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VANADIUM(IV) OXIDE

Description References
Product Name
VANADIUM(IV) OXIDE
CAS No.
12036-21-4
Chemical Name
VANADIUM(IV) OXIDE
Synonyms
VO2;dioxovanadium;VANADIUM OXIDE;Vanadium(Ⅳ)oxide;VANADIUM DIOXIDE;VANADIUM(IV) OXIDE;vanadiumoxide(vo2);Vanadium tetroxide;VANADIUM TETRAOXIDE;Vanadium(IV)dioxide
CBNumber
CB7715136
Molecular Formula
O2V
Formula Weight
82.94
MOL File
12036-21-4.mol
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VANADIUM(IV) OXIDE Property

Melting point:
1967°C
Density 
4.339 g/mL at 25 °C(lit.)
solubility 
insoluble in H2O; soluble in acid solutions, alkaline solutions
form 
Powder
Specific Gravity
4.339
color 
black
Water Solubility 
Insoluble in water.
Crystal Structure
MoO2 type
crystal system
Monoclinic
Space group
P21/c
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.535280.453780.5382590115.208900.1183
Exposure limits
NIOSH: Ceiling 0.05 mg/m3
CAS DataBase Reference
12036-21-4(CAS DataBase Reference)
EPA Substance Registry System
Vanadium oxide (VO2) (12036-21-4)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/38
Safety Statements 
26-37/39
RIDADR 
UN3285
WGK Germany 
3
10-23
HazardClass 
6.1
PackingGroup 
II
HS Code 
28253090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
215821
Product name
Vanadium(IV) oxide
Purity
≥99% trace metals basis
Packaging
5g
Price
$141
Updated
2024/03/01
Sigma-Aldrich
Product number
215821
Product name
Vanadium(IV) oxide
Purity
≥99% trace metals basis
Packaging
20g
Price
$408
Updated
2024/03/01
Alfa Aesar
Product number
022957
Product name
Vanadium(IV) oxide
Purity
99% (metals basis)
Packaging
10g
Price
$89.9
Updated
2024/03/01
Alfa Aesar
Product number
022957
Product name
Vanadium(IV) oxide
Purity
99% (metals basis)
Packaging
50g
Price
$360
Updated
2024/03/01
Strem Chemicals
Product number
93-2309
Product name
Vanadium(IV) oxide, 99+%
Packaging
2g
Price
$39
Updated
2024/03/01
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VANADIUM(IV) OXIDE Chemical Properties,Usage,Production

Description

Vanadium (IV) dioxide is a kind of inorganic compound with its chemical formula being VO2. It can undergo a phase transition at a normal temperature (~66 °C). Its electrical resistivity and opacity can also change several fold. These special properties make it have many applications. For example, it can be used in chemical sensors, energy-conserving coatings, transparent conductors and switching materials. It can also be used as a stationary optical shutter, optical modulators, cameras and data storage. Moreover, it can be applied to the missile guidance system due to its infrared modulation capability. It can also be used to make thin films which have been used in electro-optical switches, micro-optical switch, passive smart radiators and sunshields for spacecraft. It can also be used in phase change computing and memory.

References

https://en.wikipedia.org/wiki/Vanadium(IV)_oxide
https://www.alfa.com/en/catalog/022957/

Chemical Properties

Blue-black powder. Insoluble in water; soluble in alkalies and acids.

Chemical Properties

Vanadium(IV) Oxide (vanadium dioxide, VO2) is a blue-black solid, having a distorted rutile (TiO2) structure. It can be prepared from the reaction of V2O5 at the melting point with sulfur or carbonaceous reductants such as sugar or oxalic acid. The dioxide slowly oxidizes in air. Vanadium dioxide dissolves in acids to give the stable (VO)2+ ions and in hot alkalies to yield vanadate(IV) species, eg, (HV2O5)?.

Uses

Vanadium(IV) oxide is used in chemical sensors, energy-conserving coatings, transparent conductors and switching materials. It acts as a stationary optical shutter, optical modulators, cameras and data storage. As infrared modulators, it is used for the missile guidance systems. Thin films made up of vanadium dioxide find applications in electro-optical switches, micro-optical switch, passive smart radiators and sunshields for spacecraft.

Definition

ChEBI: Vanadium dioxide is a vanadium oxide.

Hazard

Toxic and irritating.

Flammability and Explosibility

Non flammable

VANADIUM(IV) OXIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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VANADIUM(IV) OXIDE Suppliers

GfE Gesellschaft fur Elektrometallurgie mbH
Tel
--
Fax
--
Email
contact@gfe.com
Country
Germany
ProdList
13
Advantage
58
ABCR GmbH & CO. KG
Tel
--
Fax
--
Email
info@abcr.de
Country
Germany
ProdList
6831
Advantage
75
Service Chemical Inc.
Tel
--
Fax
--
Email
sales@chemos-group.com
Country
Germany
ProdList
6350
Advantage
71
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View Lastest Price from VANADIUM(IV) OXIDE manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
VANADIUM(IV) OXIDE 12036-21-4
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-11-01
Hebei Mojin Biotechnology Co., Ltd
Product
VANADIUM(IV) OXIDE 12036-21-4
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-10-16

12036-21-4, VANADIUM(IV) OXIDERelated Search:


  • Vanadium oxide (VO2)
  • vanadiumoxide(vo2)
  • VO2
  • VANADIUM TETRAOXIDE
  • VANADIUM OXIDE
  • VANADIUM(IV) OXIDE
  • VANADIUM DIOXIDE
  • Vanadium(Ⅳ)oxide
  • VANADIUM(IV) OXIDE, 99.9%
  • VANADIUM(IV) OXIDE 98+%
  • VANADIUM (IV) OXIDE 99+%
  • Vanadium(IV)oxide(metalsbasis)
  • Vanadium tetroxide
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  • DivanadiuM tetroxide
  • VanadiuM(IV) oxide 99.9% trace Metals basis
  • Vanadium(IV) oxide >=99% trace metals basis
  • dioxovanadium
  • Vanadium(IV) oxide, 99% (metals basis)
  • Vanadium(IV)dioxide
  • Vanadium (IV) oxide/ 99.5%
  • Vanadium(IV) oxide,Vanadium dioxide
  • Vanadium (IV) oxide, 97% (99%-V)
  • Nano Vanadium Dioxide
  • 99% trace metals basis
  • Vanadium (IV) odide
  • vanadium dioxide nanoparticles
  • 12036-21-4
  • V2O4
  • O2V
  • Vanadium
  • Catalysis and Inorganic Chemistry
  • metal oxide