ChemicalBook > CAS DataBase List > 1,3,5-TRIMETHYL-1,3,5-TRIPHENYLCYCLOTRISILOXANE

1,3,5-TRIMETHYL-1,3,5-TRIPHENYLCYCLOTRISILOXANE

Product Name
1,3,5-TRIMETHYL-1,3,5-TRIPHENYLCYCLOTRISILOXANE
CAS No.
546-45-2
Chemical Name
1,3,5-TRIMETHYL-1,3,5-TRIPHENYLCYCLOTRISILOXANE
Synonyms
LS 8490;Methyl phenyl ring;Mixedcis-/trans-isomeres;PHENYLMETHYLCYCLOSILOXANES;Methylphenylcyclosiloxanes;TRIPHENYLTRIMETHYLCYCLOTRISILOXANE;Phenylmethylsiloxane cyclic trimer;Trimethyltriphenylcyclotrisiloxane;2,4,6-TRIMETHYL-2,4,6-TRIPHENYLCYCLO;sym-Trimethyltriphenylcyclo trisiloxane
CBNumber
CB7767751
Molecular Formula
C21H24O3Si3
Formula Weight
408.67
MOL File
546-45-2.mol
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1,3,5-TRIMETHYL-1,3,5-TRIPHENYLCYCLOTRISILOXANE Property

Melting point:
100°C
Boiling point:
160-90°C 5mm
Density 
1.102 g/mL at 20 °C(lit.)
refractive index 
1.545
Flash point:
>200°C
storage temp. 
Sealed in dry,Room Temperature
form 
solid
Specific Gravity
1.1
Hydrolytic Sensitivity
1: no significant reaction with aqueous systems
BRN 
2954104
InChI
InChI=1S/C21H24O3Si3/c1-25(19-13-7-4-8-14-19)22-26(2,20-15-9-5-10-16-20)24-27(3,23-25)21-17-11-6-12-18-21/h4-18H,1-3H3
InChIKey
HAURRGANAANPSQ-UHFFFAOYSA-N
SMILES
[Si]1(C)(O[Si](O[Si](C)(C2C=CC=CC=2)O1)(C)C1C=CC=CC=1)C1=CC=CC=C1
EPA Substance Registry System
Cyclotrisiloxane, 2,4,6-trimethyl-2,4,6-triphenyl- (546-45-2)
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Safety

Risk Statements 
20/21/22
Safety Statements 
24/25-36/37/39
WGK Germany 
3
TSCA 
TSCA listed
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
T798340
Product name
1,3,5-Trimethyl-1,3,5-triphenylcyclotrisiloxane(Cis&TransIsomersMixture)
Packaging
250mg
Price
$45
Updated
2021/12/16
Frontier Specialty Chemicals
Product number
JK548830
Product name
2,4,6-Trimethyl-2,4,6-triphenylcyclotrisiloxane
Purity
95%
Packaging
5g
Price
$130
Updated
2021/12/16
AK Scientific
Product number
Z2247
Product name
1,3,5-Trimethyl-1,3,5-triphenylcyclotrisiloxane,mixtureofcisandtransisomers,tech.
Packaging
10g
Price
$143
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ORS0005352
Product name
1,3,5-TRIMETHYL-1,3,5-TRIPHENYLCYCLOTRISILOXANE
Purity
95.00%
Packaging
5G
Price
$226.8
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ORS0005352
Product name
1,3,5-TRIMETHYL-1,3,5-TRIPHENYLCYCLOTRISILOXANE
Purity
95.00%
Packaging
5ML
Price
$881.84
Updated
2021/12/16
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1,3,5-TRIMETHYL-1,3,5-TRIPHENYLCYCLOTRISILOXANE Chemical Properties,Usage,Production

Chemical Properties

Colorless to white solid

Definition

ChEBI: Cis-2,4,6-Trimethyl-2,4,6-triphenylcyclotrisiloxane is an organosilicon compound.

Synthesis

A method of preparing a synthetic 2,4,6-trimethyl-2,4,6-triphenylcyclotrisiloxane, comprising the steps as follows:

(1) adding methylphenyl dianisoxysilane and pure water at a mass ratio of I:0. I~I to a reaction vessel for hydrolysis reaction, hydrolysis temperature of 60??C~200??C, stirring, and constantly evaporating the mixture of methanol and water produced by the reaction. When the density of the evaporated liquid reaches 0.9~lg/ml, stop evaporation, reflux 0.5~4h, and separate out the lower oil phase hydrolysate;

(2) Move the oil phase hydrolysate obtained in step (I) into the reactor for dewatering under reduced pressure, and dewatering of low-boiling materials, with the pressure ranging from -0.05MPa to -0.098MPa, and the temperature ranging from 80??C to 200??C, and the time from 0.5h to 8h ;

(3) Add the oil phase hydrolysate into the reaction vessel for hydrolysis reaction at the temperature of 60??C~200??C, stirring, and continuously evaporating the mixture of methanol and water produced by the reaction. 0.5h~8h;

(3) After dehydration and stripping out the low-boiling material, continue to raise the temperature, and distill the methyl phenyl cyclosiloxane under reduced pressure, with the temperature range of 200??C~400??C, and the pressure range of -0.098MPa~-0.0999MPa, and collect the methyl phenyl cyclosiloxane fraction.

1,3,5-TRIMETHYL-1,3,5-TRIPHENYLCYCLOTRISILOXANE Preparation Products And Raw materials

Raw materials

Preparation Products

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1,3,5-TRIMETHYL-1,3,5-TRIPHENYLCYCLOTRISILOXANE Suppliers

Gelest, Inc.
Tel
--
Fax
--
Country
Singapore
ProdList
2215
Advantage
39
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View Lastest Price from 1,3,5-TRIMETHYL-1,3,5-TRIPHENYLCYCLOTRISILOXANE manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
sym-Trimethyltriphenylcyclo trisiloxane 546-45-2
Price
US $8.80-2.20/kg
Min. Order
1kg
Purity
99%
Supply Ability
100kg
Release date
2025-06-27
Henan Aochuang Chemical Co.,Ltd.
Product
1,3,5-TRIMETHYL-1,3,5-TRIPHENYLCYCLOTRISILOXANE 546-45-2
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-09-30
Career Henan Chemical Co
Product
1,3,5-trimethyl-1,3,5-triphenylcyclotrisiloxane 546-45-2
Price
US $1.00/g
Min. Order
1g
Purity
Min98% HPLC
Supply Ability
g/kg/ton
Release date
2019-12-28

546-45-2, 1,3,5-TRIMETHYL-1,3,5-TRIPHENYLCYCLOTRISILOXANERelated Search:


  • 2,4,6-Trimethyl-2,4,6-triphenyl-1,3,5,2,4,6-trioxatrisilinane
  • 2,4,6-trimethyl-2,4,6-triphenyl-cyclotrisiloxan
  • Cyclotrisiloxane, 2,4,6-trimethyl-2,4,6-triphenyl-
  • PHENYLMETHYLCYCLOSILOXANES
  • TRIPHENYLTRIMETHYLCYCLOTRISILOXANE
  • 2,4,6-TRIMETHYL-2,4,6-TRIPHENYLCYCLOTRISILOXANE
  • 1,3,5-TRIMETHYL-1,3,5-TRIPHENYLCYCLOTRISILOXANE
  • 1,3,5-TRIMETHYL-1,3,5-TRIPHENYLCYCLOTRISILOXANE, MIXED CIS,TRANS ISOMERS
  • Triphenyltrimethylcyclotrisiloxanemixedcistransisomers
  • 2,4,6-TRIMETHYL-2,4,6-TRIPHENYLCYCLO
  • TRIPHENYLTRIMETHYLCYCLOTRISILOXANE: 90% MIXED CIS/TRANS ISOMERS
  • Mixedcis-/trans-isomeres
  • PHENYLMETHYLCYCLOSILOXANES , CONTAINS TETRASILOXANES AND TRISILOXANES
  • 2,4,6-Trimethyl-2,4,6-triphenyl 1,3,5-trioxa-2,4,6-trisilacyclohexane
  • 2,4,6-Trimethyl-2,4,6-triphenyl-1,3,5-trioxa-2,4,6-trisilacyclohexane
  • 2,4,6-Trimethyl-2,4,6-triphenylcyclohexanetrisiloxane
  • 2,4,6-Triphenyl-2,4,6-trimethylcyclohexanetrisiloxane
  • Methylphenylcyclosiloxanes
  • LS 8490
  • Phenylmethylsiloxane cyclic trimer
  • Trimethyltriphenylcyclotrisiloxane
  • 1,3,5-TRIPHENYLTRIMETHYLCYCLOTRISILOXANE, 90%
  • 2,4,6-Trimethyl-2,4,6-triphenyl-1,3,5,2,4,6-trioxatrisilinane(mixture of tetramer)
  • 1,3,5-Trimethyl-1,3,5-triphenylcyclotrisiloxane (Cis & Trans Isomers Mixture)
  • sym-Trimethyltriphenylcyclo trisiloxane
  • 1,3,5-Trimethyl-1,3,5-Triphenylcyclotrisiloxane, Mixture Of Cis And Trans Isomers
  • Methyl phenyl ring
  • 1,3,5-TRIMETHYL-1,3,5-TRIPHENYLCYCLOTRISILOXANE,2,4,6,8-tetramethyl-2,4,6,8-tetraphenylcyclotetrasiloxane,SILASTIC 3110 RTV LOW VISCOSITY MOULD MAKING AND ENCAPSULATING RUBBER,2-Amino-6-chloro-4-pyrimidinol,Dimethicone
  • 1,3,5-Trimethyl-1,3,5-triphenylcyclotrisiloxane, mixture of cis and trans isomers, tech.
  • 1,3,5-Trimethyl-1,3,5-triphenylcyclotrisiloxane, mixture of isomers of cis and trans
  • 546-45-2
  • C21H24O3Si3
  • C21H24O3Si3C28H32O4Si4
  • C21H24O3Si3C35H40O5Si5
  • Siloxanes
  • Organosilicon
  • Organometallic Reagents
  • Chemical Synthesis
  • Organometallic Reagents
  • Organosilicon
  • Siloxanes