ChemicalBook > CAS DataBase List > 5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole

5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole

Product Name
5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole
CAS No.
1239478-87-5
Chemical Name
5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole
Synonyms
AdBippyphos;Ad-BGPhos;Adamantyl-BippyPhos;5-[Di(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1′H-[1,4′]bipyrazole;5-[Bis(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1,4′-bi-1H-pyrazole;5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole;5-[Di(1-adamantyl)phosphino]-1',3',5'-triphenyl-1'H-[1,4']bipyrazole 97%;5-[Di(1-adamantyl)phosphino](1,3,5-triphenyl-1H-pyrazol-4-yl)-1H-pyrazole;5-[bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphino]- 1',3',5'-triphenyl-1,4'-Bi-1H-pyrazole;1,4'-Bi-1H-pyrazole, 5-[bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphino]-1',3',5'-triphenyl-
CBNumber
CB72720831
Molecular Formula
C44H47N4P
Formula Weight
662.84
MOL File
1239478-87-5.mol
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5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole Property

Melting point:
295-300°C
storage temp. 
2-8°C
form 
solid
pka
-0.58±0.19(Predicted)
color 
white to light yellow
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-37
WGK Germany 
3
TSCA 
No
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Hazard and Precautionary Statements (GHS)

Signal word
Warning
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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
740845
Product name
5-[Di(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1′H-[1,4′]bipyrazole
Purity
97%
Packaging
1g
Price
$400
Updated
2024/03/01
Sigma-Aldrich
Product number
740845
Product name
5-[Di(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1′H-[1,4′]bipyrazole
Purity
97%
Packaging
5g
Price
$1360
Updated
2024/03/01
Sigma-Aldrich
Product number
740845
Product name
5-[Di(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1′H-[1,4′]bipyrazole
Purity
97%
Packaging
250mg
Price
$153
Updated
2024/03/01
TRC
Product number
D495213
Product name
5-[Di(1-adamantyl)phosphino](1,3,5-triphenyl-1H-pyrazol-4-yl)-1H-pyrazole
Packaging
2.5mg
Price
$45
Updated
2021/12/16
ChemSupplyAustralia
Product number
300040
Product name
5-[Di(1-adamantyl)phosphino](1,3,5-triphenyl-1H-pyrazol-4-yl)-1H-pyrazole, 97%
Packaging
250mg
Price
$77
Updated
2021/12/16
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5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole Chemical Properties,Usage,Production

Uses

5-[Di(1-adamantyl)phosphino](1,3,5-triphenyl-1H-pyrazol-4-yl)-1H-pyrazole can be used as a catalyst.

Uses

5-[Di(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1′H-[1,4′]bipyrazole (Ad-BippyPhos) is an effective ligand that catalyzes C-O coupling reactions of aryl and heteroaryl bromides/chlorides with primary aliphatic alcohols. It can also be used as a catalyst in the synthesis of fluorinated anilines by coupling fluoroalkylamines with aryl bromides and chlorides.

reaction suitability

reagent type: ligand

5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole Preparation Products And Raw materials

Raw materials

Preparation Products

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5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole Suppliers

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1239478-87-5, 5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazoleRelated Search:


  • 5-[Di(1-adaMantyl)phosphino](1,3,5-triphenyl-1H-pyrazol-4-yl)-1H-pyrazole, 97+% (AdaMantyl-BippyPhos)
  • 5-[Bis(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1,4′-bi-1H-pyrazole
  • 5-[Di(1-adamantyl)phosphino]-1′,3′,5′-triphenyl-1′H-[1,4′]bipyrazole
  • Adamantyl-BippyPhos
  • Ad-BGPhos
  • 5-[Di(1-adamantyl)phosphino]-1',3',5'-triphenyl-1'H-[1,4']bipyrazole 97%
  • 5-[Di(1-adamantyl)phosphino](1,3,5-triphenyl-1H-pyrazol-4-yl)-1H-pyrazole, (Adamantyl-BippyPhos)
  • 5-[bis(tricyclo[3.3.1.13,7]dec-1-yl)phosphino]- 1',3',5'-triphenyl-1,4'-Bi-1H-pyrazole
  • AdBippyphos
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  • 5-(Di(adamantan-1-yl)phosphino)-1',3',5'-triphenyl-1'H-1,4'-bipyrazole[Adamantyl-BippyPhos
  • 1239478-87-5
  • C44H47N4P