ChemicalBook > CAS DataBase List > Triisopropanolamine

Triisopropanolamine

Product Name
Triisopropanolamine
CAS No.
122-20-3
Chemical Name
Triisopropanolamine
Synonyms
TPEA;AMIX TI;Tripropanolamine;Tri-2-propanolamine;Pharmaceutical Intermediate and Research Chemical 122-20-3;AMIX TI 85%;Trisisopropanol;78-96-61,1’,1’’-;Trisopropanolamine;Triisopropanolamin
CBNumber
CB7677311
Molecular Formula
C9H21NO3
Formula Weight
191.27
MOL File
122-20-3.mol
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Triisopropanolamine Property

Melting point:
48-52 °C (lit.)
Boiling point:
190 °C/23 mmHg (lit.)
Density 
1.0
vapor pressure 
1 hPa (100 °C)
refractive index 
1.4200 (estimate)
Flash point:
160 °C
storage temp. 
Store below +30°C.
form 
Crystalline Low Melting Solid
pka
14.37±0.20(Predicted)
color 
White to slightly yellow
PH
10.8 (100g/l, H2O, 20℃)
explosive limit
0.8-5.8%(V)
Water Solubility 
Soluble
FreezingPoint 
52℃
Sensitive 
Hygroscopic
BRN 
1071570
LogP
-0.015 at 23℃
CAS DataBase Reference
122-20-3(CAS DataBase Reference)
NIST Chemistry Reference
2-Propanol, 1,1',1''-nitrilotris-(122-20-3)
EPA Substance Registry System
Triisopropanolamine (122-20-3)
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Safety

Hazard Codes 
Xi
Risk Statements 
36-52/53
Safety Statements 
26-61
RIDADR 
UN 3259 8/PG 2
WGK Germany 
1
RTECS 
UB8750000
Autoignition Temperature
275 °C
TSCA 
Yes
HS Code 
2922 19 00
HazardClass 
8
PackingGroup 
III
Hazardous Substances Data
122-20-3(Hazardous Substances Data)
Toxicity
LD50 orally in Rabbit: 4000 mg/kg LD50 dermal Rabbit 10000 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H319Causes serious eye irritation

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.08236
Product name
1,1′,1"-Nitrilotri-2-propanol
Purity
for synthesis
Packaging
100g
Price
$41
Updated
2024/03/01
Sigma-Aldrich
Product number
8.08236
Product name
1,1′,1"-Nitrilotri-2-propanol
Purity
for synthesis
Packaging
1kg
Price
$45.8
Updated
2024/03/01
Sigma-Aldrich
Product number
8.08236
Product name
1,1′,1"-Nitrilotri-2-propanol
Purity
for synthesis
Packaging
25L
Price
$674
Updated
2024/03/01
Sigma-Aldrich
Product number
254746
Product name
Triisopropanolamine
Purity
95%
Packaging
100g
Price
$40.3
Updated
2024/03/01
Sigma-Aldrich
Product number
254746
Product name
Triisopropanolamine
Purity
95%
Packaging
1kg
Price
$91.2
Updated
2024/03/01
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Triisopropanolamine Chemical Properties,Usage,Production

Description

Triisopropanolamine (TIPA), a tertiary alkanolamine, is majorly used as a grinding chemical that reduces agglomeration in the ball milling process and changes the particle distribution of the finished cement.

Chemical Properties

Triisopropanolamine is a white to slightly yellow crystalline that is almost odorless. It is fully soluble in water.
Triisopropanolamine is a corrosive and hygroscopic solid.

Uses

Triisopropanolamine is used as an emulsifying agent.

Uses

Triisopropanolamine is an amine used for a variety of industrial applications including as an emulsifier, stabilizer, and chemical intermediate. It is also used to neutralize acidic components of some herbicides.
Triisopropanolamine is an aminoalcohol and belongs to the group of alkanolamines. It is majorly used as a grinding chemical that reduces agglomeration in the ball milling process and changes the particle distribution of the finished cement.

Uses

Major applications include water-based coating applications and agricultural products. Additional applications are antistat agents for polymers, corrosion inhibitor, electrodeposition/electrocoating, lubricants, paper, pigment dispersion, plastics, polyurethane additive, reaction intermediates, rubber curing, surfactants, mineral dispersion, and urethanes.

Definition

ChEBI: Triisopropanolamine is an amino alcohol.

Application

Triisopropanolamine (TIPA) can act as an interfacial transition zone (ITZ) to improve the mechanical properties of the mortar and the concrete. It can also be used to increase the compressive strength of the cement-fly ash system by accelerating the hydration of both the compounds.
1. Cement industry - TIPA is commonly used a cement grinding additives. It increases the strength of cement and other mixtures for cement.
2. Metallurgy - TIPA is used as antioxidants and coolant and prevent corrosion in metals.
3. Polyurethane industry - preliminary usage as a agent and catalyst to improve PU quality.
4. Textile industry - TIPA is used as refining agent and other dye specific agent properties.

General Description

White solid with slight odor of ammonia. Denser than water .

Air & Water Reactions

Water soluble

Reactivity Profile

Triisopropanolamine neutralizes acids to form salts plus water in exothermic reactions. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by combination with strong reducing agents, such as hydrides.

Hazard

Irritant to skin and eyes.

Health Hazard

Irritation of eyes and skin. May cause slight corneal injury or burn. Repeated contact may cause skin burn. Heated vapor may cause moderate respiratory irritation. Low to moderately toxic by oral routes.

Flammability and Explosibility

Non flammable

Toxicity evaluation

Diisopropanolamine, Triisopropanolamine, Isopropanolamine, and Mixed Isopropanolamine are used as water-soluble emulsifiers and neutralizers in cosmetic products at concentrations up to 1%. In animal studies these ingredients were slightly toxic to practically nontoxic to rats and guinea pigs via acute oral administration. Triisopropanolamine was relatively nontoxic to rats in the two subchronic oral studies. These ingredients were moderate skin irritants for rabbits. All four ingredients, when tested at 100% concentrations, were severe ocular irritants in rabbits. Products containing small amounts (-1%) of Diisopropanolamine or Triisopropanolamine were not ocular irritants in rabbits. The Triisopropanolamine salt was not mutagenic in Aspergillus nidulans. Diisopropanolamine and Isopropanolamine at concentrations of 2% did not induce allergic contact dermatitis or photoallergic dermatitis in humans. Clinical studies on cosmetic products containing no more than 1% Diisopropanolamine or 1.1% Triisopropanolamine were minimal skin irritant and contact sensitizers. It is concluded that Diisopropanolamine, Triisopropanolamine, Isopropanolamine, and Mixed Isopropanolamine are safe as cosmetic ingredients in the present practices of use and concentration. The Isopropanolamines should not be used in products containing N-nitrosating agents.
Final Report on the Safety Assessment of Diisopropanolamine, Triisopropanolamine, Isopropanolamine, and Mixed Isopropanolamine

Precautions

Hygroscopic. Store away from oxidizing agents, water/moisture. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.

References

Pensri Piboonchaisit, et al. Novel Route to Tris(silatranyloxy-i-propyl)amine Directly from Silica and Triisopropanolamine, Part I.ScienceAsia.1999,25113-119.
Paul J. Sandberg.; F. Doncaster. On the mechanism of strength enhancement of cement paste and mortar with triisopropanolamine.Cem. Concr. Res.2004,34(6), 973-976.

Triisopropanolamine Preparation Products And Raw materials

Raw materials

Propylene oxide

Preparation Products

Triisopropanolamine cyclic borate demulsifier KN-1
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Triisopropanolamine Suppliers

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View Lastest Price from Triisopropanolamine manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Triisopropanolamine TIPA 122-20-3
Price
US $100.00-45.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-04-30
Nanjing Deda New Material Technology Co., Ltd
Product
Triisopropanolamine 122-20-3
Price
US $5.00-1.00/kg
Min. Order
1kg
Purity
99.5
Supply Ability
50 ton per month
Release date
2023-12-06
Hunan aslsen technology co.,ltd
Product
Triisopropanolamine 122-20-3
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 tons
Release date
2024-04-15

122-20-3, TriisopropanolamineRelated Search:

Aluminium isopropoxide Isopropyl alcohol 1-Dimethylamino-2-propanol Amino-2-propanol Triisopropylsilane Triethylenediamine NA Triethanolamine TRIISOPROPANOLAMINE CYCLIC BORATE,Triisopropanolamine cyclic borate, 98+% 5-(TERT-BUTYL)-2-IODO-1,3-DIMETHYLBENZENE 2,6-DICHLOROPHENOLINDOPHENYL ACETATE 1-Propanol 2,4-dichlorophenoxyacetic acid triisopropanolamine salt picloram, triisopropanolamine salt tri-isopropanlamiue polyoxypropyleal polyoxy-ethylene ether Triisopropanolamine Titanium, diethylene glycol ethylene glycol triisopropanolamine complexes Antirust agent A

  • 2-Propanol, 1,1',1''-nitrilotri-
  • AMIX TI 85%
  • (Mixture of isoMer)
  • TriisopropanolaMine&nbsp
  • TriisopropanolaMine, 98% 1KG
  • TriisopropanolaMine, 98% 5GR
  • 1,1',1"-NITRILOTRI-2-PROPANOL FOR SYNTHE
  • TriisopropanolaMine, Mixture of isoMers
  • TriisopropanolaMine, 99.5%
  • TriisopropanolaMine (TIPA)
  • 1,1',1"-Nitrilotri-2-propanol for synthesis
  • Triisopropanolamine, 99%, mixture of isomers
  • 2-Propanol,1,1’,1’’-nitrilotris-
  • 3,3',3 -Nitrilotri(2-propanol)
  • 78-96-61,1’,1’’-
  • 78-96-61,1’,1’’-nitrilotripropan-2-ol
  • 78-96-61,1’,1’’-nitrilotripropan-2-ol/1-aminopropan-2-ol
  • Tri-2-propanolamine
  • Tripropanolamine
  • Tris(2-hydroxy-1-propyl)amine
  • Tris(2-propanol)amine
  • Trisisopropanol
  • Trisopropanolamine
  • Triisopropanolamin
  • Triisopropanolamine (mixture of isomer)
  • 1,1',1"-Nitrilotris(propan-2-ol)
  • 1,1',1''-nitrilotripropan-2-ol triisopropanolamine
  • 1,1μ,1μμ-Nitrilotri(-2-propanol), Tris(2-hydroxypropyl)amine
  • Triisopropanolamine,98%
  • 1,1',1''-Nitrilotris(propane-2-ol)
  • AMIX TI
  • 1,1',1''-NITRILOTRI-2-PROPANOL
  • 1,1',1''-NITRILOTRIPROPAN-2-OL
  • 1,1',1''-NITRILOTRIS(2-PROPANOL)
  • 1,1',1''-NITROLOTRIPROPAN-2-OL
  • TRIS(2-HYDROXYPROPYL)AMINE
  • TRIISOPROPANOLAMINE
  • NITRILOTRIPROPANOL
  • 1,1',1-Nitrilopropan-2-ol
  • 1,1’,1’’-nitrilotri-2-propano
  • 1,1’,1’’-nitrilotris-2-propano
  • Remimazolam Impurity 7
  • TRIISOPROPANOLAMINE, 95%TRIISOPROPANOLAMINE, 95%TRIISOPROPANOLAMINE, 95%
  • Triisopropanolamine(mixtureofisomer)&gt
  • Triisopropanolamine ISO 9001：2015 REACH
  • TPEA
  • Pharmaceutical Intermediate and Research Chemical 122-20-3
  • Remazolam impurity 7
  • 122-20-3
  • C9H21N1O3
  • HOC3H63N
  • CH3CHOHCH23N
  • C9H21NO3
  • Organic Building Blocks
  • Oxygen Compounds
  • Amino Alcohols
  • Building Blocks
  • AMINE