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MAGNESIUM METHOXIDE

Product Name
MAGNESIUM METHOXIDE
CAS No.
109-88-6
Chemical Name
MAGNESIUM METHOXIDE
Synonyms
magnesium methanolate;nesium methoxide;Dimethoxymagnesium;MAGNESIUM METHOXIDE;MAGNESIUM METHYLATE;Manganese()methoxide;MAGNESIUM DIMETHOXIDE;Bis(methoxy)magnesium;methanol,magnesiumsalt;Magnesium bismethoxide
CBNumber
CB7380136
Molecular Formula
C2H6MgO2
Formula Weight
86.37
MOL File
109-88-6.mol
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MAGNESIUM METHOXIDE Property

Density 
0.816 g/mL at 25 °C
vapor pressure 
17kPa at 25℃
refractive index 
n20/D 1.3381
Flash point:
46 °F
solubility 
Chloroform (Soluble), Methanol (Soluble), Water (Soluble)
form 
Liquid
Specific Gravity
0.815
Water Solubility 
Decomposes in water.
Sensitive 
Moisture Sensitive
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
Exposure limits
ACGIH: TWA 200 ppm; STEL 250 ppm (Skin)
OSHA: TWA 200 ppm(260 mg/m3)
NIOSH: IDLH 6000 ppm; TWA 200 ppm(260 mg/m3); STEL 250 ppm(325 mg/m3)
Stability:
Hygroscopic, Moisture sensitive
LogP
0.77 at 20℃
CAS DataBase Reference
109-88-6(CAS DataBase Reference)
EPA Substance Registry System
Methanol, magnesium salt (109-88-6)
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Safety

Hazard Codes 
F,T
Risk Statements 
11-23/24/25-39/23/24/25-36/38
Safety Statements 
16-36/37-45-26
RIDADR 
UN 3274 3/PG 2
WGK Germany 
1
TSCA 
Yes
HazardClass 
3
PackingGroup 
II
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H314Causes severe skin burns and eye damage

H370Causes damage to organs

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
335657
Product name
Magnesium methoxide solution
Purity
6-10wt. % in methanol
Packaging
500ml
Price
$90.5
Updated
2024/03/01
Sigma-Aldrich
Product number
335657
Product name
Magnesium methoxide solution
Purity
6-10wt. % in methanol
Packaging
2l
Price
$143
Updated
2024/03/01
Alfa Aesar
Product number
040448
Product name
Magnesium methoxide, 7-8% in methanol
Packaging
1kg
Price
$61.9
Updated
2024/03/01
Alfa Aesar
Product number
040448
Product name
Magnesium methoxide, 7-8% in methanol
Packaging
2kg
Price
$76.65
Updated
2024/03/01
Alfa Aesar
Product number
040448
Product name
Magnesium methoxide, 7-8% in methanol
Packaging
250g
Price
$23.7
Updated
2024/03/01
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MAGNESIUM METHOXIDE Chemical Properties,Usage,Production

Uses

The use of magnesium methoxide for the deprotection of alkyl esters is described. This mild reagent provides a good method to cleave esters efficiently and more importantly, allows for effective differentiation between two different esters. Dimethyl carbonate is synthesized directly from carbon dioxide and methanol in the presence of magnesium methoxide. 20 mol% DEA additions to magnesium methoxide showed enhanced stability such that a time-dependent change in the sol was not observed in air. Also enhanced the crystallization process.

Preparation

Magnesium Methoxide is prepared by addition of small batches of Magnesium metal to anhydrous MeOH.[1]

General Description

Magnesium Methoxide is a weakly basic metal alkoxide; forms stable chelates with enolizable carbonyl compounds.

Flammability and Explosibility

Flammable

reaction suitability

core: magnesium

storage

Magnesium Methoxide uses same precautions as for other metal alkoxides (see Potassium t-Butoxide); avoid contact with eyes and clothing; handle and conduct reactions under an inert atmosphere. For critical experiments, it is recommended that the reagent be freshly prepared. Use in a fume hood.

References

1. FF 1969, 2, 255.

MAGNESIUM METHOXIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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MAGNESIUM METHOXIDE Suppliers

Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57505
Advantage
58
Riedel-de Haen AG
Tel
--
Fax
--
Country
United States
ProdList
6773
Advantage
87
American Custom Chemicals Corporation
Tel
--
Fax
--
Email
sales@acccorporation.com
Country
United States
ProdList
6820
Advantage
51
Pfaltz & Bauer, Inc.
Tel
--
Fax
--
Email
sales@pfaltzandbauer.com
Country
United States
ProdList
6828
Advantage
72
MP Biomedicals, Inc.
Tel
--
Fax
--
Country
United States
ProdList
6561
Advantage
81
Alfa Aesar
Tel
--
Fax
--
Email
tech@alfa.com
Country
United States
ProdList
6814
Advantage
81
ProChem, Inc.
Tel
--
Fax
--
Email
prochem1@aol.com
Country
United States
ProdList
1691
Advantage
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Gelest, Inc.
Tel
--
Fax
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Email
info@gelest.com
Country
United States
ProdList
3973
Advantage
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View Lastest Price from MAGNESIUM METHOXIDE manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Magnesium Methoxide 109-88-6
Price
US $120.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-11
Hebei Mujin Biotechnology Co.,Ltd
Product
MAGNESIUM METHOXIDE 109-88-6
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-09-01
Hebei Weibang Biotechnology Co., Ltd
Product
MAGNESIUM METHOXIDE 109-88-6
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-19

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