4-(tert-ButyldiMethylsilyloxy)butanal

Synthesis

Product Name: 4-(tert-ButyldiMethylsilyloxy)butanal
CAS No.: 87184-81-4
Chemical Name: 4-(tert-ButyldiMethylsilyloxy)butanal
Synonyms: DKSI081;MDS-09-02;DKFELEX0263;4-(tert-ButyldiMethylsilyloxy)butanal;4-(tert-Butyldimethylsilyloxy)butyraldehyde;4-(tert-Butyldimethylsilyloxy)butanal - [B3803];4-[[(1,1-Dimethylethyl)dimethylsilyl]oxy]butanal;Butanal, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-;4-(tert-butyldimethylsiliconalkaneoxy)nbutylaldehyde
CBNumber: CB72721575
Molecular Formula: C10H22O2Si
Formula Weight: 202.37
MOL File: 87184-81-4.mol

More

Less

4-(tert-ButyldiMethylsilyloxy)butanal Property

Boiling point:: 225.3±23.0 °C(Predicted)
Density: 0.868±0.06 g/cm3(Predicted)
storage temp.: -20°C, stored under nitrogen
Appearance: Colorless to light yellow Liquid

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H227Combustible liquid

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

More

Less

N-Bromosuccinimide Price

TRC

Product number: T205913
Product name: 4-(tert-Butyldimethylsilyloxy)butanal
Packaging: 10mg
Price: $45
Updated: 2021/12/16

Synthonix

Product number: B3803
Product name: 4-(tert-Butyldimethylsilyloxy)butanal
Purity: 95%+
Packaging: 500mg
Price: $150
Updated: 2021/12/16

Synthonix

Product number: B3803
Product name: 4-(tert-Butyldimethylsilyloxy)butanal
Purity: 95%+
Packaging: 1g
Price: $275
Updated: 2021/12/16

Matrix Scientific

Product number: 115667
Product name: 4-(tert-Butyldimethylsilyloxy)butanal
Purity: 95+%
Packaging: 500mg
Price: $607
Updated: 2021/12/16

Matrix Scientific

Product number: 115667
Product name: 4-(tert-Butyldimethylsilyloxy)butanal
Purity: 95+%
Packaging: 1g
Price: $773
Updated: 2021/12/16

More

Less

4-(tert-ButyldiMethylsilyloxy)butanal Chemical Properties,Usage,Production

Synthesis

To a solution of oxalyl chloride (2.1 mL, 24 mmol, 1.2 equivalents) in CH2Cl2 (30 mL) cooled at −78 °C was added dropwise a solution of dimethylsulfoxide (DMSO 3.3 mL, 21 mmol, 1.1 equivalents) in CH2Cl2 (32 mL). After 5 min, a solution of 4-(tert-butyldimethylsilanyloxy)butan-1-ol (4.0 g, 20 mmol, 1.0 equivalents) in CH2Cl2 (26 mL) was added. The reaction mixture was then stirred for 15 min at −78 °C and triethylamine (14.0 mL, 100 mmol, 5.00 equivalents) was added in 1 portion. After 10 min at −78 °C, the mixture was allowed to warm to room temperature and diluted with CH2Cl2 (140 mL). The organic layer was successively washed with a saturated aqueous solution of NH4Cl (30 mL) and brine (2 × 30 mL). The combined organic extracts were dried over MgSO4, fifiltered, and concentrated under reduced pressure. Purifification by flflash chromatography on silica gel (petroleum ether/EtOAc: 90/10) afforded 3.88 g (96% yield) of the aldehyde as a colorless oil.

Reference: Taillier, C.; Gille, B.; Bellosta, V.; Cossy, J. J. Org. Chem. 2005, 70, 2097−2108.

4-(tert-ButyldiMethylsilyloxy)butanal Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

4-(tert-ButyldiMethylsilyloxy)butanal Suppliers

China 41 United States 6 Global 47

Beijing Ouhe Technology Co., Ltd

Tel: 13552068683 13522913783
Fax: +86-10-82967029
Email: 2355560935@qq.com
Country: China
ProdList: 11780
Advantage: 60

Bide Pharmatech Ltd.

Tel: 400-400-164-7117 18317119277
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 39999
Advantage: 60

Chongqing Acemol Technology Co.,Ltd

Tel: 023-86822659 18611316925
Email: sales@acemol.com
Country: China
ProdList: 995
Advantage: 55

Haimen Ruiyi Medical Tech Co., LTD

Tel: 021-54718086
Fax: 021-54711707
Email: sales5@ruiyitech.com
Country: China
ProdList: 271
Advantage: 58

Aikon International Limited

Tel: 025-58859352 19370895928
Fax: 02557626880
Email: sales01@aikonchem.com
Country: China
ProdList: 15082
Advantage: 58

Shanghai Haohong Pharmaceutical Co., Ltd.

Tel: 400-8210725 400821072
Fax: 021-58955996
Email: malulu@leyan.com
Country: China
ProdList: 24972
Advantage: 58

Fuyang Ziyi Biological Pharmaceutical Co., Ltd.

Tel: 19308655899; 19308655899
Fax: -
Email: 2677609105@qq.com
Country: China
ProdList: 500
Advantage: 58

Cool Pharm, Ltd

Tel: 021-58581007 18019463053
Fax: 021-50966098
Email: sales@coolpharm.com
Country: China
ProdList: 10000
Advantage: 58

Beijing Minruida Technology Co., Ltd.

Tel: 010-82387566 18001021521;
Fax: 82387566-801
Email: sales@mreda.com.cn
Country: China
ProdList: 10083
Advantage: 58

Shanghai Hongle Biotechnology Co., Ltd

Tel: 021-56145923; 4001631568
Email: sales@honglebiotech.com
Country: China
ProdList: 929
Advantage: 58

87184-81-4, 4-(tert-ButyldiMethylsilyloxy)butanalRelated Search:

4-(tert-ButyldiMethylsilyloxy)butanal

Butanal, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-

4-[[(1,1-Dimethylethyl)dimethylsilyl]oxy]butanal

DKFELEX0263

DKSI081

MDS-09-02

4-(tert-Butyldimethylsilyloxy)butyraldehyde

4-(tert-Butyldimethylsilyloxy)butanal - [B3803]

4-(tert-butyldimethylsiliconalkaneoxy)nbutylaldehyde

87184-81-4