Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)

Reaction

Product Name: Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
CAS No.: 1702311-34-9
Chemical Name: Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
Synonyms: Josiphos Pd G3;JOSIPHOS Palladacycle Gen. 3;BRUNO PALLADACYCLE;cyclopenta-2,4-dien-1-yl-[(1R)-2-[(1R)-1-ditert-butylphosphanylethyl]-1-dicyclohexylphosphanyl-cyclopenta-2,4-dien-1-yl]iron;Chloro{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)Josiphos Pd G3;Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II),[Josiphos Palladacycle Gen. 3];METHANESULFONATO{(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE}(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),MIN.98%[JOSIPHOSPALLADACYCLEGEN.3]
CBNumber: CB73159041
Molecular Formula: C45H66FeNO3P2PdS10*-
Formula Weight: 925.287962
MOL File: 1702311-34-9.mol

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Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II) Property

Melting point:: 180-186 °C
form: solid
color: red-orange

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 747130
Product name: Josiphos SL-J009-1 Pd G3
Packaging: 100MG
Price: $111
Updated: 2023/06/20

Sigma-Aldrich

Product number: 747130
Product name: Josiphos SL-J009-1 Pd G3
Packaging: 250MG
Price: $272
Updated: 2023/06/20

Sigma-Aldrich

Product number: 747130
Product name: Josiphos SL-J009-1 Pd G3
Packaging: 1G
Price: $944
Updated: 2023/06/20

Sigma-Aldrich

Product number: 747130
Product name: Josiphos SL-J009-1 Pd G3
Packaging: 5G
Price: $4110
Updated: 2023/06/20

Strem Chemicals

Product number: 46-0353
Product name: Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [Josiphos Palladacycle Gen. 3]
Packaging: 100mg
Price: $104
Updated: 2024/03/01

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Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II) Chemical Properties,Usage,Production

Reaction

Catalyst used for C-O coupling reactions between electron-deficient phenols and functionalized heteroaryl chlorides.

General Description

Josiphos SL-J009-1 Pd G3 (Josiphos SL-J009-1-G3-palladacycle) is a modified G3 precatalyst (G3′). It has been synthesized by Buchwald and coworkers from second generation (G2) precatalyst by methylation of the amino group present on biphenyl backbone. It is a useful catalyst for various cross-coupling reactions. G3 precatalysts are versatile catalysts. They have long life in solution and are readily soluble in various organic solvents. G3- precatalysts have been employed in various C-N bond forming reactions.

Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II) Suppliers

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1702311-34-9, Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)Related Search:

tBuXPhos-Pd-G3 XPhos Pd G3 BrettPhos Pd G3 SPhos Pd G3 XantPhos Pd G4

Chloro{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)

JOSIPHOS Palladacycle Gen. 3

Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)

METHANESULFONATO{(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-T-BUTYLPHOSPHINE}(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),MIN.98%[JOSIPHOSPALLADACYCLEGEN.3]

Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II),[Josiphos Palladacycle Gen. 3]

BRUNO PALLADACYCLE

Josiphos Pd G3

Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)Josiphos Pd G3

Methanesulfonato{(R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-t-butylphosphine}(2'-amino-1,1'-biphenyl-2-yl)palladium(II)

cyclopenta-2,4-dien-1-yl-[(1R)-2-[(1R)-1-ditert-butylphosphanylethyl]-1-dicyclohexylphosphanyl-cyclopenta-2,4-dien-1-yl]iron

(SP-4-3)-[2′-(Amino-κN)[1,1′-biphenyl]-2-yl-κC][(2R)-1-[(1R)-1-[bis(1,1-dimethylethyl)phosphino-κP]ethyl]-2-(dicyclohexylphosphino)ferrocene](methanesulfonato-κO)palladium (ACI)

1702311-34-9

C45H65FeNO3P2PdS