(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY

Reaction

Product Name: (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY
CAS No.: 656233-53-3
Chemical Name: (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY
Synonyms: (S)-SHIP;(R)-SHIP;1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY;PHENYL-[(S)-1,1-SPIROBIINDANE-7,7-DIYL]-PHOSPHITE;PHENYL-[(R)-1,1-SPIROBIINDANE-7,7-DIYL]-PHOSPHITE;Phenyl-[(R)-1,1-spirobiindane-7,7-diyl]-phosphite ,97%;Phenyl-[(R)-1,1′-spirobiindane-7,7′-diyl]-phosphite((R)-ShiP);12-phenoxy-4,5,6,7-tetrahydroiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine;(R)-12-phenoxy-4,5,6,7-tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine;(11aR)-10,11,12,13-Tetrahydro-5-phenoxy-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin
CBNumber: CB7382271
Molecular Formula: C23H19O3P
Formula Weight: 374.37
MOL File: 656233-53-3.mol

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(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY Property

Melting point:: 104-106°C
Boiling point:: 454.8±45.0 °C(Predicted)
alpha: +216° (c 0.5, CH2Cl2)
storage temp.: -20°C, protect from light, stored under nitrogen
form: solid
color: white
Sensitive: moisture sensitive

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Safety

Hazard Codes: Xn
Risk Statements: 22

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P330Rinse mouth.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Strem Chemicals

Product number: 15-5156
Product name: (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy, min. 98% (R)-ShiP
Packaging: 100mg
Price: $113
Updated: 2022/04/27

Strem Chemicals

Product number: 15-5156
Product name: (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy, min. 98% (R)-ShiP
Packaging: 500mg
Price: $452
Updated: 2022/04/27

American Custom Chemicals Corporation

Product number: ING0001117
Product name: (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY
Purity: 95.00%
Packaging: 50MG
Price: $614.87
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: ING0001117
Product name: (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY
Purity: 95.00%
Packaging: 250MG
Price: $821.64
Updated: 2021/12/16

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(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY Chemical Properties,Usage,Production

Reaction

Chiral ligands for rhodium-catalyzed arylation of aldehydes with arylboronic acids.
Chiral ligands for rhodium-catalyzed arylation of imines with arylboronic acids.
Chiral ligands for rhodium-catalyzed arylation of α-ketoesters with arylboronic acids.
Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes.
Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of (Z)-β-arylenamides.

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY Preparation Products And Raw materials

Raw materials

CALCIUM HYDRIDE Benzyl chloride Ethanol Acetone Sodium bromide Methanesulfonic acid Hydrogen peroxide Toluene Phenol N,N-Diisopropylethylamine Nickel Cinchonidine Triethylamine Boron tribromide Palladium 3-Hydroxybenzaldehyde Phosphorus trichloride (R)-1,1'-SPIROBIINDANE-7,7'-DIOL Tetrahydrofuran Ethyl acetate Hydrochloric acid Sodium bicarbonate Hydrogen Dichloromethane Sodium hydroxide PETROLEUM ETHER (S)-1,1'-SPIROBIINDANE-7,7'-DIOL

Preparation Products

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(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY Suppliers

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656233-53-3, (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXYRelated Search:

Indacaterol Triphenyl phosphite (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY 2-Pyridinemethanamine, N-[(1aS,4aS,9bS)-10-[bis[3,5-bis(1,1-dimethylethyl)phenyl]phosphino]-1a,2,3,4,4a,5-hexahydro-1H-indeno[2,1-d]fluoren-9-yl]-3-methyl- 2-Pyridinemethanamine, N-[(1S)-7'-[bis[3,5-bis(1,1-dimethylethyl)phenyl]phosphino]-2,2',3,3'-tetrahydro-1,1'-spirobi[1H-inden]-7-yl]-3-methyl-

(R)-SHIP

(S)-SHIP

PHENYL-[(R)-1,1-SPIROBIINDANE-7,7-DIYL]-PHOSPHITE

PHENYL-[(S)-1,1-SPIROBIINDANE-7,7-DIYL]-PHOSPHITE

(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy,min.98%(R)-ShiP

Phenyl-[(R)-1,1-spirobiindane-7,7-diyl]-phosphite, (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1μ,7μ-fg][1,3,2]dioxaphosphocin-5-phenoxy

(11AS)-(-)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY

1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY

Phenyl-[(R)-1,1-spirobiindane-7,7-diyl]-phosphite ,97%

(11aR)-10,11,12,13-Tetrahydro-5-phenoxy-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin,99%e.e.

Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin, 10,11,12,13-tetrahydro-5-phenoxy-, (11aR)-

Phenyl-[(R)-1,1′-spirobiindane-7,7′-diyl]-phosphite((R)-ShiP)

12-phenoxy-4,5,6,7-tetrahydroiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine

(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1'',7''-fg][1,3,2]dioxaphosphocin-5-phenoxy

(11aR)-10,11,12,13-Tetrahydro-5-phenoxy-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin

11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY

(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy, min. 98% (R)-ShiP

(11aR)-10,11,12,13-Tetrahydro-5-phenoxy-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin

(R)-12-phenoxy-4,5,6,7-tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocine

656233-53-3