1,1-DICYCLOPROPANECARBOXYLIC ACID
- Product Name
- 1,1-DICYCLOPROPANECARBOXYLIC ACID
- CAS No.
- 60629-92-7
- Chemical Name
- 1,1-DICYCLOPROPANECARBOXYLIC ACID
- Synonyms
- 1,1-Dicyclopanecarboxylic Acid;1,1-DICYCLOPROPANECARBOXYLIC ACID;-bi(cyclopropane)]-1-carboxylic acid;[1,1'-Bicyclopropyl]-1-carboxylic acid;1-cyclopropylcyclopropanecarboxylic acid;[1,1'-bi(cyclopropane)]-1-carboxylic acid;1-cyclopropylcyclopropane-1-carboxylic acid
- CBNumber
- CB7849521
- Molecular Formula
- C7H10O2
- Formula Weight
- 126.15
- MOL File
- 60629-92-7.mol
1,1-DICYCLOPROPANECARBOXYLIC ACID Property
- Melting point:
- 51-53℃
- Boiling point:
- 239.9±8.0 °C(Predicted)
- Density
- 1.389±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- pka
- 4.78±0.20(Predicted)
- Appearance
- White to off-white Solid
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
N-Bromosuccinimide Price
- Product number
- B411708
- Product name
- [1,1''-Bi(cyclopropane)]-1-carboxylicacid
- Packaging
- 2.5mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- B411708
- Product name
- [1,1''-Bi(cyclopropane)]-1-carboxylicacid
- Packaging
- 5mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- B411708
- Product name
- [1,1''-Bi(cyclopropane)]-1-carboxylicacid
- Packaging
- 25mg
- Price
- $175
- Updated
- 2021/12/16
- Product number
- 8712CU
- Product name
- [1,1'-Bi(cyclopropane)]-1-carboxylicacid
- Packaging
- 250mg
- Price
- $379
- Updated
- 2021/12/16
- Product number
- 8712CU
- Product name
- [1,1'-Bi(cyclopropane)]-1-carboxylicacid
- Packaging
- 1g
- Price
- $824
- Updated
- 2021/12/16
1,1-DICYCLOPROPANECARBOXYLIC ACID Chemical Properties,Usage,Production
Synthesis
1447944-40-2
60629-92-7
General procedure for the synthesis of [1,1'-bicyclopropane]-1-carboxylic acid from the compound (CAS: 1447944-40-2): to a mixture of ester B-41a (100 mg, 0.462 mmol) dissolved in methanol (2.5 mL) and water (0.5 mL) at 0 °C was added an aqueous solution of 1 N NaOH (1 mL, 0.247 mmol ) and stirred at 0 °C for 10 min. The reaction mixture was then warmed to 25 °C and stirring was continued for 12 hours. After completion of the reaction, the volatile components were completely removed under reduced pressure. Water (5 mL) was added to the residue and extracted with ether (2 x 10 mL). The aqueous layer was adjusted to pH ~2 with 1.5 N HCl and then extracted with a 10% MeOH/DCM (3 × 10 mL) mixture. The organic layers were combined, washed with brine solution (10 mL) and dried with anhydrous sodium sulfate. The solvent was removed under reduced pressure to afford [1,1'-bicyclopropane]-1-carboxylic acid (CapB-41) (60 mg, 0.476 mmol, 93% yield) as an off-white solid.1H NMR (CDCl3, δ=7.26 ppm, 400 MHz): δ1.49-1.46 (m, 1H), 1.15 (app. q J=3.6 Hz. 2H), 0.62 (app.q J=3.6 Hz, 2H), 0.49-0.44 (m, 2H), 0.04--0.008 (m, 2H).
References
[1] Patent: WO2015/5901, 2015, A1. Location in patent: Page/Page column 657; 658
1,1-DICYCLOPROPANECARBOXYLIC ACID Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 1,1-DICYCLOPROPANECARBOXYLIC ACID manufacturers
- Product
- 1,1-DICYCLOPROPANECARBOXYLIC ACID 60629-92-7
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-10-13
- Product
- 1,1-DICYCLOPROPANECARBOXYLIC ACID 60629-92-7
- Price
- US $1.00/g
- Min. Order
- 1g
- Purity
- MIn98% HPLC/LC
- Supply Ability
- 100KGS
- Release date
- 2020-10-28