3-CARENE
- Product Name
- 3-CARENE
- CAS No.
- 13466-78-9
- Chemical Name
- 3-CARENE
- Synonyms
- carene;DELTA-3-CARENE;Car-3-ene;3,7,7-TRIMETHYLBICYCLO[4.1.0]HEPT-3-ENE;D-CARENE;delta-3-CARENE, NATURAL;3-Karen;3-CARENE;3-CARVENE;FEMA 3821
- CBNumber
- CB7349182
- Molecular Formula
- C10H16
- Formula Weight
- 136.23
- MOL File
- 13466-78-9.mol
3-CARENE Property
- Melting point:
- 25°C
- Boiling point:
- 168-169 °C/705 mmHg (lit.)
- Density
- 0.857 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.474(lit.)
- FEMA
- 3821 | DELTA-3-CARENE
- Flash point:
- 115 °F
- storage temp.
- 2-8°C
- solubility
- Chloroform: Soluble; Methanol: Soluble
- form
- Liquid
- color
- Clear colorless to slightly yellow
- Odor
- at 100.00 %. citrus terpenic herbal pine solvent resinous phenolic cypress medicinal woody
- Odor Type
- citrus
- optical activity
- [α]20/D +15°, neat
- JECFA Number
- 1342
- Merck
- 1836
- Stability:
- Stable. Flammable. Incompatible with strong oxidizing agents.
- LogP
- 4.38
- EPA Substance Registry System
- 3-Carene (13466-78-9)
Safety
- Hazard Codes
- Xi,N,Xn
- Risk Statements
- 10-43-50/53-65-38-52/53
- Safety Statements
- 16-26-36/37-60-61-62-37-24
- RIDADR
- UN 2319 3/PG 3
- WGK Germany
- 2
- RTECS
- FH8400000
- HazardClass
- 3.2
- PackingGroup
- III
- HS Code
- 29021990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H226Flammable liquid and vapour
H304May be fatal if swallowed and enters airways
H315Causes skin irritation
H317May cause an allergic skin reaction
H412Harmful to aquatic life with long lasting effects
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P331Do NOT induce vomiting.
N-Bromosuccinimide Price
- Product number
- 115576
- Product name
- 3-Carene
- Purity
- 90%
- Packaging
- 25ml
- Price
- $50.2
- Updated
- 2024/03/01
- Product number
- 115576
- Product name
- 3-Carene
- Purity
- 90%
- Packaging
- 1l
- Price
- $149
- Updated
- 2024/03/01
- Product number
- CRM40752
- Product name
- 3-Carene solution
- Purity
- certifiedreferencematerial,2000?μg/mLinmethanol,ampuleof1?mL
- Packaging
- 1mL
- Price
- $127
- Updated
- 2022/05/15
- Product number
- C0047
- Product name
- (+)-3-Carene
- Purity
- >90.0%(GC)
- Packaging
- 25mL
- Price
- $16
- Updated
- 2021/12/16
- Product number
- C0047
- Product name
- (+)-3-Carene
- Purity
- >90.0%(GC)
- Packaging
- 500mL
- Price
- $37
- Updated
- 2021/12/16
3-CARENE Chemical Properties,Usage,Production
Description
Hydroperoxides of Δ-3-carene are allergens contained in turpentine. Occupational exposure occurs in painters, varnishers, or in ceramic decoration. The percentage of Δ-3-Carene is higher in Indonesian turpentine than in Portugese.
Description
(±)-3-Carene is a bicyclic monoterpene found in a variety of plants, including Cannabis. It decreases phagocytosis by rat alveolar macrophages when used at a concentration of 0.5 μM and decreases their viability at a concentration of 5 μM. (±)-3-Carene increases the expression and activity of alkaline phosphatase in mouse osteoblastic MC3T3-E1 subclone 4 cells, indicating induction of osteoblastic differentiation. It also induces calcium formation and increases the expression of osteopontin and type I collagen, which are related to osteoblast mineralization. (±)-3-Carene induces bronchoconstriction in isolated guinea pig lungs when exposed at an air concentration of 3,000 mg/m3.
Chemical Properties
Clear, colorless liquid. Stable to approx- imately 250C, resinifies with oxygen. Insoluble in water; miscible with organic solutions. Com- bustible.
Chemical Properties
3-Carene has a sweet, pungent turpentine-like taste.
Occurrence
Reported present in basil oil, bell pepper, bilberry, black currant berry juice and buds, fennel oil, grapefruit juice, kumquat peel oil, lemon peel oil, lime peel oil (cold pressed and distilled), lovage seed, mandarin peel oil, orange juice, orange peel oil, orange (bitter) peel oil, tangerine peel oil and other natural products.
Uses
Solvent, intermediate. 3-Carene is a mutagenic compound that may be found in the fumes of heating freshly cut spruce and birch chips. 3-Carene is also found i many esential oils and it inhibits acetylcholinesterase activity.
Preparation
Extracted from the pine tree oil.
Definition
A terpene hydrocarbon with both a 6-member and 3-member ring.
Synthesis Reference(s)
Tetrahedron Letters, 25, p. 5255, 1984 DOI: 10.1016/S0040-4039(01)81577-X
General Description
Colorless liquid with a sweet, turpentine-like odor. Floats on water.
Reactivity Profile
3-CARENE may react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release hydrogen gas. In the presence of various catalysts (such as acids) or initiators, may undergo exothermic addition polymerization reactions. Will attack some forms of plastics [USCG, 1999].
Health Hazard
Inhalation causes headache, confusion, respiratory distress. Ingestion irritates entire digestive system and may injure kidneys; if liquid enters lungs, it causes severe pneumonitis. Contact with eyes or skin causes irritation.
Contact allergens
Hydroperoxides of D-3-carene are allergens contained in turpentine. Occupational exposure occurs in painters, varnishers, or ceramic decoration. The percentage of D-3-carene is higher in Indonesian than in Portuguese turpentine.
3-CARENE Preparation Products And Raw materials
Raw materials
Preparation Products
3-CARENE Suppliers
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View Lastest Price from 3-CARENE manufacturers
- Product
- 3-CARENE 13466-78-9
- Price
- US $6.80-2.20/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 10 tons
- Release date
- 2024-07-05
- Product
- 3-CARENE 13466-78-9
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 50000KG/month
- Release date
- 2024-10-22
- Product
- 3-Carene 13466-78-9
- Price
- US $0.00-0.00/Kg
- Min. Order
- 100G
- Purity
- 99.0%+
- Supply Ability
- 100 tons
- Release date
- 2020-01-17