TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]CERIUM(III)
- Product Name
- TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]CERIUM(III)
- CAS No.
- 41836-21-9
- Chemical Name
- TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]CERIUM(III)
- Synonyms
- Ceriumtrisbistrimethylsilylamide;Cerium(3+) bis(trimethylsilyl)amide;Cerium(III) bis(trimethylsilyl)amide;HEXAMETHYLDISILAZANE CERIUM(III) SALT;cerium iii tris(hexamethyldisilazide);bis(trimethylsilyl)azanide,cerium(3+);CERIUM III TRIS[BIS(METHYLSILYLAMIDE)];N,N-BIS(TRIMETHYLSILYLAMINE)CERIUM(III);CERIUM III TRIS(BIS(TRIMETHYLSILYLAMIDE));Tris(bis(trimethylsilyl)amino)cerium(III)
- CBNumber
- CB7680047
- Molecular Formula
- C6H19CeNSi2
- Formula Weight
- 301.51
- MOL File
- 41836-21-9.mol
TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]CERIUM(III) Property
- Melting point:
- 132-140 °C(lit.)
- Boiling point:
- 95-9°C/10-4mmHg
- Flash point:
- 36 °F
- storage temp.
- Flammables + water-Freezer (-20°C)e area
- form
- Powder
- Water Solubility
- Soluble in water, protic solvents.
- Sensitive
- Moisture Sensitive
Safety
- Hazard Codes
- F,C
- Risk Statements
- 11-14/15-34
- Safety Statements
- 16-26-36/37/39-43-45-7/8
- RIDADR
- UN 3396 4.3/PG 2
- WGK Germany
- 3
- TSCA
- No
- HazardClass
- 4.1
- PackingGroup
- III
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Hazard statements
-
H228Flammable solid
H261In contact with water releases flammable gas
H314Causes severe skin burns and eye damage
H318Causes serious eye damage
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P309IF exposed or if you feel unwell:
P310Immediately call a POISON CENTER or doctor/physician.
P402+P404Store in a dry place. Store in a closed container.
N-Bromosuccinimide Price
- Product number
- 044362
- Product name
- Tris[N,N-bis(trimethylsilyl)amide]cerium(III), 98%
- Packaging
- 25g
- Price
- $1553.65
- Updated
- 2024/03/01
TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]CERIUM(III) Chemical Properties,Usage,Production
Chemical Properties
Bright yellow crystalline powder
Uses
Tris[N,N-bis(trimethylsilyl)amide]cerium(III) is used as a reactant for synthesis of amidocerium(IV) oxides, Sterically encumbered N-heterocyclic carbene ligands, Lanthanide imidodiphosphinate complexes with electroluminescent properties, Lanthanide complexes of an oxazoline-phenoxide hybrid chelate. Some of the other applications include it is used as a reactant for One-electron oxidation to produce tetravalent cerium compounds, Addition-elimination reactions across the M-C bond of metal N-heterocyclic carbenes.