2,3-BIS(BROMOMETHYL)QUINOXALINE
- Product Name
- 2,3-BIS(BROMOMETHYL)QUINOXALINE
- CAS No.
- 3138-86-1
- Chemical Name
- 2,3-BIS(BROMOMETHYL)QUINOXALINE
- Synonyms
- NSC 38602;2,3-BIS-(BROMETHYL)QUINOXALINE;2,3-BIS(BROMOMETHYL)QUINOXALINE;2,3-bis(bromomethyl)-quinoxalin;2,3-Bis (bromomethyl) quinoline;Quinoxaline, 2,3-bis(bromomethyl)-;2,3-BIS-(BROMETHYL)-QUINOXALINE98%;2,3-Bis(bromomethyl)quinoxaline,98%;2,3-Bis(bromomethyl)-1,4-benzodiazine;2,3-Bis-(bromomethyl)quinoxaline, HPLC 98%
- CBNumber
- CB7321872
- Molecular Formula
- C10H8Br2N2
- Formula Weight
- 315.99
- MOL File
- 3138-86-1.mol
2,3-BIS(BROMOMETHYL)QUINOXALINE Property
- Melting point:
- 152-156 °C(lit.)
- Boiling point:
- 345.7±37.0 °C(Predicted)
- Density
- 1.7904 (rough estimate)
- refractive index
- 1.7040 (estimate)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- powder
- pka
- -1.31±0.48(Predicted)
- Appearance
- Off-white to gray Solid
- EPA Substance Registry System
- Quinoxaline, 2,3-bis(bromomethyl)- (3138-86-1)
Safety
- Hazard Codes
- C
- Risk Statements
- 34-36/37
- Safety Statements
- 26-27-28-36/37/39-45
- RIDADR
- UN 3261 8/PG 2
- WGK Germany
- 3
- RTECS
- VD1420000
- TSCA
- Yes
- HazardClass
- 8
- PackingGroup
- III
- Toxicity
- LD50 ivn-mus: 18 mg/kg CSLNX* NX#02400
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
H335May cause respiratory irritation
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- B37159
- Product name
- 2,3-Bis(bromomethyl)quinoxaline
- Purity
- 98%
- Packaging
- 10g
- Price
- $673
- Updated
- 2023/01/07
- Product number
- HCH0010612
- Product name
- 2,3-BIS(BROMOMETHYL)QUINOXALINE
- Purity
- 95.00%
- Packaging
- 10G
- Price
- $1206.2
- Updated
- 2021/12/16
- Product number
- FB04248
- Product name
- 2,3-Bis(bromomethyl)quinoxaline
- Packaging
- 10g
- Price
- $200
- Updated
- 2021/12/16
- Product number
- FB04248
- Product name
- 2,3-Bis(bromomethyl)quinoxaline
- Packaging
- 1g
- Price
- $50
- Updated
- 2021/12/16
- Product number
- FB04248
- Product name
- 2,3-Bis(bromomethyl)quinoxaline
- Packaging
- 2g
- Price
- $72
- Updated
- 2021/12/16
2,3-BIS(BROMOMETHYL)QUINOXALINE Chemical Properties,Usage,Production
Chemical Properties
grey to beige-brown crystalline powder
Safety Profile
Poison by intravenous route. Seealso BROMIDES. When heated to decomposition it emitsvery toxic fumes of Br- and NOx.
Synthesis
95-54-5
6305-43-7
3138-86-1
The general procedure for the synthesis of 2,3-bis(bromomethyl)quinoxaline from o-phenylenediamine and 1,4-dibromo-2,3-butanedione was as follows: 6.52 g (27 mmol) of 1,4-dibromo-2,3-butanedione and 300 mL of ethanol were added to a 1,000 mL three-neck flask. Subsequently, a solution made from 2.94 g (27 mmol) of o-phenylenediamine dissolved in 150 mL of ethanol was added to the mixture with continuous stirring for 30 minutes at room temperature. White solid precipitation was observed during the reaction. To the reaction mixture, 200 mL of water was added and the white solid was collected by filtration and dried under reduced pressure to give 6.74 g (yield: 81%) of the target product 2,3-bis(bromomethyl)quinoxaline. The 1H nuclear magnetic resonance (1H-NMR) spectral data of the compound were as follows: 1H-NMR (CDCl3): δ 4.93 (s, 4H), 7.81 (q, 2H), 8.08 (q, 2H).
References
[1] Tetrahedron, 2013, vol. 69, # 4, p. 1403 - 1416
[2] Journal of Organic Chemistry, 2005, vol. 70, # 13, p. 5055 - 5061
[3] Organometallics, 2013, vol. 32, # 12, p. 3493 - 3501
[4] Synthetic Communications, 2011, vol. 41, # 3, p. 417 - 425
[5] Journal of Chemical Crystallography, 2006, vol. 36, # 3, p. 211 - 215
2,3-BIS(BROMOMETHYL)QUINOXALINE Preparation Products And Raw materials
Raw materials
Preparation Products
2,3-BIS(BROMOMETHYL)QUINOXALINE Suppliers
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View Lastest Price from 2,3-BIS(BROMOMETHYL)QUINOXALINE manufacturers
- Product
- 2,3-BIS(BROMOMETHYL)QUINOXALINE 3138-86-1
- Price
- US $1.00/Kg
- Min. Order
- 1Kg
- Purity
- 98%
- Supply Ability
- 20T
- Release date
- 2024-07-07