Preparation
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Cobalt(II) fluoride

Preparation
Product Name
Cobalt(II) fluoride
CAS No.
10026-17-2
Chemical Name
Cobalt(II) fluoride
Synonyms
difluorocobalt;COBALT FLUORIDE;Cobalt(Ⅱ)fluorde;Cobalt(Ⅱ)fluoride;COBALT DIFLUORIDE;COBALTOUS FLUORIDE;COBALT(II) FLUORIDE;Two cobalt fluoride;COBALT FLUORIDE PINK;cobaltfluoride(cof2)
CBNumber
CB7681660
Molecular Formula
CoF2
Formula Weight
96.93
MOL File
10026-17-2.mol
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Cobalt(II) fluoride Property

Melting point:
1200 °C
Boiling point:
1400 °C
Density 
4.46 g/mL at 25 °C
solubility 
soluble in acid solutions
form 
powder
color 
Pink
Specific Gravity
4.46
Water Solubility 
Soluble in water, alcohol and acetone.
Sensitive 
Hygroscopic
Crystal Structure
Rutile type
crystal system
square
Merck 
14,2440
Space group
P42/mnm
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.46950.46950.31829090900.0701
Exposure limits
ACGIH: TWA 0.02 mg/m3; TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3
Stability:
hygroscopic
CAS DataBase Reference
10026-17-2(CAS DataBase Reference)
EPA Substance Registry System
Cobalt fluoride (CoF2) (10026-17-2)
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Safety

Hazard Codes 
T,C
Risk Statements 
25-34
Safety Statements 
26-36/37/39-45-50A-28A
RIDADR 
UN 2923 8/PG 3
WGK Germany 
3
RTECS 
GG0770000
21
Hazard Note 
Toxic
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
III
HS Code 
28261990
Hazardous Substances Data
10026-17-2(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
236128
Product name
Cobalt(II) fluoride
Purity
powder
Packaging
25g
Price
$112
Updated
2023/06/20
Alfa Aesar
Product number
013074
Product name
Cobalt(II) fluoride, anhydrous, 98%
Packaging
25g
Price
$72.65
Updated
2024/03/01
Alfa Aesar
Product number
013074
Product name
Cobalt(II) fluoride, anhydrous, 98%
Packaging
100g
Price
$225
Updated
2023/06/20
Strem Chemicals
Product number
93-2738
Product name
Cobalt(II) fluoride, anhydrous, 99%
Packaging
10g
Price
$46
Updated
2024/03/01
Strem Chemicals
Product number
93-2738
Product name
Cobalt(II) fluoride, anhydrous, 99%
Packaging
50g
Price
$164
Updated
2024/03/01
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Cobalt(II) fluoride Chemical Properties,Usage,Production

Preparation

Cobalt(II) fluoride is prepared by heating anhydrous cobalt(II) chloride or oxide in a stream of hydrogen fluoride:
CoCl2 + 2HF → CoF2 + 2HCl
CoO + 2HF → CoF2 + 2H2O
Also, cobalt(II) fluoride can be prepared as a tetrahydrate, CoF2•4H2O by dissolving cobalt(II) hydroxide in hydrofluoric acid. The tetrahydrate is then dehydrated to anhydrous fluoride. Elemental fluorine combines with cobalt at 450°C forming mixtures of cobalt(II)–and cobalt(III) fluorides.

Chemical Properties

Rose-red crystals or powder. Soluble in cold water and hydrofluoric acid. Decomposes in hot water. Ammine complexes can be prepared from the hydrate.

Physical properties

Red tetragonal crystal; density 4.46 g/cm3; melts at 1,127°C; vaporizes around 1,400°C; sparingly soluble in water; soluble in warm mineral acids; decomposes in boiling water. Tetrahydrate is red orthogonal crystal; density 2.22 g/cm3; decomposes on heating; soluble in water; di- and trihydrates are soluble in water.

Uses

Cobalt(II) fluoride can be used as a catalyst to alloy metals. It is also used for optical deposition, of which it tremendously improves optical quality. The compound may be used in dental care.

Uses

Catalyst for organic reactions.

General Description

Violet to red solid. Sinks and mixes slowly with water.

Reactivity Profile

Cobalt(II) fluoride is a toxic, light brown crystalline material, when exposed to water Cobalt(II) fluoride forms highly corrosive hydrofluoric acid. When heated to decomposition Cobalt(II) fluoride emits toxic fumes of metallic cobalt and fluorides [Lewis, 3rd ed., 1993, p. 344].

Hazard

Highly toxic.

Health Hazard

INHALATION: Inhalation of dust may cause pulmonary symptoms. EYES: Irritation. SKIN: Skin rashes, dermatitis. INGESTION: Nausea and vomiting caused by local irritation.
LD50 oral (rat): 150 mg/kg

Safety Profile

Poison by ingestion. When heated to decomposition it emits toxic fumes of Co and F-.

Cobalt(II) fluoride Preparation Products And Raw materials

Raw materials

Preparation Products

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Cobalt(II) fluoride Suppliers

Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17770
Advantage
75
Beijing HuaMeiHuLiBiological Chemical
Tel
010-56205725
Fax
010-65763397
Email
waley188@sohu.com
Country
China
ProdList
12335
Advantage
58
9ding chemical ( Shanghai) Limited
Tel
4009209199
Fax
86-021-52271987
Email
sales@9dingchem.com
Country
China
ProdList
22514
Advantage
55
Shanghai Macklin Biochemical Co.,Ltd.
Tel
15221275939 15221275939
Fax
021-50706099
Email
shenlinxing@macklin.cn
Country
China
ProdList
16166
Advantage
55
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51456
Advantage
80
Nanjing Vital Chemical Co., Ltd.
Tel
025-87193546 18652950785
Fax
025-87193546
Email
chemweiao@163.com
Country
China
ProdList
9021
Advantage
60
Shandong Xiya Chemical Co., Ltd.
Tel
4009903999 13395398332
Fax
0539-6365991
Email
sales@xiyashiji.com
Country
China
ProdList
20806
Advantage
60
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View Lastest Price from Cobalt(II) fluoride manufacturers

Career Henan Chemical Co
Product
Cobalt(II) fluoride 10026-17-2
Price
US $1.00/KG
Min. Order
1g
Purity
98%
Supply Ability
200kgs
Release date
2020-01-09

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