4-(4-Methoxyphenyl)-2-butanone

Product Name: 4-(4-Methoxyphenyl)-2-butanone
CAS No.: 104-20-1
Chemical Name: 4-(4-Methoxyphenyl)-2-butanone
Synonyms: 4-(4-METHOXYPHENYL)BUTAN-2-ONE;ANISYLACETONE;PARA ANISYL ACETONE;p-Methoxybenzylacetone;4-(P-METHOXYPHENYL)-2-BUTANONE;ANISALACETONE;METHOXY PHENYL BUTANONE;Raspberry ketone methyl ether;1-(4-METHOXYPHENYL)-3-BUTANONE;2-Butanone, 4-(4-methoxyphenyl)-
CBNumber: CB7731013
Molecular Formula: C11H14O2
Formula Weight: 178.23
MOL File: 104-20-1.mol

More

Less

4-(4-Methoxyphenyl)-2-butanone Property

Melting point:: 8 °C (lit.)
Boiling point:: 152-153 °C/15 mmHg (lit.)
Density: 1.046 g/mL at 25 °C (lit.)
vapor pressure: 9-2000Pa at 20-115℃
FEMA: 2672 | 4-(P-METHOXYPHENYL)-2-BUTANONE
refractive index: n20/D 1.519(lit.)
Flash point:: >230 °F
storage temp.: Sealed in dry,Room Temperature
solubility: Chloroform (Slightly), Methanol (Slightly)
form: Oil
color: A colourless oily liquid with a sweet floral odour
Odor: at 100.00 %. sweet dried raspberry rose cherry fruity cassie absolute
Odor Type: berry
Water Solubility: Not miscible in water.
JECFA Number: 818
BRN: 1869592
LogP: 2 at 23.1℃
CAS DataBase Reference: 104-20-1(CAS DataBase Reference)
NIST Chemistry Reference: 2-Butanone, 4-(4-methoxyphenyl)-(104-20-1)
EPA Substance Registry System: 2-Butanone, 4-(4-methoxyphenyl)- (104-20-1)

More

Less

Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 23-24/25
WGK Germany: 2
RTECS: EL9085500
TSCA: Yes
HS Code: 29145090
Toxicity: Both the acute oral LD₅₀ value in rats and the acute dermal LD₅₀ value in rabbits exceeded 5 g/kg (Russell, 1973)

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P233Keep container tightly closed.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304IF INHALED:

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P340Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P362Take off contaminated clothing and wash before reuse.

P403Store in a well-ventilated place.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: W267201
Product name: 4-(4-Methoxyphenyl)-2-butanone
Purity: ≥98%, FCC, FG
Packaging: sample-k
Price: $54.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: W267201
Product name: 4-(4-Methoxyphenyl)-2-butanone
Purity: ≥98%, FCC, FG
Packaging: 100g
Price: $59.1
Updated: 2024/03/01

Sigma-Aldrich

Product number: W267201
Product name: 4-(4-Methoxyphenyl)-2-butanone
Purity: ≥98%, FCC, FG
Packaging: 1kg
Price: $99.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: W267201
Product name: 4-(4-Methoxyphenyl)-2-butanone
Purity: ≥98%, FCC, FG
Packaging: 5kg
Price: $424
Updated: 2024/03/01

Sigma-Aldrich

Product number: M19600
Product name: 4-(4-Methoxyphenyl)-2-butanone
Purity: 98%
Packaging: 10g
Price: $16.74
Updated: 2024/03/01

More

Less

4-(4-Methoxyphenyl)-2-butanone Chemical Properties,Usage,Production

Description

4-(p-Methoxyphenyl)-2-butanone has an intensely sweet, floral, fruity odor and a cherry-raspberry flavor at low concentrations. May be prepared by condensing acetone with anisaldehyde to yield anisylidene acetone and subsequent hydrogenation in the presence of Pd catalyst.

Chemical Properties

4-(p-Methoxyphenyl)-2-butanone has an intensely sweet, floral,fruity odor and cherry–raspberry flavor at low concentrations.

Chemical Properties

4-(4-Methoxyphenyl)-2-butanone is a clear colourless to pale yellow liquid. B.P. 277℃. Solidifies in the cold, melts again at 10℃. Very slightly soluble in water, soluble in alcohol and oils, poorly soluble in Propylene glycol. Intensely sweet, floral and slightly fruity, Cherry-preserve-like odor of good tenacity. It has considerable resemblance to Heliotropine in its overall performance in a composition. Pleasant, sweet-fruity, Cherry-Raspberry-type flavor at concentrations below 40 ppm. Tends to appear "perfumey" at levels higher than 100 ppm.

Occurrence

Contained (approximately 53% level) in the odorous principle obtained by extraction and hydrolysis from aloe wood (Aquilaria algallocha Roxb.) and in anise.

Uses

4-(4-Methoxyphenyl)-2-butanone is used as pharmaceutical intermediate.

Uses

4-(4-Methoxyphenyl)-2-butanone is used in insect attractants, organic synthesis, flavoring. This ketone, a methylether of a very popular material (see para-Hydroxy phenylbutanone), finds use in perfume compositions as a modifier for Heliotropine, a sweetener for Cyclamen aldehyde, and a blender in many types of sweet florals, Fougeres, Oriental fragrances, etc. It suffers from the drawback of being considerably more expensive than Heliotropine, and it can therefore not truly be classified as a substitute for that material. It shows less tendency of discoloration in combination with the materials normally causing such trouble with Heliotropine. It is also used in flavor compositions, particularly in Raspberty and Cherry, two flavors which are commonly used as targets for fantasy fragrances for Iipst ick perfumes. As a sweetener, it modifies Anise and Anethole in licorice flavor compositions, and it is generally used in smaller amounts in many imitation fruit flavors for baked goods or hard candy, where heat stability is essential.

Preparation

By condensing acetone with anisaldehyde to yield anisylidene acetone and subsequent hydrogenation in the presence of Pd catalyst. It can also be prepared from Methyl vinyl ketone by catalytic condensation with Phenol, followed by Methylation.

Definition

ChEBI: 4-(4-Methoxyphenyl)-2-butanone is a member of methoxybenzenes.

Aroma threshold values

Aroma characteristics at 5.0%: sweet, fruity, woody, powdery, honey, vanilla, raspberry and ionone-like.

Taste threshold values

Taste characteristics at 40 ppm: floral, woody, ionone, raspberry, fruity, spice and berry.

Synthesis Reference(s)

Tetrahedron Letters, 33, p. 951, 1992 DOI: 10.1016/S0040-4039(00)91585-5

Safety Profile

Low oral and skin toxicity. A flammable liquid. When heated to decomposition it emits acrid smoke and irritating fumes.

4-(4-Methoxyphenyl)-2-butanone Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

4-(4-Methoxyphenyl)-2-butanone Suppliers

Americas 1 Australia 1 Belgium 1 China 227 Europe 3 France 3 Germany 9 India 25 Ireland 2 Italy 2 Japan 6 Russia 1 Singapore 1 Slovakia 1 South Korea 2 Spain 2 Switzerland 2 Ukraine 1 United Kingdom 16 United States 70 Global 376

Jiangyin Baoyuan Chemical Co.,Ltd

Tel: 0510-86326538 13915249541
Email: 395368097@qq.com
Country: China
ProdList: 10
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 94657
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44688
Advantage: 61

Nanjing Chemlin Chemical Co., Ltd

Tel: 025-83697070
Fax: +86-25-83453306
Email: info@chemlin.com.cn
Country: China
ProdList: 19182
Advantage: 64

Shanghai Hanhong Scientific Co.,Ltd.

Tel: 021-54306202 13764082696
Email: info@hanhongsci.com
Country: China
ProdList: 42958
Advantage: 64

Chemsky（shanghai）International Co.,Ltd.

Tel: 021-50135380
Email: shchemsky@sina.com
Country: China
ProdList: 32321
Advantage: 50

jiliang chemicals

Tel: 21-62165282 15801962796;
Fax: 021 61153784
Email: bidingchem@163.com
Country: China
ProdList: 1199
Advantage: 60

More

Less

View Lastest Price from 4-(4-Methoxyphenyl)-2-butanone manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd

Product: 4-(4-Methoxyphenyl)-2-butanone 104-20-1
Price: US $45.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20 tons
Release date: 2024-12-09

Hebei Weibang Biotechnology Co., Ltd

Product: 4-(4-Methoxyphenyl)-2-butanone 104-20-1
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-11-28

Shandong Deshang Chemical Co., Ltd.

Product: 4-(4-Methoxyphenyl)-2-butanone 104-20-1
Price: US $9.30-7.20/kg
Min. Order: 1kg
Purity: 99.99%
Supply Ability: 10 tons
Release date: 2024-06-21

104-20-1, 4-(4-Methoxyphenyl)-2-butanoneRelated Search:

4-Methyl-2-pentanone Geranylacetone 2-Butanone Thiophanate-methyl Acetylacetone 2-Butanone oxime p-Anisaldehyde Anise oil o-Dianisidine 4-Methoxybenzyl alcohol Benzylacetone Piperonyl acetone Methyl salicylate (+-) 1-BROMO-2-METHYLBUTANE 95 Methyl 2',6'-DIHYDROXY-4,4'-DIMETHOXYDIHYDROCHALCONE 7-Methoxy-2-tetralone 6,7-Dimethoxy-2-tetralone

2-Butanone, 4-(p-methoxyphenyl)-

4-(4-

4-(4-methoxyphenyl)-2-butanon

4-(4-methoxyphenyl)butan-2

4-(P-METHOXYPHENYL)-2-BUTANONE 98+% F&

2-Butanone, 4-(4-methoxyphenyl)-

P-METHOXY PHENYL BUTANONE

PARA ANISYL ACETONE

RASPBERRYKETONEMETHYLESTER

4-(PARA-METHOXYPHENYL)BUTAN-2-ONE

4-(4-Methoxyphenyl)butan-2-on

FRAMBINONMETHYLAETHER

4-(p-Methoxyphenyl)butan-2-one

Raspberry ketone methyl ether

4-(4-METHOXYPHENYL)-2-BUTANONE WITH GC

4-Methoxyphenethylmethyl ketone

Methyl(4-methoxyphenethyl) ketone

4-(4-Methoxyphenyl)-2-butanone,98%

P-METHOXY PHENYL BUTANONE, NATURAL

Anisylacetone 4-Methoxybenzylacetone

4-(4-Methoxyphenyl)Butanone

4-(4-Methoxyphenyl)-2-butanoneFCC Grade, ≥ 98% (GC)

1'',1''']quaterphenyl

2',3,4-Trifluoro-4'''-pentyl-[1,1'

METHOXY PHENYL BUTANONE

ANISYLACETONE

ANISALACETONE

BUTANONE, 4-(P-METHOXYPHENYL)-2-

FEMA 2672

1-(P-METHOXYPHENYL)-3-BUTANONE

1-(4-METHOXYPHENYL)-3-BUTANONE

4-METHOXYBENZYLACETONE

4-ANISYLACETONE

4-(PARA METHOXYPHENYL)-2-BUTANONE

4-(P-METHOXYPHENYL) BUTANONE

4-(P-METHOXYPHENYL)-2-BUTANONE

4-(P-METHOXYPHENYL)-3-BUTAN-2-ONE

4-(4'-METHOXYPHENYL)-2-BUTANONE

4-(4-METHOXYPHENYL)-2-BUTANONE

4-(4-METHOXYPHENYL)BUTAN-2-ONE

4-(p-methoxyphenyl)-2-butanon

ENT 20,279

ent20,279

p-Methoxybenzylacetone

4-(4-Methoxyphenyl)-2-butanone&gt

Dobutamine HCl EP Impurity E

4-(4-Methoxyphenyl)-2-butanone USP/EP/BP

Para Anisyl Acetone (FRAMBINONE METHYL ETHER)

Dobutamine Impurity E

4-(4-Methoxyphenyl)-2-butanone 104-20-1

Dobutamine EP Impurity E HCl

PARA METHOXY BENZYL ACETONE / PARA ANISYL ACETONE

Dobutamine E

104-20-1

CH3OC6H4CH22COCH3

CH3OC6H4CH2CH2COCH3

Organic Building Blocks

Ketones