DIMETHYLKETENE METHYL TRIMETHYLSILYL ACETAL

Product Name: DIMETHYLKETENE METHYL TRIMETHYLSILYL ACETAL
CAS No.: 31469-15-5
Chemical Name: DIMETHYLKETENE METHYL TRIMETHYLSILYL ACETAL
Synonyms: MTDA;((1-Methoxy-2-Methylprop-1-en-1-yl)oxy)triMethylsilane;DKSI044;DKFELEX0086;1-Methoxy-1-tri;DIMETHYLKETENE METHYL;organosilicon monomer;1-METHOXY-2-METHYL-1-TRIMETHYL-;METHYL TRIMETHYLSILYL DIMETHYLKETENE ACETAL;DIMETHYLKETENE METHYL TRIMETHYLSILYL ACETAL
CBNumber: CB7339664
Molecular Formula: C8H18O2Si
Formula Weight: 174.31
MOL File: 31469-15-5.mol

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DIMETHYLKETENE METHYL TRIMETHYLSILYL ACETAL Property

Boiling point:: 35 °C15 mm Hg(lit.)
Density: 0.858 g/mL at 25 °C(lit.)
refractive index: n20/D 1.415(lit.)
Flash point:: 58 °F
storage temp.: Inert atmosphere,Room Temperature
solubility: freely sol organic solvents.
form: clear liquid
color: Colorless to Almost colorless
Specific Gravity: 0.858
Water Solubility: Hydrolyzes in water.
Sensitive: Moisture Sensitive
Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
BRN: 1362893
Stability:: Moisture and Acid Sensitive
CAS DataBase Reference: 31469-15-5(CAS DataBase Reference)
EPA Substance Registry System: Silane, [(1-methoxy-2-methyl-1-propenyl)oxy]trimethyl- (31469-15-5)

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Safety

Hazard Codes: Xi
Risk Statements: 10-36/37/38
Safety Statements: 16-26-36
RIDADR: UN 3271 3/PG 3
WGK Germany: 3
F: 10-21
TSCA: Yes
HazardClass: 3
PackingGroup: III
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 274585
Product name: Methyl trimethylsilyl dimethylketene acetal
Purity: 95%
Packaging: 5g
Price: $61.2
Updated: 2024/03/01

Sigma-Aldrich

Product number: 274585
Product name: Methyl trimethylsilyl dimethylketene acetal
Purity: 95%
Packaging: 25g
Price: $112.4
Updated: 2024/03/01

TCI Chemical

Product number: D1789
Product name: Dimethylketene Methyl Trimethylsilyl Acetal
Purity: >95.0%(GC)
Packaging: 5mL
Price: $55
Updated: 2024/03/01

TCI Chemical

Product number: D1789
Product name: Dimethylketene Methyl Trimethylsilyl Acetal
Purity: >95.0%(GC)
Packaging: 25mL
Price: $161
Updated: 2024/03/01

Alfa Aesar

Product number: L06931
Product name: 1-Methoxy-2-methyl-1-(trimethylsiloxy)propene, 97%
Packaging: 5g
Price: $68.65
Updated: 2024/03/01

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DIMETHYLKETENE METHYL TRIMETHYLSILYL ACETAL Chemical Properties,Usage,Production

Chemical Properties

Clear colorless liquid

Physical properties

bp 35 °C/15 mmHg; d 0.858 g cm?3.

Uses

1-Methoxy-2-methyl-1-(trimethylsilyloxy) propene is widely used as functional equivalent of enolate of methyl isobutyrate; ester enolate surrogate in electrophilic reactions including alkylation, aldol reaction, Michael reaction, initiator for group transfer polymerization of acrylates, nitroarylation, oxidation, dimerization, and cycloadditions.

Uses

1-Methoxy-2-methyl-1-(trimethylsiloxy)propene is used in the synthesis of chiral β-lactams by reacting with (S)-alkylidene(1-arylethyl)amines in the presence of titanium tetrachloride. It acts as a catalyst or initiator in the group-transfer polymerization. It is also used as a versatile reagent in conjugate addition4 and aldol reactions.

Preparation

The title compound is a prototypical ketene silyl acetal (KSA) that can been prepared by either of the two most commonly employed methods: (a) deprotonation of the |á-hydrogen of an ester followed by silylation (1),16 and (b) metal-catalyzed hydrosilylation of |á,|?-unsaturated esters(2).

Purification Methods

Add Et2O, wash with cold H2O, dry (Na2SO4), filter, evaporate Et2O, and distil the oily residue in a vacuum. [Ainsworth et al. J Organometal Chem 46 59 1972.]

DIMETHYLKETENE METHYL TRIMETHYLSILYL ACETAL Preparation Products And Raw materials

Raw materials

Preparation Products

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DIMETHYLKETENE METHYL TRIMETHYLSILYL ACETAL Suppliers

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View Lastest Price from DIMETHYLKETENE METHYL TRIMETHYLSILYL ACETAL manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: DIMETHYLKETENE METHYL TRIMETHYLSILYL ACETAL 31469-15-5
Price: US $1.00/Kg
Min. Order: 1Kg
Purity: 98%
Supply Ability: 20T
Release date: 2024-07-20

Career Henan Chemical Co

Product: DIMETHYLKETENE METHYL 31469-15-5
Price: US $7.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100KG
Release date: 2020-01-09

31469-15-5, DIMETHYLKETENE METHYL TRIMETHYLSILYL ACETALRelated Search:

2-(4-BROMOPHENYL)-1,3-DIOXOLANE 1-(2-TRIMETHYLSILOXYETHOXY)-1-TRIMETHYLSILOXY-2-METHYLPROPENE 1-METHOXY-1-TRIMETHYLSILYLOXYPROPENE VINYLOXYTRIMETHYLSILANE DIMETHYLKETENE METHYL TRIMETHYLSILYL ACETAL 2-METHYL-1-(TRIMETHYLSILOXY)-1-PROPENE

MTDA

[(1-METHOXY-2-METHYL-1-PROPENYL)OXY]TRIMETHYLSILANE

1-METHOXY-2-METHYL-1-(TRIMETHYLSILOXY)PROPENE

DIMETHYLKETENE METHYL TRIMETHYLSILYL ACETAL

METHYL TRIMETHYLSILYL DIMETHYLKETENE ACETAL

DIMETHYLKETENE METHYL

Silane,[(1-methoxy-2-methyl-1-propen-1-yl)oxy]trimethyl-

organosilicon monomer

1-Methoxy-1-trimethylsiloxy-2-methyl-1-propene~Methyl trimethylsilyl dimethylketene acetal~MTDA

1-METHOXY-2-METHYL-1-TRIMETHYL-

1-METHOXY-1-(TRIMETHYLSILOXY)-2-METHYL-1-PROPENE

1-METHOXY-1-TRIMETHYLSILOXY-2-METHYLPROPENE

Silane, ((1-methoxy-2-methyl-1-propenyl)oxy)trimethyl-

Methyl Trimethylsiliyl dimethyl ketene acetal

1-methoxy-2-methyl-1-trimethylsiloxypropane

(1-Methoxy-2-methyl-1-propenyloxy)trimethylsilane, MTDA

(1-Methoxy-2-methyl-1-propenyloxy)trimethylsilane, 1-Methoxy-2-methyl-1-(trimethylsiloxy)propene, MTDA

(1-Methoxy-2-methyl-1-propenyl)(trimethylsilyl) ether

(Trimethylsilyl)(1-methoxy-2-methyl-1-propenyl) ether

1-[(Trimethylsilyl)oxy]-1-methoxy-2-methyl-1-propene

2-Methyl-1-(trimethylsiloxy)-1-methoxy-1-propene

1-Methoxy-1-(triMethylsilyloxy)-2-Methyl-1-propene

(1-Methoxy-2-Methylprop-1-enyloxy)triMethylsilane

((1-Methoxy-2-Methylprop-1-en-1-yl)oxy)triMethylsilane

1-Methoxy-1-tri

Methyl triMethylsilyl diMethylketene acetal 95%

(1-methoxy-2-methylprop-1-enoxy)-trimethylsilane

DimethylketeneMethylTrimethylsilylAcetal&gt

1-Methoxy-2-methyl-1-(trimethylsilyloxy)propene

DKFELEX0086

DKSI044

31469-15-5

CH32CCOCH3OSiCH33

Building Blocks

Oxygen Compounds

Acetals/Ketals/Ortho Esters

Enol Ethers

Organic Building Blocks

Si-O Compounds

Silicon Compounds (for Synthesis)

Vinylsilanes, Allylsilanes

Monoalkoxysilanes

Si (Classes of Silicon Compounds)

Monoalkoxysilanes

Si (Classes of Silicon Compounds)

Silicon Compounds (for Synthesis)

Si-O Compounds

Synthetic Organic Chemistry

Vinylsilanes, Allylsilanes