ChemicalBook > CAS DataBase List > Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
Reaction- Product Name
- Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
- CAS No.
- 1702311-34-9
- Chemical Name
- Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
- Synonyms
- Josiphos Pd G3;JOSIPHOS Palladacycle Gen. 3;BRUNO PALLADACYCLE;cyclopenta-2,4-dien-1-yl-[(1R)-2-[(1R)-1-ditert-butylphosphanylethyl]-1-dicyclohexylphosphanyl-cyclopenta-2,4-dien-1-yl]iron;Chloro{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)Josiphos Pd G3;Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II),[Josiphos Palladacycle Gen. 3];METHANESULFONATO{(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE}(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),MIN.98%[JOSIPHOSPALLADACYCLEGEN.3]
- CBNumber
- CB73159041
- Molecular Formula
- C45H66FeNO3P2PdS10*-
- Formula Weight
- 925.287962
- MOL File
- 1702311-34-9.mol
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Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II) Property
- Melting point:
- 180-186 °C
- form
- solid
- color
- red-orange
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 747130
- Product name
- Josiphos SL-J009-1 Pd G3
- Packaging
- 100MG
- Price
- $111
- Updated
- 2023/06/20
Sigma-Aldrich
- Product number
- 747130
- Product name
- Josiphos SL-J009-1 Pd G3
- Packaging
- 250MG
- Price
- $272
- Updated
- 2023/06/20
Sigma-Aldrich
- Product number
- 747130
- Product name
- Josiphos SL-J009-1 Pd G3
- Packaging
- 1G
- Price
- $944
- Updated
- 2023/06/20
Sigma-Aldrich
- Product number
- 747130
- Product name
- Josiphos SL-J009-1 Pd G3
- Packaging
- 5G
- Price
- $4110
- Updated
- 2023/06/20
Strem Chemicals
- Product number
- 46-0353
- Product name
- Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [Josiphos Palladacycle Gen. 3]
- Packaging
- 100mg
- Price
- $104
- Updated
- 2024/03/01
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Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II) Chemical Properties,Usage,Production
Reaction
Catalyst used for C-O coupling reactions between electron-deficient phenols and functionalized heteroaryl chlorides.
General Description
Josiphos SL-J009-1 Pd G3 (Josiphos SL-J009-1-G3-palladacycle) is a modified G3 precatalyst (G3′). It has been synthesized by Buchwald and coworkers from second generation (G2) precatalyst by methylation of the amino group present on biphenyl backbone. It is a useful catalyst for various cross-coupling reactions. G3 precatalysts are versatile catalysts. They have long life in solution and are readily soluble in various organic solvents. G3- precatalysts have been employed in various C-N bond forming reactions.
Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II) Preparation Products And Raw materials
Raw materials
Preparation Products
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Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II) Suppliers
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