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ESCHENMOSER'S SALT

Product Name
ESCHENMOSER'S SALT
CAS No.
30354-18-8
Chemical Name
ESCHENMOSER'S SALT
Synonyms
ESCHENMOSER SALT;ESCHENMOSER'S SALT;Dimethylformiminium chloride;dimethylmethylenammonium chloride;Methylenedimethylammonium chloride;Dimethyl(methylene)iminium chloride;DIMETHYL(METHYLIDENE)AZANIUM BROMIDE;N,N-dimethylmethyleneammonium bromide;dimethyl(methylidene)azanium:chloride;N,N-DIMETHYL-METHYLENEIMINIUM CHLORIDE
CBNumber
CB7779334
Molecular Formula
C3H8ClN
Formula Weight
93.56
MOL File
30354-18-8.mol
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ESCHENMOSER'S SALT Property

Melting point:
146-148 °C(lit.)
Flash point:
180 °F
storage temp. 
Store below +30°C.
solubility 
Chloroform (Very Slightly, Heated), DMSO (Sparingly, Heated, Sonicated)
form 
Solid
color 
White to Off-White
BRN 
505955
Stability:
Hygroscopic, Unstable in Protic Solvent
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
RIDADR 
UN 1325 4.1/PG 3
WGK Germany 
3
3-10-21
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H228Flammable solid

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
40766
Product name
N,N-Dimethylmethyleneiminium chloride
Purity
≥95.0% (AT)
Packaging
5g
Price
$93.4
Updated
2024/03/01
Sigma-Aldrich
Product number
40766
Product name
N,N-Dimethylmethyleneiminium chloride
Purity
≥95.0% (AT)
Packaging
25g
Price
$364
Updated
2024/03/01
Sigma-Aldrich
Product number
483893
Product name
N,N-Dimethylmethyleneiminium chloride
Purity
technical grade, 90%
Packaging
5g
Price
$102
Updated
2024/03/01
Sigma-Aldrich
Product number
483893
Product name
N,N-Dimethylmethyleneiminium chloride
Purity
technical grade, 90%
Packaging
25g
Price
$143.6
Updated
2024/03/01
TRC
Product number
D494093
Product name
N,N-DimethylmethyleneiminiumChloride(TechnicalGrade)
Packaging
50mg
Price
$70
Updated
2021/12/16
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ESCHENMOSER'S SALT Chemical Properties,Usage,Production

Uses

N,N-Dimethylmethyleneiminium chloride (B?hme′s salt) is a dimethylaminomethylating agent that can be used as one of the key reagents in the following applications:

  • Electrophilic aminomethylation of aldehydes and ketones to synthesize corresponding Mannich products, also known as Mannich reaction.
  • Preparation of dihydronaphthyridinones as HIV-1 integrase inhibitors.
  • Preparation of cyanotetrahydrooxo-β-carbolines via cyclocondensation of cyanomethyl indole-2-carboxylate with ammonia.
  • Asymmetric synthesis of phalarine via stereospecific Pictet-Spengler cyclocondensation and traceless chirality transfer from L-tryptophan.
  • Synthesis of functionalized diarylpyrrolizines as inhibitors of microsomal prostaglandin E2 synthase-1 (mPGES-1) and 5-lipoxygenase (5-LOX).
  • Synthesis of (±)-phalarine with the rearrangement of an azaspiroindolenine and Gassman oxindole preparation as key steps.

ESCHENMOSER'S SALT Preparation Products And Raw materials

Raw materials

Preparation Products

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30354-18-8, ESCHENMOSER'S SALTRelated Search:


  • ESCHENMOSER SALT
  • ESCHENMOSER'S SALT
  • N,N-DIMETHYLMETHYLENEAMMONIUM CHLORIDE
  • N,N-DIMETHYL-METHYLENEIMINIUM CHLORIDE
  • DIMETHYL(METHYLIDENE)AZANIUM BROMIDE
  • N,N-dimethylmethyleneammonium bromide
  • dimethylmethylenammonium chloride
  • N,N-DIMETHYLMETHYLENEAMMONIUM CHLORIDE, TECH., 90%
  • Methanaminium, N-methyl-N-methylene-, chloride
  • N-Methylene-N-methylmethanaminium·chloride
  • N-Methyl-N-MethyleneMethanaMiniuM chloride
  • N,N-DIMETHYL-METHYLENEIMINIUM CHLORIDE F
  • Dimethyl(methylene)iminium chloride
  • N,N-DiMethylMethyleneiMiniuM chloride >=95.0% (AT)
  • N,N-DiMethylMethyleneiMiniuM chloride technical grade, 90%
  • Dimethylformiminium chloride
  • Methylenedimethylammonium chloride
  • dimethyl(methylidene)azanium:chloride
  • 30354-18-8
  • C3H8NCl
  • CH2NCH32Cl
  • Synthetic Reagents
  • Imines/Amidines
  • Nitrogen Compounds
  • Organic Building Blocks
  • Others
  • Building Blocks
  • C-C Bond Formation