4-Phenoxybutyl bromide
- Product Name
- 4-Phenoxybutyl bromide
- CAS No.
- 1200-03-9
- Chemical Name
- 4-Phenoxybutyl bromide
- Synonyms
- 1-Bromo-4;(4-Bromobutoxy);Phenoxybutyl bromide;4-Phenoxyethylbromide;4-PHENOXYBUTYL BROMIDE;-Phenoxy-4-bromobutane;(4-Bromobutoxy)benzene;4-Phenoxy-1-bromobutane;4-Bromo-1-phenoxybutane;1-BROMO-4-PHENOXYBUTANE
- CBNumber
- CB7357040
- Molecular Formula
- C10H13BrO
- Formula Weight
- 229.11
- MOL File
- 1200-03-9.mol
4-Phenoxybutyl bromide Property
- Melting point:
- 41-43 °C(lit.)
- Boiling point:
- 153-156 °C18 mm Hg(lit.)
- Density
- 1.3236 (rough estimate)
- refractive index
- 1.5310 (estimate)
- Flash point:
- >230 °F
- storage temp.
- Sealed in dry,Room Temperature
- form
- powder to lump
- color
- White to Almost white
- Water Solubility
- Insoluble in water.
- BRN
- 2044374
- InChI
- InChI=1S/C10H13BrO/c11-8-4-5-9-12-10-6-2-1-3-7-10/h1-3,6-7H,4-5,8-9H2
- InChIKey
- QBLISOIWPZSVIK-UHFFFAOYSA-N
- SMILES
- C1(OCCCCBr)=CC=CC=C1
- CAS DataBase Reference
- 1200-03-9(CAS DataBase Reference)
- NIST Chemistry Reference
- Benzene, (4-bromobutoxy)-(1200-03-9)
- EPA Substance Registry System
- Benzene, (4-bromobutoxy)- (1200-03-9)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- 132543
- Product name
- 4-Bromobutyl phenyl ether
- Purity
- 97%
- Packaging
- 25g
- Price
- $184
- Updated
- 2023/06/20
- Product number
- 132543
- Product name
- 4-Bromobutyl phenyl ether
- Purity
- 97%
- Packaging
- 100g
- Price
- $464
- Updated
- 2023/06/20
- Product number
- P1851
- Product name
- 4-Phenoxybutyl Bromide
- Purity
- >96.0%(GC)
- Packaging
- 5g
- Price
- $92
- Updated
- 2025/07/31
- Product number
- B686778
- Product name
- (4-Bromobutoxy)benzene
- Packaging
- 500mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- 409277
- Product name
- 1-Bromo-4-
- Packaging
- 100mg
- Price
- $305
- Updated
- 2021/12/16
4-Phenoxybutyl bromide Chemical Properties,Usage,Production
Chemical Properties
OFF-WHITE CRYSTALLINE MASS
Uses
(4-Bromobutoxy)benzene is used to produce 5-phenoxy-valeric acid with carbon dioxide and reagent Mg.
Synthesis
110-52-1
108-95-2
1200-03-9
General procedure: In a 500 mL round-bottomed flask, phenol (50 g, 1 eq.), 1,4-dibromobutane (137.7 g, 1.2 eq.), and potassium carbonate (110.5 g, 1.5 eq.), which has been baked at 70 °C for about 2 hours and milled, are added sequentially at room temperature. Potassium iodide (5.5 g, based on 5% of the mass of potassium carbonate) was added under mechanical stirring. The reaction mixture was then warmed up to 80 °C and the reaction was continued at this temperature for 4 to 6 hours, during which the reaction progress was monitored by liquid chromatography. Upon completion of the reaction, the reaction solution was cooled to room temperature and filtered. The filtrates were combined at 40-45 °C and concentrated under reduced pressure at 0.09-0.1 MPa. The resulting crude product had a purity of 90.6% and was subsequently distilled under reduced pressure at 120-130 °C to collect the fractions.The recovery of 1,4-dibromobutane was 64.1% and the net yield of the target product, 4-phenoxybromobutane, was 96.1%.
References
[1] Patent: CN104447220, 2016, B. Location in patent: Paragraph 0024-0026
[2] Archiv der Pharmazie, 2009, vol. 342, # 12, p. 732 - 739
[3] Bioorganic and Medicinal Chemistry, 2010, vol. 18, # 3, p. 1244 - 1251
[4] Tetrahedron Letters, 2010, vol. 51, # 35, p. 4612 - 4616
[5] Chemical Communications, 2014, vol. 50, # 39, p. 5017 - 5019
4-Phenoxybutyl bromide Preparation Products And Raw materials
Raw materials
Preparation Products
4-Phenoxybutyl bromide Suppliers
- Tel
- 0371-0371-55135753 18003832934
- Fax
- QQ：2853979818
- 2853979818@qq.com
- Country
- China
- ProdList
- 9991
- Advantage
- 58
- Tel
- 18210857532; 18210857532
- Fax
- 86-10-82849933
- jkinfo@jkchemical.com
- Country
- China
- ProdList
- 96815
- Advantage
- 76
- Tel
- 010-88425576
- Fax
- (+86)-10-88425546
- sales@dhltchem.com
- Country
- China
- ProdList
- 793
- Advantage
- 59
- Tel
- 400-6106006
- Fax
- 021-67582001/03/05
- saleschina@alfa-asia.com
- Country
- China
- ProdList
- 30123
- Advantage
- 84
- Tel
- 021-67121386
- Fax
- 021-67121385
- Sales-CN@TCIchemicals.com
- Country
- China
- ProdList
- 24529
- Advantage
- 81
- Tel
- 021-021-58432009 400-005-6266
- Fax
- 021-58436166
- sales8178@energy-chemical.com
- Country
- China
- ProdList
- 44801
- Advantage
- 61
- Tel
- 021-50795510 4000665055
- Fax
- 021-50795055
- sales@accelachem.com
- Country
- China
- ProdList
- 11035
- Advantage
- 64
- Tel
- 0086-21-58956006
- Fax
- 0086-21-58956100
- Country
- China
- ProdList
- 7811
- Advantage
- 57
- Tel
- 800-810-5118
- Fax
- +86-10-84193589
- cnchemical@thermofisher.com
- Country
- China
- ProdList
- 17770
- Advantage
- 75
- Tel
- 400-810-7969 010-59572699
- Fax
- 010-59572688
- ningzi.li@inno-chem.com.cn
- Country
- China
- ProdList
- 6134
- Advantage
- 55
View Lastest Price from 4-Phenoxybutyl bromide manufacturers
- Product
- 4-Phenoxybutyl bromide 1200-03-9
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 200kg
- Release date
- 2020-01-08