ChemicalBook > CAS DataBase List > 2,4-DIMETHYLBENZYL ALCOHOL

2,4-DIMETHYLBENZYL ALCOHOL

Product Name
2,4-DIMETHYLBENZYL ALCOHOL
CAS No.
16308-92-2
Chemical Name
2,4-DIMETHYLBENZYL ALCOHOL
Synonyms
RARECHEM AL BD 0048;2,4-DIMETHYLBENZYL ALCOHOL;2,4-Dimethylbenzenemethanol;2,4-DIMETHYLPHENYL METHANOL;2,4-DimethylbenzylAlcohol>Benzyl alcohol, 2,4-dimethyl-;2,4-Dimethylbenzyl alcohol,90%;Benzenemethanol, 2,4-dimethyl-
CBNumber
CB7364446
Molecular Formula
C9H12O
Formula Weight
136.19
MOL File
16308-92-2.mol
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2,4-DIMETHYLBENZYL ALCOHOL Property

Melting point:
22°C
Boiling point:
120 °C13 mm Hg(lit.)
Density 
1.0310
refractive index 
n20/D 1.534(lit.)
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
form 
Liquid After Melting
pka
14.50±0.10(Predicted)
color 
Clear colorless to slightly yellow
BRN 
1859679
LogP
2.049 (est)
CAS DataBase Reference
16308-92-2(CAS DataBase Reference)
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Safety

Safety Statements 
24/25
WGK Germany 
3
HS Code 
29062990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

TCI Chemical
Product number
D4519
Product name
2,4-Dimethylbenzyl Alcohol
Purity
>98.0%(GC)
Packaging
5g
Price
$167
Updated
2025/07/31
TCI Chemical
Product number
D4519
Product name
2,4-Dimethylbenzyl Alcohol
Purity
>98.0%(GC)
Packaging
25g
Price
$380
Updated
2021/12/16
TRC
Product number
D481095
Product name
(2,4-Dimethylphenyl)methanol
Packaging
500mg
Price
$75
Updated
2021/12/16
Biosynth Carbosynth
Product number
FD70069
Product name
2,4-Dimethylbenzyl alcohol
Packaging
5G
Price
$60
Updated
2021/12/16
Frontier Specialty Chemicals
Product number
JK444311
Product name
2,4-Dimethylbenzyl Alcohol
Purity
97%
Packaging
1g
Price
$38
Updated
2021/12/16
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2,4-DIMETHYLBENZYL ALCOHOL Chemical Properties,Usage,Production

Chemical Properties

clear colorless to slightly yellow

Uses

2,4-Dimethylbenzyl alcohol is an aryl alcohol that can be used in the preparation of aldehydes, ketones and esters by oxidation reactions. It is also used in the preparation of thermoplastic polymers.

Synthesis

15764-16-6

16308-92-2

General procedure for the synthesis of (2,4-dimethylphenyl)methanol from 2,4-dimethylbenzaldehyde: To a methanolic solution (100 mL) of 2,4-dimethylbenzaldehyde (10.4 g) was slowly added sodium borohydride (0.83 g) at 0 °C. The reaction mixture was stirred continuously at 0 °C for 1 hour. Upon completion of the reaction, the mixture was concentrated under reduced pressure to remove the solvent. Water was added to the concentrated residue and extracted with ethyl acetate. The combined organic extracts were washed sequentially with saturated aqueous sodium bicarbonate, water and saturated brine to remove impurities. The washed organic layer was dried with anhydrous magnesium sulfate, filtered and concentrated under reduced pressure to give the title compound (2,4-dimethylphenyl)methanol as a colorless oil (yield 10.8 g, quantitative yield). The product was characterized by 1H-NMR (CDCl3) with chemical shifts δ: 1.55 (1H, t, J = 5.4 Hz), 2.31 (3H, s), 2.33 (3H, s), 4.64 (2H, d, J = 5.4 Hz), 6.98-7.00 (2H, m), 7.19-7.22 (1H, m).

References

[1] Patent: EP1787991, 2007, A1. Location in patent: Page/Page column 45
[2] Journal of the Chemical Society, 1907, vol. 91, p. 759
[3] Advanced Synthesis and Catalysis, 2007, vol. 349, # 10, p. 1633 - 1636
[4] Patent: EP1510512, 2005, A1. Location in patent: Page/Page column 5-6
[5] Chemistry Letters, 2010, vol. 39, # 5, p. 500 - 501

2,4-DIMETHYLBENZYL ALCOHOL Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 2,4-DIMETHYLBENZYL ALCOHOL manufacturers

Career Henan Chemical Co
Product
2,4-DIMETHYLBENZYL ALCOHOL 16308-92-2
Price
US $1.00/KG
Min. Order
1g
Purity
99.0%
Supply Ability
100kg
Release date
2020-01-10

16308-92-2, 2,4-DIMETHYLBENZYL ALCOHOLRelated Search:


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