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ChemicalBook > CAS DataBase List > 2-AMINO-4-BROMOBENZALDEHYDE

2-AMINO-4-BROMOBENZALDEHYDE

Application
Product Name
2-AMINO-4-BROMOBENZALDEHYDE
CAS No.
59278-65-8
Chemical Name
2-AMINO-4-BROMOBENZALDEHYDE
Synonyms
Ambroxol Impurity 60;2-Amino-4-bromobenzaL;4-BroMo-2-aMinobenzaldehyde;2-AMINO-4-BROMOBENZALDEHYDE;Benzaldehyde, 2-amino-4-bromo-;2-AMINO-4-BROMOBENZALDEHYDE ISO 9001：2015 REACH
CBNumber
CB7294688
Molecular Formula
C7H6BrNO
Formula Weight
200.03
MOL File
59278-65-8.mol
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2-AMINO-4-BROMOBENZALDEHYDE Property

Melting point:
85 °C
Boiling point:
317.1±32.0 °C(Predicted)
Density 
1.672±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
pka
-0.72±0.10(Predicted)
Appearance
Off-white to yellow Solid
InChI
InChI=1S/C7H6BrNO/c8-6-2-1-5(4-10)7(9)3-6/h1-4H,9H2
InChIKey
ZZVUOSVSPAPBEJ-UHFFFAOYSA-N
SMILES
C(=O)C1=CC=C(Br)C=C1N
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Safety

HS Code 
2922390090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
A594835
Product name
2-Amino-4-bromobenzaldehyde
Packaging
100mg
Price
$75
Updated
2021/12/16
AK Scientific
Product number
W7224
Product name
2-Amino-4-bromobenzaldehyde
Packaging
1g
Price
$107
Updated
2021/12/16
Apolloscientific
Product number
OR51844
Product name
2-Amino-4-bromobenzaldehyde
Packaging
1g
Price
$140
Updated
2021/12/16
Biosynth Carbosynth
Product number
FA139324
Product name
2-Amino-4-bromobenzaldehyde
Packaging
1g
Price
$150
Updated
2021/12/16
SynQuest Laboratories
Product number
4656-9-44
Product name
2-Amino-4-bromobenzaldehyde
Packaging
1g
Price
$154
Updated
2021/12/16
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2-AMINO-4-BROMOBENZALDEHYDE Chemical Properties,Usage,Production

Application

2-Amino-4-bromobenzaldehyde is an organic synthesis intermediate and a pharmaceutical intermediate that can be used in laboratory research and development processes as well as in chemical and pharmaceutical synthesis.

Synthesis

5551-12-2

59278-65-8

Step 3. Synthesis of 2-amino-4-bromobenzaldehyde: Iron powder was added to 0.2 M of 4-bromo-2-nitrobenzaldehyde in a mixed solvent system of acetic acid and ethanol (v/v 1:1) under argon protection. The reaction mixture was stirred at room temperature for 1.5 h. The completion of the reaction was confirmed by LCMS monitoring. The insoluble solids were removed by filtration and the filtrate was concentrated under vacuum. The residue was diluted with ethyl acetate, washed sequentially with saturated sodium bicarbonate solution and brine, and the organic phase was dried over anhydrous sodium sulfate and concentrated. The crude product was purified by Biotage system using hexane solution of 15% ethyl acetate as eluent to afford the target compound 2-amino-4-bromobenzaldehyde in 38% yield.ES/MS m/z 200/202 (MH+).

References

[1] Tetrahedron Letters, 2016, vol. 57, # 45, p. 5003 - 5008
[2] Patent: WO2016/86200, 2016, A1. Location in patent: Page/Page column 219
[3] Patent: WO2007/117607, 2007, A2. Location in patent: Page/Page column 333-334
[4] Chemische Berichte, 1909, vol. 42, p. 3697
[5] Bioorganic and Medicinal Chemistry, 2006, vol. 14, # 7, p. 2462 - 2467

2-AMINO-4-BROMOBENZALDEHYDE Preparation Products And Raw materials

Raw materials

Preparation Products

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2-AMINO-4-BROMOBENZALDEHYDE Suppliers

China 126 India 3 United Kingdom 4 United States 13 Global 146
A.J Chemicals
Tel
--
Fax
--
Email
sales@ajchem.in
Country
India
ProdList
6100
Advantage
58
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View Lastest Price from 2-AMINO-4-BROMOBENZALDEHYDE manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
2-AMINO-4-BROMOBENZALDEHYDE 59278-65-8
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-26
Career Henan Chemical Co
Product
2-AMINO-4-BROMOBENZALDEHYDE 59278-65-8
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
100KG
Release date
2019-12-30

59278-65-8, 2-AMINO-4-BROMOBENZALDEHYDERelated Search:

Halofuginone Lactate Halofuginone 4-Bromo-2-nitrobenzoic acid 6-Bromoisatin 2-AMINO-4,5-DIBROMOBENZOIC ACID Halofuginone hydrobromide 7-BROMO-1H-QUINAZOLIN-4-ONE 4-Bromo-2-nitrobenzaldehyde 2-Amino-4'-bromobenzophenone 2-Amino-4-bromobenzoic acid 2-Amino-5-bromobenzaldehyde 4-Bromobenzaldehyde 4-BROMO-2-(N-MORPHOLINO)-BENZALDEHYDE 1-(2-AMINO-4-BROMO-PHENYL)-PROPAN-1-ONE 4-BROMO-2,6-DINITROBENZOIC ACID 6-BROMO-5-METHYLISATIN N-BOC-2-AMINO-5-BROMOBENZALDEHYDE ALIZARIN FAST BLUE 2B

  • 2-AMINO-4-BROMOBENZALDEHYDE
  • 4-BroMo-2-aMinobenzaldehyde
  • Ambroxol Impurity 60
  • 2-Amino-4-bromobenzaL
  • Benzaldehyde, 2-amino-4-bromo-
  • 2-AMINO-4-BROMOBENZALDEHYDE ISO 9001：2015 REACH
  • 59278-65-8
  • Aromatic Aldehydes & Derivatives (substituted)