ALDICARB-SULFONE

ChemicalBook > CAS DataBase List > ALDICARB-SULFONE

Product Name: ALDICARB-SULFONE
CAS No.: 1646-88-4
Chemical Name: ALDICARB-SULFONE
Synonyms: ALDOXYCARB;UCES;ent4.9;Standak;STANDOK;UC21865;Sulfocarb;STANDAK(R);aldoxycarbe;YangdiMiewei
CBNumber: CB7710151
Molecular Formula: C7H14N2O4S
Formula Weight: 222.26
MOL File: 1646-88-4.mol

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ALDICARB-SULFONE Property

Melting point:: 132-135 °C
Density: 1.3816 (rough estimate)
vapor pressure: 1.2×10^-2 Pa (25 °C)
refractive index: 1.5690 (estimate)
storage temp.: 0-6°C
solubility: DMSO (Slightly), Methanol (Slightly)
Water Solubility: 10 g l^-1 (25 °C)
pka: 13.44±0.46(Predicted)
form: Solid
color: White to Off-White
BRN: 2215242
EPA Substance Registry System: Aldicarb sulfone (1646-88-4)

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Safety

Hazard Codes: T+
Risk Statements: 24-26/28
Safety Statements: 28-36/37-45
RIDADR: 2757
WGK Germany: 3
RTECS: UE2080000
HazardClass: 6.1(a)
PackingGroup: I
Toxicity: duck,LD50,oral,33500ug/kg (33.5mg/kg),Pesticide Manual. Vol. 9, Pg. 18, 1991.

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H400Very toxic to aquatic life

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P262Do not get in eyes, on skin, or on clothing.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 33387
Product name: Aldicarb-sulfone
Purity: PESTANAL
Packaging: 100mg
Price: $171
Updated: 2024/03/01

Cayman Chemical

Product number: 24210
Product name: Aldicarb sulfone
Purity: ≥98%
Packaging: 50mg
Price: $72
Updated: 2024/03/01

Cayman Chemical

Product number: 24210
Product name: Aldicarb sulfone
Purity: ≥98%
Packaging: 25mg
Price: $40
Updated: 2023/06/20

Cayman Chemical

Product number: 24210
Product name: Aldicarb sulfone
Packaging: 100mg
Price: $130
Updated: 2024/03/01

American Custom Chemicals Corporation

Product number: PST0000340
Product name: ALDICARB-SULFONE
Purity: 98.00%
Packaging: 100MG
Price: $750.75
Updated: 2021/12/16

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ALDICARB-SULFONE Chemical Properties,Usage,Production

Description

Aldoxycarb, is also called 2-mesyl-2-methylpropionaldehyde O-methylcarbamoyloxime (IUPAC), the sulfone analog of aldicarb, is also a systemic insecticide effective for control of insects (mainly sucking insect pests such as aphids, leafhoppers, etc.).

Chemical Properties

Aldoxycarb is a carbamate pesticide used mainly as an insecticide and acaricide. It is a white crystalline powder with a slightly sulfurous odor. Aldoxycarb is extremely toxic to wildlife. Aldoxycarb (Aldicarb sulfone) is a breakdown product of aldicarb. Aldoxycarb is a degradate/metabolite of aldicarb produced by the oxidation of the thio-moiety.

Uses

Aldoxycarb is a soil applied systemic oxime carbamate insecticide effective for the control of insects (mainly sucking pests such as aphids, leafhoppers, etc.), mites and nematodes on many field (cotton, maize, etc.) and vegetable crops.

Uses

Aldicarb Sulfone is an analog of Aldicarb (A514650) detected in agricultural products as pesticide residue.

Definition

ChEBI: Aldoxycarb is a sulfone.

General Description

White crystalline solid. Insecticide.

Reactivity Profile

ALDICARB-SULFONE is a carbamate ester. Carbamates are chemically similar to, but more reactive than amides. Like amides they form polymers such as polyurethane resins. Carbamates are incompatible with strong acids and bases, and especially incompatible with strong reducing agents such as hydrides. Flammable gaseous hydrogen is produced by the combination of active metals or nitrides with carbamates. Strongly oxidizing acids, peroxides, and hydroperoxides are incompatible with carbamates.

Health Hazard

Exposures to high levels of aldoxycarb cause adverse health effects and damages the nervous system of humans and laboratory animals. Chemicals that cause adverse health effects in humans and laboratory animals after high levels of exposure may pose a risk of adverse health effects in humans exposed to lower levels over long periods of time. Ingestion and other exposures to the chemical cause various health disorders. The type and severity of symptoms varies depending on the amount of chemical involved and the nature of the exposure. The symptoms include, but are not limited to, eye irritation, skin irritation, dizziness, sweating, malaise, CNS depression, abdominal pain, diarrhea, nausea, vomiting, salivation, headache, ataxia, muscle twitching, muscle weakness, runny nose, tearing eyes, pinpoint pupils or dark vision, wheezing, increased or decreased heart rate, seizures, convulsions, and death. It has not caused any delayed neurotoxicity in animals. The onset of these symptoms is rapid and the severity of symptoms depends on the dose. The immediate cause of death is usually respiratory failure.

Health Hazard

Highly toxic by all routes of exposure;cholinesterase inhibitor; ingestion of 1–3 gmay cause death to adult humans.
LD50 oral (mouse): 20 mg/kg
LD50 inhalation (rat): 140 mg/m³/4 hr
LD50 skin (rabbit): 200 mg/kg.

Agricultural Uses

Insecticide, Acaricide, Nematicide: Used to control honey locust, gall midge and other insects and mites on cotton, potatoes, sugar beets and ornamentals. Applied to the soil by soluble mixture or spikes. Not listed for use in EU countries.

Trade name

ALDICARB SULFONE®; TEMIK SULFONE®; SULFOCARB®; STANDAK®; UC-21865®

Metabolic pathway

Aldoxycarb is the sulfone analogue of aldicarb. It has now been superseded but, because of its close relationship with aldicarb, it is included here. The degradation and metabolic pathway of these two structurally related compounds are consistent with each other. Information on the metabolism of aldoxycarb discussed in this summary is based on results obtained from studies where aldoxycarb was the test substance. Additional information can be obtained from the aldicarb summary. The metabolism of aldoxycarb in soils, plants and animals follow common metabolic pathways which include the hydrolysis and elimination of the oxime carbamate to yield the corresponding oximes and nitriles. These primary metabolites are further degraded via hydrolysis to the corresponding amides and acids. Other reactions also include the hydrolysis/ oxidation of the oxime to the corresponding alcohol, aldehyde and acid. Further degradation to methane sulfonic acid was observed in plants and animals. The metabolic pathways of aldoxycarb are presented in Scheme 1.

Degradation

Aldoxycarb (1) is susceptible to alkaline hydrolysis. It was stable under acidic (pH 5) conditions, slowly degraded (DT₅₀ 82 days) in neutral conditions (pH 7) and rapidly degraded (DT₅₀ 0.8 days) under basic (pH 9) conditions (Andrawes, 1976a). Aldoxycarb oxime (2), aldoxycarb nitrile (3) and methanesulfonic acid (4) were the major hydrolysis products. Aldoxycarb degraded slowly in water under photolytic conditions (xenon lamp) with a half-life of approximately 38 days (Andrawes, 1976b) to yield aldoxycarb nitrile (3) as the major degradation product.

ALDICARB-SULFONE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from ALDICARB-SULFONE manufacturers

Career Henan Chemical Co

Product: Aldicarb (sulfone) 1646-88-4
Price: US $1.00/KG
Min. Order: 1KG
Purity: Min98% HPLC
Supply Ability: g/kg/ton
Release date: 2020-01-29

1646-88-4, ALDICARB-SULFONERelated Search:

DITHIANON Butyraldehyde Butyraldehyde oxime BANOL ENDOSULFAN LACTONE ALDICARB-SULFONE ALDICARB ALDICARB-SULFOXIDE TERT-BUTYL METHYL SULFOXIDE ALDICARB-OXIME Methylthio acetaldoxime isobutyraldehyde oxime ISOPROPYL METHYL SULFONE ALDICARB SULFONE SOLUTION 100UG/ML IN METHANOL 5ML ALDICARB SULFONE SOLUTION 100UG/ML IN METHANOL 1ML ALDICARB SULFONE SOLUTION 100UG/ML IN METHANOL 5X1ML Aldicarb-sulfone D3

ALDICARB-SULFONE PESTANAL<TM>

ENDOSULFAN LACTONE PESTANAL, 100 MG

(1E)-2-Methyl-1-(([(methylamino)carbonyl]oxy)imino)-2-(methylsulfonyl)propane

2-mesyl-2-methylpropionaldehydeo-methylcarbamoyloxime

ALDOXYCARB, 10MG, NEAT

Aldicarb sulfone 10mg [1646-88-4]

Aldoxycarb 10mg [1646-88-4]

UCES

YangdiMiewei

Propanal,2-methyl-w-(methyl-sulfonyl)-O-[(methylamino)carbonyl]oxime

AldicarbSulrone

2-methyl-2-(methylsulfonyl)-propionaldehydo-(methylcarbamoyl)oxime

aldoxycarbe

Carbamic acid, methyl-, O-[[2-methyl-2-(methylsulfonyl)propylidene]amino] deriv.

ent4.9

entai3-29261

Propanal, 2-methyl-2-(methylsulfonyl)-, O-[(methylamino)carbonyl]oxime

Propionaldehyde, 2-methyl-2-(methylsulfonyl)-, O-(methylcarbamoyl)oxime

Standak

Sulfocarb

Temik sulfone

2-METHYL-2-(METHYLSULFONYL)PROPANAL-O-[(METHYLAMINO)CARBONYL]OXIME

2-METHYL-2-(METHYLSULFONYL)-PROPIONALDEHYDE O-(METHYLCARBAMOYL)-OXIME

ALDICARB-SULFONE

ALDICARB SULPHONE

ALDOXYCARB

STANDOK

STANDAK(R)

UC21865

2-methyl-2-(methylsulphonyl)propionaldehyde O-(methylcarbamoyl)oxime

ALDICARB SULFONE(TEMIK SULFONE)

AldicarbSulfoneSolution,2000mg/L,1ml

AldicarbSulfoneSolution,10mg/L,1ml

AldicarbSulfoneSolution,100mg/L,1ml

Aldicarb sulfone Solution in Acetonitrile, 1000μg/mL

Aldicarb sulfone Solution in Methanol, 100μg/mL

Aldicarb sulfone Solution in Methanol, 1000μg/mL

Aldicarb sulfone,Cholinesterase (ChE),inhibit,Inhibitor

Aldicarb-sulfone in Acetone

Aldicarb-sulfone in Methanol

C10080000 Aldicarb-sulfone

1646-88-4

AA to ALPesticides

A-BAlphabetic

Alpha sort

CarbamatesEnvironmental Standards

Insecticides

MetabolitesPesticides&Metabolites

Nematicides

Pesticides

Pesticides&Metabolites