METHYL 4-[(Z)-AMINO(HYDROXYIMINO)METHYL]BENZOATE
- Product Name
- METHYL 4-[(Z)-AMINO(HYDROXYIMINO)METHYL]BENZOATE
- CAS No.
- 65695-05-8
- Chemical Name
- METHYL 4-[(Z)-AMINO(HYDROXYIMINO)METHYL]BENZOATE
- Synonyms
- Methyl 4-(N-hydroxycarbamimidoyl);Methyl 4-(N-hydroxycarbaMiMidoyl)benzoate;methyl 4-(N'-hydroxycarbamimidoyl)benzoate;Methyl 4-[amino(hydroxyimino)methyl]benzoate;Methyl 4-[(hydroxyamino)iminomethyl]benzoate;(E)-Methyl 4-(N'-hydroxycarbaMiMidoyl)benzoate;methyl 4-[(Z)-N'-hydroxycarbamimidoyl]benzoate;METHYL 4-[(Z)-AMINO(HYDROXYIMINO)METHYL]BENZOATE;METHYL 4-[AMINO(HYDROXYIMINO)METHYL]BENZENECARBOXYLATE;4-[(HYDROXYAMINO)IMINOMETHYL]-BENZOIC ACID, METHYL ESTER
- CBNumber
- CB7715095
- Molecular Formula
- C9H10N2O3
- Formula Weight
- 194.19
- MOL File
- 65695-05-8.mol
METHYL 4-[(Z)-AMINO(HYDROXYIMINO)METHYL]BENZOATE Property
- Melting point:
- 172-174
- Boiling point:
- 327.2±44.0 °C(Predicted)
- Density
- 1.28±0.1 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- pka
- 13.88±0.50(Predicted)
- form
- solid
- color
- White
N-Bromosuccinimide Price
- Product number
- M321340
- Product name
- Methyl4-(N-Hydroxycarbamimidoyl)benzoate
- Packaging
- 25mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- 046883
- Product name
- Methyl 4-[amino(hydroxyimino)methyl]-benzenecarboxylate
- Purity
- >95%
- Packaging
- 500mg
- Price
- $92
- Updated
- 2021/12/16
- Product number
- HTS028063
- Product name
- methyl4-[(Z)-amino(hydroxyimino)methyl]benzoate
- Packaging
- 1mg
- Price
- $117
- Updated
- 2021/12/16
- Product number
- 046883
- Product name
- Methyl 4-[amino(hydroxyimino)methyl]-benzenecarboxylate
- Purity
- >95%
- Packaging
- 1g
- Price
- $142
- Updated
- 2021/12/16
- Product number
- 4641-1-01
- Product name
- Methyl 4-[amino(hydroxyimino)methyl]benzoate
- Packaging
- 1g
- Price
- $192
- Updated
- 2021/12/16
METHYL 4-[(Z)-AMINO(HYDROXYIMINO)METHYL]BENZOATE Chemical Properties,Usage,Production
Synthesis
1129-35-7
65695-05-8
General procedure for the synthesis of methyl 4-(N-hydroxyformamidinyl)benzoate (IV) from methyl 4-cyanobenzoate (III): methyl 4-cyanobenzoate (III) (2.50kg, 1wt) was dissolved in methanol (7.5L, 3vol) and diluted with methyl tert-butyl ether (9.3kg, 3.7wt). Aqueous hydroxylamine (50% solution; 1.23 kg, 0.5 wt, 1.2 eq.) was added slowly over about 0.5 h at 20-25 °C. The dosing line was flushed with methanol (1 kg, 0.4 wt) and the reaction was kept at 20-25 °C for about 12 hours. Upon completion of the reaction, the reaction mixture was cooled to 5±5°C and aged at this temperature for 3 hours. The product, methyl 4-(N'-hydroxyformamidinyl)benzoate (IV), was isolated by filtration, washed with methyl tert-butyl ether (2 x 5.5 kg, 2 x 2.2 wt) and dried under a stream of nitrogen for about 4 h to give the product (2.38 kg, 93% yield).
References
[1] Patent: WO2017/220446, 2017, A1. Location in patent: Page/Page column 26
[2] Journal of Labelled Compounds and Radiopharmaceuticals, 2012, vol. 55, # 2, p. 71 - 79
[3] Organic Letters, 2017, vol. 19, # 11, p. 2885 - 2888
METHYL 4-[(Z)-AMINO(HYDROXYIMINO)METHYL]BENZOATE Preparation Products And Raw materials
Raw materials
Preparation Products
METHYL 4-[(Z)-AMINO(HYDROXYIMINO)METHYL]BENZOATE Suppliers
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