O-ALLYLHYDROXYLAMINE HYDROCHLORIDE

ChemicalBook > CAS DataBase List > O-ALLYLHYDROXYLAMINE HYDROCHLORIDE

O-ALLYLHYDROXYLAMINE HYDROCHLORIDE

Product Name: O-ALLYLHYDROXYLAMINE HYDROCHLORIDE
CAS No.: 38945-21-0
Chemical Name: O-ALLYLHYDROXYLAMINE HYDROCHLORIDE
Synonyms: (Allyloxy)amine hydrochloride;O-ALLYHYDROXYAMINE HYDROCHLORIDE);O-ALLYLHYDROXYLAMINE HYDROCHLORIDE;3-(Aminooxy)prop-1-ene hydrochloride;O-Allylhydroxylamine Hydrochloride >O-prop-2-enylhydroxylamine hydrochloride;O-(2-PROPENYL)HYDROXYLAMINE HYDROCHLORIDE;O-Allylhydroxylamine Hydrochloride;HydroxylaMine, O-2-propenyl-, hydrochloride;O-Allylhydroxylamine hydrochloride >=98.0% (AT)
CBNumber: CB7738618
Molecular Formula: C3H8ClNO
Formula Weight: 109.55
MOL File: 38945-21-0.mol

Less

O-ALLYLHYDROXYLAMINE HYDROCHLORIDE Property

Melting point:: ~170 °C (dec.)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: powder to crystal
color: White to Almost white
BRN: 3552394
InChIKey: XIQUJVRFXPBMHS-UHFFFAOYSA-N

Less

Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
F: 3-9
HS Code: 2928009090

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 05983
Product name: O-Allylhydroxylamine hydrochloride
Purity: ≥98.0% (AT)
Packaging: 5g
Price: $96.1
Updated: 2024/03/01

Sigma-Aldrich

Product number: 05983
Product name: O-Allylhydroxylamine hydrochloride
Purity: ≥98.0% (AT)
Packaging: 25g
Price: $322
Updated: 2023/06/20

TCI Chemical

Product number: A1449
Product name: O-Allylhydroxylamine Hydrochloride
Purity: >98.0%(T)
Packaging: 1g
Price: $90
Updated: 2024/03/01

TCI Chemical

Product number: A1449
Product name: O-Allylhydroxylamine Hydrochloride
Purity: >98.0%(T)
Packaging: 5g
Price: $306
Updated: 2024/03/01

TRC

Product number: A556543
Product name: O-Allylhydroxylamine Hydrochloride
Packaging: 100mg
Price: $75
Updated: 2021/12/16

Less

O-ALLYLHYDROXYLAMINE HYDROCHLORIDE Chemical Properties,Usage,Production

Preparation

To a solution of 86.8 gm (1.55 moles) of potassium hydroxide in 330 ml of absolute ethanol is added a solution of 159 gm (1.52 moles) of ethyl N-hydroxycarbamate in 330 ml of absolute ethanol. With external cooling to maintain an internal temperature of 25°C to this mixture is added 195.5 gm (1.62 moles) of allyl bromide. After the addition has been completed, the mixture is heated under reflux for 2 hr. After separating the potassium bromide formed during the reaction and washing it with absolute alcohol, the alcoholic solution is evaporated under reduced pressure. The residue is dissolved in ether and then the ether solution is extracted repeatedly with 10% aqueous sodium hydroxide solution. [From the ether solution, on evaporation 25.5 gm (18%) of ethyl N,O-diallylhydroxycar-bamate, b.p. 91-92°C (8.55 mm Hg) may be isolated.] The aqueous extract is acidified with 10% aqueous sulfuric acid and the ethyl O-allylhy-droxycarbamate is extracted with ether. Upon evaporating the ether off, 134.2 gm (61%) of the intermediate product, b.p. 107°C (12.5 mm Hg), is isolated.
In a steam distillation apparatus, 134 gm of ethyl O-allylhydroxy-carbamate is treated with a solution of 120 gm of potassium hydroxide in 280 ml of water. The product is steam-distilled into a receiver containing dilute hydrochloric acid.
The steam distillate is evaporated under reduced pressure. The residue is taken up twice in absolute ethanol and dried by evaporation under reduced pressure. The yield is 91 gm (55%, overall), m.p. 169-170°C. Upon recrystallization from absolute alcohol and dry ether, the melting point is raised to 170.6-170.8°C (172-174°C). Free O-allylhydrox-ylamine has the following reported properties: b.p. 98-99°C, n²⁵_D 1.4300.
The problems connected with the preparation of O-arylhydroxylamines by this method have been attributed to the instability of the aryl- substituted aminooxy group to the hydrolytic system used in its preparation. This problem has recently been circumvented by substituting for ethyl N-hydroxycarbamate, t-butyl N-hydroxycarbamate.

O-ALLYLHYDROXYLAMINE HYDROCHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

Less

O-ALLYLHYDROXYLAMINE HYDROCHLORIDE Suppliers

Americas 1 China 105 Europe 1 Germany 1 India 4 Japan 1 Switzerland 1 United Kingdom 3 United States 11 Global 128

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006608290; 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40241
Advantage: 62

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24539
Advantage: 81

Shanghai Longsheng chemical Co.,Ltd.

Tel: 021-58099652-8005 13585536065
Fax: 021-58099609
Email: bin.wu@shlschem.com
Country: China
ProdList: 9816
Advantage: 59

XiaoGan ShenYuan ChemPharm co,ltd

Tel: 0712-0712-2580635 15527768850
Email: 1791901229@qq.com
Country: China
ProdList: 8849
Advantage: 52

Syntechem Co.,Ltd

Tel
Fax: E-Mail Inquiry
Email: info@syntechem.com
Country: China
ProdList: 12990
Advantage: 57

Zhengzhou Kingsfine Chemical Co., Ltd.

Tel: 0371-56632527 13838252817
Fax: 0371-56635027
Email: sales@kingsfine.com
Country: China
ProdList: 100
Advantage: 62

Beijing Taiya Jie Technology Development Co., Ltd.

Tel: 021-33690831-8001 13552411790
Fax: 021-33690831
Email: postmaster@tyjchem.cn
Country: China
ProdList: 1542
Advantage: 55

Hangzhou Sage Chemical Co., Ltd.

Tel: +86057186818502 13588463833
Fax: Pls mail us for more information!
Email: info@sagechem.com
Country: China
ProdList: 10269
Advantage: 58

Shanghai T&W Pharmaceutical Co., Ltd.

Tel: +86 21 61551611
Fax: +86 21 50676805
Country: China
ProdList: 9901
Advantage: 58

9ding chemical ( Shanghai) Limited

Tel: 4009209199
Fax: 86-021-52271987
Email: sales@9dingchem.com
Country: China
ProdList: 22519
Advantage: 55

Shanghai Aladdin Bio-Chem Technology Co.,LTD

Tel: 18521735133 18521732826;
Fax: 021-50323701
Email: market@aladdin-e.com
Country: China
ProdList: 25015
Advantage: 65

Shanghai Medpep Co., Ltd

Tel: 021-65566949 13901795941
Fax: 86-21-51861665
Email: market@medpep.com
Country: China
ProdList: 176
Advantage: 66

Chengdu AstaTech Trading Co., Ltd./AstaTech (Chengdu) Pharma. Co., Ltd.

Tel: +86-28-85122536 85324413
Fax: +86-28-85326443
Email: market@astatech.cn
Country: China
ProdList: 8033
Advantage: 55

Bide Pharmatech Ltd.

Tel: 400-1647117 15221909166
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 41438
Advantage: 60

Shanghai DiBai Chemicals Co., Ltd.

Tel: 021-54359730 400-008-9730
Fax: 021-54353864
Email: info@chemxyz.com
Country: China
ProdList: 3993
Advantage: 60

Shanghai Worldyang Chemical Co.,Ltd.

Tel: 021-021-56795766
Fax: +86-21-56795266
Email: sales@worldyachem.com
Country: China
ProdList: 9352
Advantage: 58

Ningbo Ocean Chemical New Materials Technology Co., Ltd.

Tel: 0574-86508062 18058587104
Fax: +86 (574) 87132055
Email: sales@nboceanchem.com
Country: China
ProdList: 19
Advantage: 60

Shanghai Xingui Biotechnology Co., Ltd.

Tel: 17501653713 17501653715
Email: xingui2022@126.com
Country: China
ProdList: 10033
Advantage: 58

Shanghai HuanChuan Industry Co.,Ltd.

Tel: 021-61478794
Fax: 021-61478794
Email: sales@hcshhai.com
Country: China
ProdList: 9798
Advantage: 50

Hubei Jusheng Technology Co.,Ltd

Tel: 027-59599241 18871490274
Fax: 027-59599241
Email: 1400878000@qq.com
Country: China
ProdList: 9972
Advantage: 58

Sigma-Aldrich

Tel: 021-61415566 800-8193336
Email: orderCN@merckgroup.com
Country: China
ProdList: 51471
Advantage: 80

Suzhou Xinkai Bio-Medical Technology Co., Ltd.

Tel: 0512-67213637 13952409868
Email: peter19zhang@163.com
Country: China
ProdList: 452
Advantage: 55

ShangHai Movin Pharmaceutical Co., Ltd.

Tel: 13681854265
Email: info@moenpharm.com
Country: China
ProdList: 511
Advantage: 55

Chengdu RunZeBenTu Chemical Co., Ltd

Tel: 028-88469284 18000562381
Email: rzbtsj@163.com
Country: China
ProdList: 9958
Advantage: 56

Shanghai YuanYe Biotechnology Co., Ltd.

Tel: 021-61312847; 18021002903
Fax: QQ:3008007432
Email: 3008007409@qq.com
Country: China
ProdList: 27322
Advantage: 60

parabiochem

Tel: 025-83453382-8005
Fax: 025-83453382
Email: sale@parabiochem.com
Country: China
ProdList: 9604
Advantage: 55

Shandong Xiya Chemical Co., Ltd.

Tel: 4009903999 13395398332
Fax: 0539-6365991
Email: sales@xiyashiji.com
Country: China
ProdList: 20810
Advantage: 60

Shenzhen Simeiquan Biotechnology Co. Ltd

Tel: 18126413629 0755-23311925 2355327053
Fax: 0755-23311925
Email: abel@ycgmp.com
Country: China
ProdList: 5115
Advantage: 58

Amadis Chemical Company Limited

Tel: 571-89925085
Fax: 0086-571-89925065
Email: sales@amadischem.com
Country: China
ProdList: 131981
Advantage: 58

Beijing Jin Ming Biotechnology Co., Ltd.

Tel: 010-60605840 18892239720
Fax: 010-60605840
Email: psaitong@jm-bio.com
Country: China
ProdList: 12308
Advantage: 58

Shenzhen Sendi Biological Technology Co., Ltd.

Tel: 18124570582 TEL：0755-23574479 2355327139
Fax: 0755-23229476 QQ: 2355327139
Email: siliao02@yccreate.com
Country: China
ProdList: 6120
Advantage: 58

Nanjing Klender Bio-Technology Co., Ltd.

Tel: 025-52343882 18112933882
Fax: 025-52343882
Email: sales@kldbio.com
Country: China
ProdList: 2019
Advantage: 55

Shandong Ono Chemical Co., Ltd.

Tel: 0539-6362799 20）
Fax: 0539-6362799（To 20）
Country: China
ProdList: 10007
Advantage: 58

Zhuhai JiaYi Biological Technology Co., Ltd.

Tel: 18578209868 2355327026
Fax: 18578209868 QQ：2355327026
Email: steroidbest@hotmail.com
Country: China
ProdList: 6504
Advantage: 58

Aikon International Limited

Tel: 025-66113011 18112977050
Fax: (5)02557626880
Email: cb6@aikonchem.com
Country: China
ProdList: 15495
Advantage: 58

Wuhan FengyaoTonghui Chemical Products Co., Ltd.

Tel: 027-87466105 15377573527
Email: 2678564200@qq.com
Country: China
ProdList: 17997
Advantage: 58

Shanghai Haohong Pharmaceutical Co., Ltd.

Tel: 400-8210725 4008210725
Fax: 021-58955996
Email: malulu@leyan.com
Country: China
ProdList: 24971
Advantage: 58

Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400-6387771-6038 18902104717
Email: sales@heowns.com
Country: China
ProdList: 20512
Advantage: 60

Shanghai Shuai Sun Industrial Co., Ltd.

Tel: 021-37590756 57450129
Fax: 021-57450128
Country: China
ProdList: 4287
Advantage: 58

Henan Alfachem Co.,Ltd.

Tel: 0371-0371-55051623 18137891487
Fax: QQ：2853979817
Email: 2853979817@qq.com
Country: China
ProdList: 9968
Advantage: 58

Shanghai Jizhi Biochemical Technology Co. Ltd.

Tel: 400-400-400-9004166 18616739031
Email: 3007523370@qq.com
Country: China
ProdList: 52712
Advantage: 58

Cool Pharm, Ltd

Tel: 18019463053
Fax: 021-50966098
Email: sales@coolpharm.com
Country: China
ProdList: 13017
Advantage: 58

Guangdong wengjiang Chemical Reagent Co., Ltd.

Tel: 0751-2815688 13927872512
Fax: 0751-8963795
Email: 3007421951@qq.com
Country: China
ProdList: 10071
Advantage: 58

Shanghai Dingfen Chemical Technology Co., Ltd.

Tel: 021-37590756
Fax: 021-57450128
Email: 373600283@qq.com
Country: China
ProdList: 5001
Advantage: 58

Henan Alfa Chemical Co., Ltd

Tel: +8618339805032
Email: alfa4@alfachem.cn
Country: China
ProdList: 12755
Advantage: 58

Hefei TNJ Chemical Industry Co.,Ltd.

Tel: 0551-65418671
Fax: 0551-65418697
Email: sales@tnjchem.com
Country: China
ProdList: 34572
Advantage: 58

Dayang Chem (Hangzhou) Co.,Ltd.

Tel: 571-88938639 +8617705817739
Fax: +86-571-88938652，+86-571- 88492614
Email: info@dycnchem.com
Country: CHINA
ProdList: 52867
Advantage: 58

Chemwill Asia Co.,Ltd.

Tel: 86-21-51086038
Fax: 86-21-51861608
Email: chemwill_asia@126.com
Country: CHINA
ProdList: 23931
Advantage: 58

Hubei Jusheng Technology Co.,Ltd.

Tel: 18871490254
Fax: 027-59599243
Email: linda@hubeijusheng.com
Country: CHINA
ProdList: 28180
Advantage: 58

Less

View Lastest Price from O-ALLYLHYDROXYLAMINE HYDROCHLORIDE manufacturers

Career Henan Chemical Co

Product: O-ALLYLHYDROXYLAMINE HYDROCHLORIDE 38945-21-0
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1ton
Release date: 2018-08-06

38945-21-0, O-ALLYLHYDROXYLAMINE HYDROCHLORIDERelated Search:

O-ALLYLHYDROXYLAMINE HYDROCHLORIDE Hydroxylamine hydrochloride 1-(3-([(4-CHLOROPHENYL)SULFONYL]METHYL)-4-NITROPHENYL)-1-ETHANONE O-(3-CHLORO-2-PROPENYL)OXIME 1-CHLORO-4-([(CINNAMOYLOXY)IMINO]METHYL)BENZENE 5-NITRO-2-([(2,3,3-TRICHLOROALLANOYL)OXY]ETHANIMIDOYL)-1-BENZOFURAN 2,4-DICHLORO-1-(([(2,3,3-TRICHLOROALLANOYL)OXY]IMINO)METHYL)BENZENE O1-(2,3,3-TRICHLOROACRYLOYL)-3-[3,5-DI(TRIFLUOROMETHYL)PHENYL]PROP-2-ENEHYDROXIMAMIDE 4-[(4-CHLOROANILINO)METHYLENE]-3-PHENYL-5(4H)-ISOXAZOLONE O1-[3-(5-CHLORO-1,3-DIMETHYL-1H-PYRAZOL-4-YL)ACRYLOYL]-4-CHLOROBENZENE-1-CARBOHYDROXIMAMIDE O-ALLYLHYDROXYLAMINE HYDROCHLORIDE HYDRATE SPECS AH-262/36795050 O4-(2,3,3-TRICHLOROACRYLOYL)-2,6-DICHLOROPYRIDINE-4-CARBOHYDROXIMAMIDE O1-[3-(5-CHLORO-1,3-DIMETHYL-1H-PYRAZOL-4-YL)ACRYLOYL]-4-(TERT-BUTYL)BENZENE-1-CARBOHYDROXIMAMIDE 4-[3-CHLORO-5-(TRIFLUOROMETHYL)-2-PYRIDINYL]-2-(3-[4-(DIMETHYLAMINO)PHENYL]-2-PROPENYLIDENE)-5-OXO-2,5-DIHYDROISOXAZOL-2-IUM-3-OLATE BUTTPARK 1\01-100 4-(PHENYLSULFONYL)-2-BUTANONE O-(3-CHLORO-2-PROPENYL)OXIME N-[BIS(4-FLUOROPHENYL)METHYLENE]-N-[(2,3,3-TRICHLOROALLANOYL)OXY]AMINE 6-(2-([(3-CHLORO-2-PROPENYL)OXY]IMINO)ETHYL)-1-(3,4-DIMETHOXYPHENETHYL)-4-OXO-1,4-DIHYDRO-5-PYRIMIDINECARBONITRILE

O-ALLYLHYDROXYLAMINE HYDROCHLORIDE

O-(2-PROPENYL)HYDROXYLAMINE HYDROCHLORIDE

O-ALLYHYDROXYAMINE HYDROCHLORIDE)

O-Allylhydroxylamine hydrochloride >=98.0% (AT)

O-prop-2-enylhydroxylamine hydrochloride

Hydroxylamine, O-2-propenyl-, hydrochloride (9CI)

<i>O</i>-Allylhydroxylamine Hydrochloride

HydroxylaMine, O-2-propenyl-, hydrochloride

(Allyloxy)amine hydrochloride

3-(Aminooxy)prop-1-ene hydrochloride

O-Allylhydroxylamine Hydrochloride &gt

(O-(prop-2-en-1-yl)hydroxylamine hydrochloride).

38945-21-0

C3H7ONHCl

C3H8ClNO

CH2CHCH2ONH2HCl

Building Blocks

Hydroxylamines (O-Substituted)

Hydroxylamines

Nitrogen Compounds

Organic Building Blocks

Hydroxylamines (O-Substituted)

Hydroxylamines