26;S1372;4,4-Di-2-ethylhexyl;4,4-di(2-ethylhexyl)-4H-cyclopenta[2,1-b;4,4-bis (2-ethylhexyl) - dithiophene-cyclopentadiene);4,4-Di-2-ethylhexyl-cyclopenta[2,1-b:3,4-b']dithiophene;4,4-di(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b]dithiophene;4,4-Bis(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b']dithiophene;4,4-Bis(2-ethylhexyl)-4H-cyclopenta[1,2-b:5,4-b']dithiophene;4H-Cyclopenta[2,1-b:3,4-b']dithiophene, 4,4-bis(2-ethylhexyl)-
- CBNumber
- CB72660076
- Molecular Formula
- C25H38S2
- Formula Weight
- 402.7
- MOL File
- 365547-20-2.mol
4,4-di(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b]dithiophene Property
- Boiling point:
- 490.0±25.0 °C(Predicted)
- Density
- 1.007±0.06 g/cm3(Predicted)
- refractive index
- 1.5430 to 1.5470
- Flash point:
- 189.00°C
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- clear liquid
- color
- Colorless to Red to Green
- InChI
- InChI=1S/C25H38S2/c1-5-9-11-19(7-3)17-25(18-20(8-4)12-10-6-2)21-13-15-26-23(21)24-22(25)14-16-27-24/h13-16,19-20H,5-12,17-18H2,1-4H3
- InChIKey
- NUCIQEWGTLOQTR-UHFFFAOYSA-N
- SMILES
- C12C3SC=CC=3C(CC(CC)CCCC)(CC(CC)CCCC)C=1C=CS2
Safety
- HS Code
- 2934.99.4400
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- B4102
- Product name
- 4,4-Bis(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b']dithiophene
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $491
- Updated
- 2025/07/31
- Product number
- B4102
- Product name
- 4,4-Bis(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b']dithiophene
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $1706
- Updated
- 2025/07/31
- Product number
- CD11134907
- Product name
- 4,4-Bis(2-ethylhexyl)-4H-cyclopenta[1,2-b:5,4-b']dithiophene
- Purity
- 95+%
- Packaging
- 25g
- Price
- $2030
- Updated
- 2021/12/16
- Product number
- 365547202
- Product name
- 4,4-Bis(2-ethylhexyl)-4H-cyclopenta[1,2-b:5,4-b']dithiophene
- Packaging
- 25g
- Price
- $2050
- Updated
- 2021/12/16
- Product number
- CD11134907
- Product name
- 4,4-Bis(2-ethylhexyl)-4H-cyclopenta[1,2-b:5,4-b']dithiophene
- Purity
- 95+%
- Packaging
- 5g
- Price
- $594
- Updated
- 2021/12/16
4,4-di(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b]dithiophene Chemical Properties,Usage,Production
Synthesis
18908-66-2
389-58-2
365547-20-2
Example 5 Synthesis of 4,4-bis-(2-ethylhexyl)-4H-cyclopenta[2,1-b;3,4-b']dithiophene: Cyclopentylbithiophene (1.5 g, 0.00843 mol) was dissolved in DMSO (50 mL). KOH (1.89 g, 0.0337 mol), sodium iodide (50 mg) and 2-ethylhexyl bromide (3.25 g, 0.0169 mol) were sequentially added to the solution under nitrogen protection. The reaction mixture was stirred under nitrogen atmosphere for 16 hours. After completion of the reaction, water was added and the reaction mixture was extracted with tert-butyl methyl ether. The organic layer was separated, dried with magnesium sulfate and concentrated. The residue was purified by column chromatography using hexane as eluent. The grades containing pure 4,4-bis-(2-ethylhexyl)-4H-cyclopenta[2,1-b;3,4-b']dithiophene were combined and concentrated. After vacuum drying, a colorless oily product was obtained in a yield of 2.68 g (79%).1H NMR (CDCl3, 250 MHz): δ 7.13 (m, 2H), 6.94 (m, 2H), 1.88 (m, 4H), 0.94 (m, 16H), 0.78 (t, J=6.4 Hz, 6H), 0.61 (t, J=7.3 Hz, 6H).
References
[1] Journal of Polymer Science, Part A: Polymer Chemistry, 2012, vol. 50, # 8, p. 1622 - 1635
[2] RSC Advances, 2014, vol. 4, # 71, p. 37738 - 37745
[3] RSC Advances, 2014, vol. 40, # 71, p. 37738 - 37745
[4] Macromolecules, 2010, vol. 43, # 2, p. 697 - 708
[5] Patent: US7772485, 2010, B2. Location in patent: Page/Page column 11-12
4,4-di(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b]dithiophene Preparation Products And Raw materials
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View Lastest Price from 4,4-di(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b]dithiophene manufacturers
- Product
- 4,4-di(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b]dithiophene 365547-20-2
- Price
- US $3.00-9.00/kg
- Min. Order
- 1kg
- Purity
- 99%min
- Supply Ability
- 50kg
- Release date
- 2025-07-29
- Product
- 4,4-di(2-ethylhexyl)-4H-cyclopenta[2,1-b:3,4-b]dithiophene 365547-20-2
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98% HPLC
- Supply Ability
- 10 tons/month
- Release date
- 2020-01-09