ChemicalBook > CAS DataBase List > DIETHYL PHENYLTHIOMETHYLPHOSPHONATE

DIETHYL PHENYLTHIOMETHYLPHOSPHONATE

Product Name
DIETHYL PHENYLTHIOMETHYLPHOSPHONATE
CAS No.
38066-16-9
Chemical Name
DIETHYL PHENYLTHIOMETHYLPHOSPHONATE
Synonyms
NSC 202497;LABOTEST-BB LT00453966;DIETHYL PHENYLTHIOMETHYLPHOSPHONATE;Diethyl phenylthiomethanephosphonate;Diethyl methylthiobenzyl phosphonate;diethoxyphosphorylmethylsulfanylbenzene;Diethyl (phenylsulfanyl)methylphosphonate;Diethyl[(phenylthio)methyl]phosphonate, 97 %;Phosphonic acid, [(phenylthio)methyl]-, diethyl ester;Phosphonic acid, P-[(phenylthio)methyl]-, diethyl ester
CBNumber
CB7362624
Molecular Formula
C11H17O3PS
Formula Weight
260.29
MOL File
38066-16-9.mol
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DIETHYL PHENYLTHIOMETHYLPHOSPHONATE Property

Boiling point:
146-148 °C (0.5 mmHg)
Density 
1.17
refractive index 
1.53-1.533
Flash point:
146-148°C/0.5mm
solubility 
Difficult to mix.
form 
Liquid
Specific Gravity
1.174
BRN 
1246215
CAS DataBase Reference
38066-16-9(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26
HS Code 
2931499090
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Biosynth Carbosynth
Product number
FD46768
Product name
Diethyl phenylthiomethylphosphonate
Packaging
1g
Price
$50
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD46768
Product name
Diethyl phenylthiomethylphosphonate
Packaging
2g
Price
$70
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD46768
Product name
Diethyl phenylthiomethylphosphonate
Packaging
5G
Price
$100
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0004107
Product name
DIETHYL PHENYLTHIOMETHYLPHOSPHONATE
Purity
95.00%
Packaging
10G
Price
$172.41
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD46768
Product name
Diethyl phenylthiomethylphosphonate
Packaging
10g
Price
$180
Updated
2021/12/16
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DIETHYL PHENYLTHIOMETHYLPHOSPHONATE Chemical Properties,Usage,Production

Chemical Properties

clear light yellow liquid

Uses

Diethyl phenylthiomethylphosphonate is used to produce Diethylphosphorylmethylphenylsulfoxid, Chemical reagents, pharmaceutical research, pharmaceutical intermediates.

Application

Diethyl phenylthiomethylphosphonate used for the conversion of aldehydes and ketones to vinyl sulfides, which can be hydrolyzed to yield  homologated aldehydes and ketones.

Preparation

The Arbuzov reaction between phenylthiomethyl chloride (Chloromethyl Phenyl Sulfide) and Triethyl  Phosphite is the most commonly used method of preparation (eq 1).

Synthesis Reference(s)

Synthesis, p. 309, 1978 DOI: 10.1055/s-1978-24736

DIETHYL PHENYLTHIOMETHYLPHOSPHONATE Preparation Products And Raw materials

Raw materials

Preparation Products

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DIETHYL PHENYLTHIOMETHYLPHOSPHONATE Suppliers

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38066-16-9, DIETHYL PHENYLTHIOMETHYLPHOSPHONATERelated Search:


  • Diethyl (phenylsulfanyl)methylphosphonate
  • Diethyl methylthiobenzyl phosphonate
  • Phosphonic acid, [(phenylthio)methyl]-, diethyl ester
  • LABOTEST-BB LT00453966
  • DIETHYL PHENYLTHIOMETHYLPHOSPHONATE
  • Diethyl phenylthiomethanephosphonate
  • NSC 202497
  • Diethyl[(phenylthio)methyl]phosphonate, 97 %
  • Phosphonic acid, P-[(phenylthio)methyl]-, diethyl ester
  • diethoxyphosphorylmethylsulfanylbenzene
  • 38066-16-9
  • C11H17O3PS