Sulfuryl bromide fluoride Property

Boiling point:

40°C (estimate)

solubility 

reacts with H2O

form 

liquid

color 

colorless

Hazard and Precautionary Statements (GHS)

Sulfuryl bromide fluoride Chemical Properties,Usage,Production

Chemical Properties

Sulfuryl bromide fluoride is a colorless compound, choking odor similar to SO2Cl2, thermally stable, reacts slowly with glass at room temperature, unreactive with quartz. Reacts vigorously with water (hydrolysis). On contact with moist air, it acquires a slightly reddish color due to liberation of bromine.

Preparation

The rate of Sulfuryl bromide fluoride formation depends upon the rate at which the following equilibrium is established: Br2 + BrF3 = 3BrF. Sulfur dioxide (120 g) is gradually distilled at +12℃ into an iron autoclave containing a mixture of 20 ml. of bromine and 21.2 ml of BrF3. After letting stand for several days, during the autoclave is which shaken once daily, the product is distilled from the pressure vessel and collected in a quartz trap at -196℃ For purification, the SO2BrF is passed through a wash bottle filled with mercury (removal of traces of bromine and BrF3), then over NaF (removal of HF), and finally over P2O5 (removal of water). The product is then fractionated and the first cut discarded. There is no residue. The yield is 88%, based on BrF3.