2,4,6-TRIS(4-CARBOXYPHENYL)-1,3,5-TRIAZINE
- Product Name
- 2,4,6-TRIS(4-CARBOXYPHENYL)-1,3,5-TRIAZINE
- CAS No.
- 61414-16-2
- Chemical Name
- 2,4,6-TRIS(4-CARBOXYPHENYL)-1,3,5-TRIAZINE
- Synonyms
- H3TATB;4,4',4''-(1,3,5-triazine-2,4,6-triyl)tribenzoic acid;TZ433;TRZ33;DK7260;DK7695;JACS-61414-16-2;p-Cyanobenzoic acid trimer;2,5-Di(4-carboxyphenyl)thiophene;2,4,6-Tris(4-carboxyphenyl)-s-triazine
- CBNumber
- CB7754919
- Molecular Formula
- C24H15N3O6
- Formula Weight
- 441.39
- MOL File
- 61414-16-2.mol
2,4,6-TRIS(4-CARBOXYPHENYL)-1,3,5-TRIAZINE Property
- Melting point:
- 83-88℃
- Boiling point:
- 799.9±70.0 °C(Predicted)
- Density
- 1.458±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- Aqueous Base (Slightly), DMSO (Slightly, Heated)
- form
- Solid
- pka
- 3.27±0.10(Predicted)
- color
- White to Off-White
- InChI
- InChI=1S/C24H15N3O6/c28-22(29)16-7-1-13(2-8-16)19-25-20(14-3-9-17(10-4-14)23(30)31)27-21(26-19)15-5-11-18(12-6-15)24(32)33/h1-12H,(H,28,29)(H,30,31)(H,32,33)
- InChIKey
- MSFXUHUYNSYIDR-UHFFFAOYSA-N
- SMILES
- N1=C(C2=CC=C(C=C2)C(O)=O)N=C(C2=CC=C(C=C2)C(O)=O)N=C1C1=CC=C(C=C1)C(O)=O
Safety
- Hazard Codes
- T
- Risk Statements
- 61-20/21-36/37/38-50/53-36/38
- Safety Statements
- 53-26-36/37-45-61
- WGK Germany
- 3
- HS Code
- 29336990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 741175
- Product name
- 4,4′,4?″-s-Triazine-2,4,6-triyl-tribenzoic acid
- Purity
- 95%
- Packaging
- 500mg
- Price
- $209
- Updated
- 2025/07/31
- Product number
- C955200
- Product name
- p-CyanobenzoicAcidTrimer
- Packaging
- 1g
- Price
- $970
- Updated
- 2021/12/16
- Product number
- 2042AQ
- Product name
- 2,4,6-Tris(4-carboxyphenyl)-1,3,5-triazine
- Packaging
- 100mg
- Price
- $179.6
- Updated
- 2021/12/16
- Product number
- 2042AQ
- Product name
- 2,4,6-Tris(4-carboxyphenyl)-1,3,5-triazine
- Packaging
- 1g
- Price
- $286.4
- Updated
- 2021/12/16
- Product number
- 92009
- Product name
- p-CyanobenzoicAcidTrimer
- Packaging
- 100mg
- Price
- $290
- Updated
- 2021/12/16
2,4,6-TRIS(4-CARBOXYPHENYL)-1,3,5-TRIAZINE Chemical Properties,Usage,Production
Uses
4,4′,4′′-s-Triazine-2,4,6-triyl-tribenzoic acid (H3TATB) is an electron acceptor that can be used in the synthesis of an electrochromic material (ECM). ECM can be used for a variety of applications such as electronic paper, smart windows, and energy storage devices. It can also be used in the formation of a metal-organic framework (MOF) for potential usage in CO2 adsorption. It can be used in the preparation of PCN-333(Al) based MOFs for the fabrication of an electrochemical biosensor.
General Description
This product has been enhanced for energy efficiency.
Synthesis
6726-45-0
61414-16-2
General procedure for the synthesis of 2,4,6-tris(4-carboxyphenyl)-1,3,5-triazine from 2,4,6-tris-tosyl-1,3,5-triazine: 2,4,6-tris(4-carboxyphenyl)-1,3,5-triazine (1.0 g, 2.8 mmol), acetic acid (24.85 mL), and concentrated sulfuric acid (1.58 mL) were added to a 100 mL round-bottomed flask and stirred for for 5 minutes. Subsequently, the reaction mixture was heated to 50 °C and a solution consisting of chromium trioxide (2.58 g) dissolved in a mixture of acetic acid (5 mL) and concentrated sulfuric acid (5 mL) was added slowly and dropwise. The resulting dark brown slurry was stirred overnight. Upon completion of the reaction, the reaction mixture was filtered and the solid residue was collected. The residue was redissolved in 2N sodium hydroxide solution and filtered to remove insoluble impurities. Finally, the filtrate was acidified with 6N hydrochloric acid to afford the white precipitated product 2,4,6-tris(4-carboxyphenyl)-1,3,5-triazine (H3TATB) in 60% yield. The product was characterized by 1H NMR (400 MHz, DMSO-d6): δ=8.80 ppm (d, J=8.5 Hz, 6H), 8.18 (d, J=8.5 Hz, 6H); mass spectrometry (ESI) analysis showed [M-H]- peaks, and molecular weights of 440.0800 for the calculated value of C24H14N3O6 and 440.0100 for the measured value.
References
[1] Journal of the American Chemical Society, 2006, vol. 128, # 12, p. 3896 - 3897
[2] Zeitschrift fur Anorganische und Allgemeine Chemie, 2015, vol. 641, # 10, p. 1781 - 1785
[3] Journal of the American Chemical Society, 2015, vol. 137, # 4, p. 1663 - 1672
[4] Journal of the American Chemical Society, 2015, vol. 137, # 36, p. 11801 - 11809
[5] Journal of Materials Chemistry C, 2016, vol. 4, # 25, p. 6117 - 6130
2,4,6-TRIS(4-CARBOXYPHENYL)-1,3,5-TRIAZINE Preparation Products And Raw materials
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View Lastest Price from 2,4,6-TRIS(4-CARBOXYPHENYL)-1,3,5-TRIAZINE manufacturers
- Product
- 4,4',4''-(1,3,5-triazine-2,4,6-triyl)trisbenzoic acid 61414-16-2
- Price
- US $74.00-736.00/g
- Min. Order
- 5g
- Purity
- 0.98
- Supply Ability
- 10kg
- Release date
- 2024-10-25
- Product
- 2,4,6-TRIS(4-CARBOXYPHENYL)-1,3,5-TRIAZINE 61414-16-2
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1000KG
- Release date
- 2018-12-16