Josiphos SL-J009-1 Pd G3
Reaction- Product Name
- Josiphos SL-J009-1 Pd G3
- CAS No.
- 1702311-34-9
- Chemical Name
- Josiphos SL-J009-1 Pd G3
- Synonyms
- Josiphos Pd G3;JOSIPHOS Palladacycle Gen. 3;BRUNO PALLADACYCLE;Josiphos SL-J009-1 Pd G3;Josiphos SL-J009-1 Pd G3 ChemBeads;cyclopenta-2,4-dien-1-yl-[(1R)-2-[(1R)-1-ditert-butylphosphanylethyl]-1-dicyclohexylphosphanyl-cyclopenta-2,4-dien-1-yl]iron;Chloro{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II);methylsulfonylacid{[(R)-(-)-1[(S)-2-(dicyclohexylphosphino)diron]ethyldibutylphosphinoyl}(2'-amino-1,1'-biphenyl-2-yl)paladium(I-I);Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)Josiphos Pd G3
- CBNumber
- CB73159041
- Molecular Formula
- C45H66FeNO3P2PdS10*-
- Formula Weight
- 925.287962
- MOL File
- 1702311-34-9.mol
Josiphos SL-J009-1 Pd G3 Property
- Melting point:
- 180-186 °C
- storage temp.
- 2-8°C, protect from light, stored under nitrogen
- form
- solid
- color
- red-orange
- InChIKey
- VXSQFQJKYCLYAK-DHOIFHORSA-N
- SMILES
- NC1=C(C=CC=C1)C2=C([Pd]OS(C)(=O)=O)C=CC=C2.C[C@@H](P(C(C)(C)C)C(C)(C)C)[C]3[C](P(C4CCCCC4)C5CCCCC5)[C][C][C]3.[C]6[C][C][C][C]6.[Fe]
Safety
- WGK Germany
- WGK 3
- Storage Class
- 11 - Combustible Solids
N-Bromosuccinimide Price
- Product number
- 747130
- Product name
- Josiphos SL-J009-1 Pd G3
- Packaging
- 100MG
- Price
- $110.4
- Updated
- 2025/07/31
- Product number
- 747130
- Product name
- Josiphos SL-J009-1 Pd G3
- Packaging
- 250MG
- Price
- $292
- Updated
- 2025/07/31
- Product number
- 747130
- Product name
- Josiphos SL-J009-1 Pd G3
- Packaging
- 1G
- Price
- $1010
- Updated
- 2025/07/31
- Product number
- 747130
- Product name
- Josiphos SL-J009-1 Pd G3
- Packaging
- 5G
- Price
- $3087
- Updated
- 2025/07/31
- Product number
- 46-0353
- Product name
- Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [Josiphos Palladacycle Gen. 3]
- Packaging
- 100mg
- Price
- $104
- Updated
- 2024/03/01
Josiphos SL-J009-1 Pd G3 Chemical Properties,Usage,Production
Reaction
Catalyst used for C-O coupling reactions between electron-deficient phenols and functionalized heteroaryl chlorides.
Uses
Josiphos SL-J009-1 Pd G3 is a good catalyst, widely used in various cross-coupling reactions, including: Buchwald-Hartwig cross-coupling reaction, Hiyama Coupling, Negishi Coupling, Heck Reaction, Sonogashira Coupling and Suzuki-Miyaura Coupling, etc.
General Description
Josiphos SL-J009-1 Pd G3 (Josiphos SL-J009-1-G3-palladacycle) is a modified G3 precatalyst (G3′). It has been synthesized by Buchwald and coworkers from second generation (G2) precatalyst by methylation of the amino group present on biphenyl backbone. It is a useful catalyst for various cross-coupling reactions. G3 precatalysts are versatile catalysts. They have long life in solution and are readily soluble in various organic solvents. G3- precatalysts have been employed in various C-N bond forming reactions.
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
Josiphos SL-J009-1 Pd G3 Preparation Products And Raw materials
Raw materials
Preparation Products
Josiphos SL-J009-1 Pd G3 Suppliers
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View Lastest Price from Josiphos SL-J009-1 Pd G3 manufacturers
- Product
- Josiphos SL-J009-1 Pd G3 1702311-34-9
- Price
- US $2.00-5.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2025-06-20