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ChemicalBook > CAS DataBase List > Bromodiphenylmethane

Bromodiphenylmethane

Uses
Product Name
Bromodiphenylmethane
CAS No.
776-74-9
Chemical Name
Bromodiphenylmethane
Synonyms
(bromomethylene)Dibenzene;BENZHYDRYL BROMIDE;1-Benzyl-2-broMobenzene;DIPHENYLBROMOMETHANE;CL048;Bromodiphenyl;pha-BromodiphenyL;Bromodiphenylmethan;BROMODIPHENYLMETHANE;DIPHENYLMETHYL BROMIDE
CBNumber
CB7481460
Molecular Formula
C13H11Br
Formula Weight
247.13
MOL File
776-74-9.mol
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Bromodiphenylmethane Property

Melting point:
35-39 °C(lit.)
Boiling point:
184 °C20 mm Hg(lit.)
Density 
0,9 g/cm3
refractive index 
1.6290 (estimate)
Flash point:
>230 °F
storage temp. 
Store below +30°C.
solubility 
0.45g/l
form 
powder to lump to clear liquid
color 
White to cream to yellow to orange to brown crystals or fused solid
PH
2 (H2O, 20℃)(saturated aqueous solution)
Water Solubility 
Insoluble
Sensitive 
Moisture Sensitive
BRN 
638544
CAS DataBase Reference
776-74-9(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1,1'-(bromomethylene)bis-(776-74-9)
EPA Substance Registry System
Benzene, 1,1'-(bromomethylene)bis- (776-74-9)
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Safety

Hazard Codes 
C
Risk Statements 
34-37
Safety Statements 
26-36/37/39-45
RIDADR 
UN 1770 8/PG 2
WGK Germany 
3
RTECS 
PA5350000
19-21
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
29036990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P309IF exposed or if you feel unwell:

P310Immediately call a POISON CENTER or doctor/physician.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
B0586
Product name
α-Bromodiphenylmethane
Packaging
25G
Price
$40
Updated
2024/03/01
TCI Chemical
Product number
B0586
Product name
α-Bromodiphenylmethane
Packaging
100G
Price
$101
Updated
2024/03/01
Alfa Aesar
Product number
L02211
Product name
Benzhydryl bromide, 90+%
Packaging
25g
Price
$26.65
Updated
2024/03/01
Alfa Aesar
Product number
L02211
Product name
Benzhydryl bromide, 90+%
Packaging
100g
Price
$59.65
Updated
2024/03/01
TCI Chemical
Product number
B0586
Product name
α-Bromodiphenylmethane
Packaging
500G
Price
$353
Updated
2024/03/01
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Bromodiphenylmethane Chemical Properties,Usage,Production

Uses

Benzhydryl Bromide is used as a reagent in the synthesis of O-(triazolyl)methyl carbamates as a novel and potent class of fatty acid amide hydrolase (FAAH) inhibitors.

Chemical Properties

ORANGE-RED TO ORANGE-BROWN LOW MELTING SOLID

Uses

Benzhydryl bromide is a halogenated building block. Benzhydryl group was preferred to the commoner benzyl to protect 2-nitrophenol in the Bartoli (vinyl Grignard) synthesis of 7-hydroxyindole. Protection was by reaction with the phenol in the presence of potassium carbonate in acetone; deprotection of the indole was by hydrogenolysis.

General Description

Bromodiphenylmethane is a white crystalline solid. Melting point 113°F. A lachrymator. In the presence of moisture corrosive to tissue and most metals.

Air & Water Reactions

Insoluble in cold water. Decomposed by hot water to give corrosive hydrobromic acid.

Reactivity Profile

Halogenated aliphatic compounds are moderately or very reactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Materials in this group are incompatible with strong oxidizing and reducing agents. Also, they are incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.

Health Hazard

TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.

Fire Hazard

Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.

Safety Profile

A corrosive, irritating liquid, When heated to decomposition it emits toxic fumes of Br-. See also

Bromodiphenylmethane Preparation Products And Raw materials

Raw materials

Preparation Products

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Bromodiphenylmethane Suppliers

Shanghai Yuqing Chemical Co., Ltd.
Tel
+86-13816254020 +86-18601759286
Fax
13166185202
Email
penny.xu@tianqing-chem.com
Country
China
ProdList
63
Advantage
58
Zhejiang zetian fine chemical co. LTD
Tel
0571-0571-87322520 18957127338
Fax
QQ:800182836
Email
sales@zetchem.com
Country
China
ProdList
451
Advantage
58
Zibo Junlida Chemical Co. , Ltd.
Tel
18560270963
Email
1258536883@qq.com
Country
China
ProdList
360
Advantage
58
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
TAIYUAN RHF CO.,LTD.
Tel
+86 351 7031519
Fax
+86 351 7031519
Email
sales@RHFChem.com
Country
China
ProdList
2341
Advantage
56
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
Beijing dtftchem Technology Co., Ltd.
Tel
010-60275820 13031183356
Fax
010-60270825
Email
elainezt@sina.com
Country
China
ProdList
1392
Advantage
62
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
Capot Chemical Co., Ltd
Tel
+86 (0) 571 85 58 67 18
Fax
0086-571-85864795
Email
sales@capotchem.com
Country
China
ProdList
18217
Advantage
66
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View Lastest Price from Bromodiphenylmethane manufacturers

Henan Fengda Chemical Co., Ltd
Product
Bromodiphenylmethane 776-74-9
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-25
Hebei Duling International Trade Co. LTD
Product
Bromodiphenylmethane 776-74-9
Price
US $25.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000 tons
Release date
2023-01-16
Shaanxi Dideu Medichem Co. Ltd
Product
Bromodiphenylmethane 776-74-9
Price
US $1.33-569.00/Kg
Min. Order
1Kg
Purity
99%
Supply Ability
100000
Release date
2023-03-20

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