Methyl Indoline-6-carboxylate

Product Name: Methyl Indoline-6-carboxylate
CAS No.: 341988-36-1
Chemical Name: Methyl Indoline-6-carboxylate
Synonyms: methyl indoline-6-carboxylate;methyl indoline-6-carboxylate - [M23157];Methyl 2,3-dihydro-1H-indole-6-carboxylate;Methyl2,3-dihydro-1H-indole-6-carboxylatato;Methyl indoline-6-carboxylate in stock Factory;1H-INDOLE-6-CARBOXYLIC ACID,2,3-DIHYDRO-,METHYL ESTER;2,3-DIHYDRO-1H-INDOLE-6-CARBOXYLIC ACID METHYL ESTER HYDROCHLORIDE
CBNumber: CB7843433
Molecular Formula: C10H11NO2
Formula Weight: 177.2
MOL File: 341988-36-1.mol

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Methyl Indoline-6-carboxylate Property

Boiling point:: 315.6±31.0 °C(Predicted)
Density: 1.162±0.06 g/cm3(Predicted)
storage temp.: 2-8°C
pka: 4.26±0.20(Predicted)
Appearance: White to yellow Solid
InChI: InChI=1S/C10H11NO2/c1-13-10(12)8-3-2-7-4-5-11-9(7)6-8/h2-3,6,11H,4-5H2,1H3
InChIKey: IVFIWGSRKYSLLR-UHFFFAOYSA-N
SMILES: N1C2=C(C=CC(C(OC)=O)=C2)CC1

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Safety

Risk Statements: 36/37/38
Safety Statements: 26-36/37/39
HS Code: 29339900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

TRC

Product number: M313608
Product name: Methylindoline-6-carboxylate
Packaging: 100mg
Price: $50
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FD56698
Product name: 2,3-Dihydro-1H-indole-6-carboxylic acid methyl ester
Packaging: 25mg
Price: $88.5
Updated: 2021/12/16

AK Scientific

Product number: W5567
Product name: Methylindoline-6-carboxylate
Packaging: 250mg
Price: $151
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FD56698
Product name: 2,3-Dihydro-1H-indole-6-carboxylic acid methyl ester
Packaging: 50mg
Price: $181
Updated: 2021/12/16

Apolloscientific

Product number: OR910526
Product name: Methylindoline-6-carboxylate
Purity: 98%
Packaging: 1g
Price: $230
Updated: 2021/12/16

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Methyl Indoline-6-carboxylate Chemical Properties,Usage,Production

Chemical Properties

White solid

Synthesis

50820-65-0

341988-36-1

Step 1: Methyl indole-6-carboxylate (534 mg, 3.05 mmol) was dissolved in acetic acid (7.5 mL) and the solution was cooled to 0°C. Sodium cyanoborohydride (580 mg, 9.2 mmol, 3 equiv) was added to the solution in batches with stirring. The reaction mixture was stirred continuously for 40 minutes at 15 °C. Subsequently, sodium cyanoborohydride (193 mg, 3.05 mmol, 1 eq.) was added again and stirring was continued for 30 minutes at room temperature. After completion of the reaction, the solvent was removed by rotary evaporator. The residue was dissolved in dichloromethane and washed with 1N NaOH solution. The organic phase was dried over anhydrous sodium sulfate, filtered and concentrated to afford methyl 2,3-dihydro-1H-indole-6-carboxylate as a pale yellow solid in a yield of 494 mg (77% yield). The product did not require further purification and could be used directly in the subsequent reaction.

References

[1] Patent: US2007/60567, 2007, A1. Location in patent: Page/Page column 25
[2] Patent: US2008/153805, 2008, A1. Location in patent: Page/Page column 12
[3] ChemMedChem, 2016, vol. 11, # 23, p. 2607 - 2620
[4] Patent: WO2018/52903, 2018, A1. Location in patent: Page/Page column 22; 43-44
[5] Patent: US2010/234340, 2010, A1. Location in patent: Page/Page column 20

Methyl Indoline-6-carboxylate Preparation Products And Raw materials

Raw materials

Preparation Products

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Methyl Indoline-6-carboxylate Suppliers

China 95 India 3 United Kingdom 1 United States 10 Global 109

Accela ChemBio Inc.

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Matrix Scientific

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Waterstone Technology, LLC

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Combi-Blocks Inc.

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Chem-Impex International, Inc.

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View Lastest Price from Methyl Indoline-6-carboxylate manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: Methyl 2,3-dihydro-1H-indole-6-carboxylate 341988-36-1
Price: US $1.10-9.90/kg
Min. Order: 1kg
Purity: 99%min
Supply Ability: 100kg
Release date: 2025-08-18

Chemwill Asia Co.,Ltd.

Product: Methyl indoline-6-carboxylate in stock Factory 341988-36-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: TOP 3 Factory in China
Supply Ability: Top 3 production capacity Factory
Release date: 2019-04-03

Career Henan Chemical Co

Product: 2,3-DIHYDRO-1H-INDOLE-6-CARBOXYLIC ACID METHYL ESTER HYDROCHLORIDE 341988-36-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 200kgs
Release date: 2020-01-09

341988-36-1, Methyl Indoline-6-carboxylateRelated Search:

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Methyl indoline-6-carboxylate in stock Factory

Methyl 2,3-dihydro-1H-indole-6-carboxylate

2,3-DIHYDRO-1H-INDOLE-6-CARBOXYLIC ACID METHYL ESTER HYDROCHLORIDE

methyl indoline-6-carboxylate

Methyl2,3-dihydro-1H-indole-6-carboxylatato

1H-INDOLE-6-CARBOXYLIC ACID,2,3-DIHYDRO-,METHYL ESTER

methyl indoline-6-carboxylate - [M23157]

341988-36-1

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