Reaction
ChemicalBook > CAS DataBase List > (R)-N-(Pyridin-2-ylmethyl)-7′-di( 3,5-di-tert-butylphenyl)phosphin o-1,1′-spirobiindanyl-7-amine

(R)-N-(Pyridin-2-ylmethyl)-7′-di( 3,5-di-tert-butylphenyl)phosphin o-1,1′-spirobiindanyl-7-amine

Reaction
Product Name
(R)-N-(Pyridin-2-ylmethyl)-7′-di( 3,5-di-tert-butylphenyl)phosphin o-1,1′-spirobiindanyl-7-amine
CAS No.
1298133-21-7
Chemical Name
(R)-N-(Pyridin-2-ylmethyl)-7′-di( 3,5-di-tert-butylphenyl)phosphin o-1,1′-spirobiindanyl-7-amine
Synonyms
(R)-SPIROPAP;(R)-DTB-SpiroPAP;99% ee) (R)-DTB-SpiroPAP;(R)-N-(Pyridin-2-ylmethyl)-7′-di( 3,5-di-tert-butylphenyl)phosphin o-1,1′-spirobiindanyl-7-amine;(R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7''-[(pyridine-2-ylmethyl)amino]-2,2'',3,3''-tetrahydro-1,1''-spirobiindane;N-[(1'R)-7'-[BIS[3,5-BIS(TERT-BUTYL)PHENYL]PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBI[1H-INDEN]-7-YL]-2-PYRIDINEMETHANAMINE;(R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7'-[(pyridine-2-ylmethyl)amino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane, min. 98% (>N-[(1'R)-7'-[Bis[3,5-bis(tert-butyl)phenyl]phosphino]-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-inden]-7-yl]-2-pyridinemethanamine,99%e.e.;2-Pyridinemethanamine, N-[(1'R)-7'-[bis[3,5-bis(1,1-dimethylethyl)phenyl]phosphino]-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-inden]-7-yl]-;(R)-(+)-7-BIS(3,5-DI-T-BUTYLPHENYL)PHOSPHINO-7'-[(PYRIDINE-2-YLMETHYL)AMINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE,MIN.98%(>99%EE)(R)-DTB-SPIROPAP
CBNumber
CB73044327
Molecular Formula
C51H63N2P
Formula Weight
735.03
MOL File
1298133-21-7.mol
More
Less

(R)-N-(Pyridin-2-ylmethyl)-7′-di( 3,5-di-tert-butylphenyl)phosphin o-1,1′-spirobiindanyl-7-amine Property

Melting point:
172-174°C
alpha 
+172° (c 0.5, CH2Cl2)
Boiling point:
751.9±60.0 °C(Predicted)
storage temp. 
2-8°C, protect from light, stored under nitrogen
pka
4.80±0.12(Predicted)
form 
solid
color 
white
Sensitive 
air sensitive
More
Less

Hazard and Precautionary Statements (GHS)

More
Less

N-Bromosuccinimide Price

Strem Chemicals
Product number
15-5166
Product name
(R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7'-[(pyridine-2-ylmethyl)amino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane, min. 98% (>99% ee) (R)-DTB-SpiroPAP
Packaging
25mg
Price
$85
Updated
2024/03/01
Strem Chemicals
Product number
15-5166
Product name
(R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7'-[(pyridine-2-ylmethyl)amino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane, min. 98% (>99% ee) (R)-DTB-SpiroPAP
Packaging
100mg
Price
$250
Updated
2024/03/01
ChemScene
Product number
CS-0059986
Product name
(R)-DTB-SpiroPAP
Packaging
50mg
Price
$240
Updated
2021/12/16
More
Less

(R)-N-(Pyridin-2-ylmethyl)-7′-di( 3,5-di-tert-butylphenyl)phosphin o-1,1′-spirobiindanyl-7-amine Chemical Properties,Usage,Production

Reaction

Extremely efficient chiral iridium catalyst used for the asymmetric hydrogenation of ketones.

(R)-N-(Pyridin-2-ylmethyl)-7′-di( 3,5-di-tert-butylphenyl)phosphin o-1,1′-spirobiindanyl-7-amine Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(R)-N-(Pyridin-2-ylmethyl)-7′-di( 3,5-di-tert-butylphenyl)phosphin o-1,1′-spirobiindanyl-7-amine Suppliers

Aladdin Scientific
Tel
Email
tp@aladdinsci.com
Country
United States
ProdList
52923
Advantage
58
Strem Chemicals, Inc.
Tel
--
Fax
--
Email
info@strem.com
Country
United States
ProdList
4910
Advantage
86

1298133-21-7, (R)-N-(Pyridin-2-ylmethyl)-7′-di( 3,5-di-tert-butylphenyl)phosphin o-1,1′-spirobiindanyl-7-amineRelated Search:


  • (R)-N-(Pyridin-2-ylmethyl)-7′-di( 3,5-di-tert-butylphenyl)phosphin o-1,1′-spirobiindanyl-7-amine
  • (R)-SPIROPAP
  • N-[(1'R)-7'-[BIS[3,5-BIS(TERT-BUTYL)PHENYL]PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBI[1H-INDEN]-7-YL]-2-PYRIDINEMETHANAMINE
  • (R)-DTB-SpiroPAP
  • N-[(1'R)-7'-[Bis[3,5-bis(tert-butyl)phenyl]phosphino]-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-inden]-7-yl]-2-pyridinemethanamine,99%e.e.
  • (R)-(+)-7-BIS(3,5-DI-T-BUTYLPHENYL)PHOSPHINO-7'-[(PYRIDINE-2-YLMETHYL)AMINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE,MIN.98%(>99%EE)(R)-DTB-SPIROPAP
  • (R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7'-[(pyridine-2-ylmethyl)amino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane, min. 98% (&gt
  • 99% ee) (R)-DTB-SpiroPAP
  • 2-Pyridinemethanamine, N-[(1'R)-7'-[bis[3,5-bis(1,1-dimethylethyl)phenyl]phosphino]-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-inden]-7-yl]-
  • (R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7''-[(pyridine-2-ylmethyl)amino]-2,2'',3,3''-tetrahydro-1,1''-spirobiindane
  • (R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7'-[(pyridine-2-ylmethyl)amino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane, min. 98% (>99% ee) (R)-DTB-SpiroPAP
  • 1298133-21-7
  • C51H63N2P
  • Chiral Phosphine
  • Chiral Spiro Ligand