(1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)

Product Name: (1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)
CAS No.: 361346-80-7
Chemical Name: (1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)
Synonyms: (R)-AMAC;(R,R)-AMAC;(1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II);(1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II);(E)-3-[[(1R,2R)-2-[[(E)-2-acetyl-3-oxidobut-2-enylidene]amino]-1,2-bis(2,4,6-trimethylphenyl)ethyl]iminomethyl]-4-oxopent-2-en-2-olate
CBNumber: CB7717721
Molecular Formula: C32H38CoN2O4
Formula Weight: 573.59
MOL File: 361346-80-7.mol

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(1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) Property

Melting point:: 246-250°C
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
optical activity: [α]/D 291°, c = 0.1 in chloroform

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Safety

Hazard Codes: Xn
Risk Statements: 20/21/22-36/37/38
Safety Statements: 22-24/25-36/37/39
WGK Germany: 2
HS Code: 2942.00.3500

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P308+P313IF exposed or concerned: Get medical advice/attention.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical

Product number: B2314
Product name: (1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II)
Packaging: 100mg
Price: $205
Updated: 2024/03/01

TRC

Product number: B592090
Product name: (1R,2R)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)
Packaging: 50mg
Price: $265
Updated: 2021/12/16

AK Scientific

Product number: 3990AL
Product name: (1R,2R)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)
Packaging: 100mg
Price: $266
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB59944
Product name: (1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II)
Packaging: 25mg
Price: $53
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB59944
Product name: (1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II)
Packaging: 50mg
Price: $92
Updated: 2021/12/16

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(1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) Chemical Properties,Usage,Production

Uses

Schiff base-cobalt complex catalyst for asymmetric borohydride reduction of carbonyl compounds

Catalyst for:

Enantioselective borohydride reduction
Stereoselective preparation of aryl alcohols via asymmetric reduction of aryl ketones with borohydride
Stereoselective borohydride reduction of diketones to diols
Stereoselective preparation of optically active deuterated primary alcohols via enantioselective borodeuteride reduction of aldehydes
Stereoselective preparation of β-hydroxy esters via dynamic kinetic resolution of alkylketo esters with enantioselective borohydride reduction
Chemoselective, diastereoselective, and enantioselective borohydride reduction of 1,3-diketones
Asymmetric synthesis of diarylhydroxypropanones by stereoselective reduction of alkyldiaryldiketones

(1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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(1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) Suppliers

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361346-80-7, (1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)Related Search:

Cobalt (1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) (S)-1-PHENYL-2-(P-TOLYL)ETHYLAMINE 1,2-Diphenylethylenediamine Benzenemethanamine,a,2,4-trimethyl-, (aS)- Benzenemethanamine, α,2,4,6-tetramethyl-, (αS)- (1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) MESO-1,2-BIS(P-TOLYL)ETHYLENEDIAMINE (1R,2R)-1,2-BIS(2,4,6-TRIMETHYLPHENYL)ETHYLENEDIAMINE

(1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)

(R)-AMAC

(R,R)-AMAC

(E)-3-[[(1R,2R)-2-[[(E)-2-acetyl-3-oxidobut-2-enylidene]amino]-1,2-bis(2,4,6-trimethylphenyl)ethyl]iminomethyl]-4-oxopent-2-en-2-olate

(1R,2R)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II)

361346-80-7

Homogeneous Catalysts

Transition Metal Compounds

Classes of Metal Compounds

Metal Complexes

Catalysts for Organic Synthesis

Co (Cobalt) Compounds

Asymmetric Synthesis

Catalysts for Organic Synthesis

Classes of Metal Compounds

Co (Cobalt) Compounds

Homogeneous Catalysts

Metal Complexes

Synthetic Organic Chemistry

Transition Metal Compounds