Methyl 2-bromomethyl-4-cyanobenzoate

Product Name: Methyl 2-bromomethyl-4-cyanobenzoate
CAS No.: 165111-46-6
Chemical Name: Methyl 2-bromomethyl-4-cyanobenzoate
Synonyms: Methyl 2-bromomethyl-4-cyanobenzoate;Benzoic acid, 2-(bromomethyl)-4-cyano-, methyl ester
CBNumber: CB7947900
Molecular Formula: C10H8BrNO2
Formula Weight: 254.08
MOL File: Mol file

More

Less

Methyl 2-bromomethyl-4-cyanobenzoate Property

Boiling point:: 380.5±37.0 °C(Predicted)
Density: 1.53±0.1 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
Appearance: White to off-white Solid
InChI: InChI=1S/C10H8BrNO2/c1-14-10(13)9-3-2-7(6-12)4-8(9)5-11/h2-4H,5H2,1H3
InChIKey: QMLVCVLSZNSKJM-UHFFFAOYSA-N
SMILES: C(OC)(=O)C1=CC=C(C#N)C=C1CBr

More

Less

Safety

HS Code: 2916399090

More

Less

Hazard and Precautionary Statements (GHS)

More

Less

N-Bromosuccinimide Price

SynQuest Laboratories

Product number: 4637-9-Y3
Product name: Methyl 2-bromomethyl-4-cyanobenzoate
Purity: 95.0%
Packaging: 1g
Price: $116
Updated: 2021/12/16

AK Scientific

Product number: 8384AA
Product name: Methyl2-(bromomethyl)-4-cyanobenzoate
Packaging: 1g
Price: $195
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0007552
Product name: METHYL 2-BROMOMETHYL-4-CYANOBENZOATE
Purity: 95.00%
Packaging: 5G
Price: $1994.98
Updated: 2021/12/16

Crysdot

Product number: CD12135557
Product name: Methyl2-(bromomethyl)-4-cyanobenzoate
Purity: 95+%
Packaging: 5g
Price: $380
Updated: 2021/12/16

Ambeed

Product number: A152862
Product name: Methyl2-(bromomethyl)-4-cyanobenzoate
Purity: 95%
Packaging: 5g
Price: $462
Updated: 2021/12/16

More

Less

Methyl 2-bromomethyl-4-cyanobenzoate Chemical Properties,Usage,Production

Synthesis

103261-67-2

165111-46-6

General procedure for the synthesis of methyl 2-bromomethyl-4-cyanobenzoate from methyl 4-cyano-2-methylbenzoate: Methyl 4-cyano-2-methylbenzoate (4.0 g, 22.83 mmol) was dissolved in carbon tetrachloride (150 mL) and N-bromosuccinimide (NBS, 4.88 g, 27.4 mmol) was added to form a suspension. The suspension was heated at 80 °C for 5 min. Subsequently, azobisisobutyronitrile (AIBN, 1.88 g, 11.42 mmol) was added and stirred continuously at 80 °C for 16 hours. After completion of the reaction, the mixture was cooled to room temperature and filtered. The filtrate was concentrated to give the crude product. Purification by silica gel column chromatography using a solvent mixture of ethyl acetate (EA) and petroleum ether (gradient elution, 0% to 5% EA) resulted in methyl 2-bromomethyl-4-cyanobenzoate (3.84 g, 66.9% yield) as a white solid.

References

[1] Patent: WO2017/201069, 2017, A1. Location in patent: Paragraph 0510
[2] Patent: US5591752, 1997, A
[3] Patent: US2009/82368, 2009, A1. Location in patent: Page/Page column 41-42
[4] Patent: WO2013/79452, 2013, A1. Location in patent: Page/Page column 165
[5] Patent: US2014/45855, 2014, A1. Location in patent: Paragraph 0552

Methyl 2-bromomethyl-4-cyanobenzoate Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

Methyl 2-bromomethyl-4-cyanobenzoate Suppliers

China 60 India 2 United Kingdom 1 United States 4 Global 67

ShangHai AmK Pharmaceutical Technology Co., Ltd.

Tel: 微信 17321281695 18019252918
Fax: 17321281695
Email: sale@amkchem.com
Country: China
ProdList: 15136
Advantage: 55

Beijing Eternalchem Co,. Ltd.

Tel: 010-59484199 18611897322
Email: sales@eternalchem.com
Country: China
ProdList: 4383
Advantage: 60

Shanghai Topbiochem Technology Co., Ltd

Tel: 021-58170097
Email: info@topbiochem.com
Country: China
ProdList: 9510
Advantage: 58

Suzhou Sino Rare Chemical Co., Ltd.

Tel: 0512-62857507
Fax: +86-512-62857507
Email: sales@sinorarechem.com
Country: China
ProdList: 991
Advantage: 58

Bide Pharmatech Ltd.

Tel: 400-164-7117 13681763483
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 39966
Advantage: 60

Shanghai Na Qian Chemical Technology Co. Ltd.

Tel: 13598610367
Fax: QQ:2468833170
Email: 2841375912@qq.com
Country: China
ProdList: 2788
Advantage: 52

Nanjing Chalf-Pharm Technology Co., Ltd.

Tel: 025-57018978 18251899859
Fax: 025-57018008
Email: sales@chalf-pharm.com
Country: China
ProdList: 5674
Advantage: 50

Changzhou Anxuan Chemical, Co., Ltd.

Tel: 13912302692 13912302692;
Fax: 0519-88064678
Email: sales@anxuanchem.com
Country: China
ProdList: 4828
Advantage: 58

ShangHai Wisacheam Pharmaceutical Co., Ltd.

Tel: 13817485796
Fax: QQ:895624079
Email: tim@wisacheampharm.com
Country: China
ProdList: 3592
Advantage: 58

SuZhou ShiYa Biopharmaceuticals, Inc.

Tel: 0512-0512-52358471 17715136450
Fax: 05125235 6881
Email: sales@shiyabiopharm.com
Country: China
ProdList: 12127
Advantage: 58

More

Less

View Lastest Price from Methyl 2-bromomethyl-4-cyanobenzoate manufacturers

Shaanxi Dideu New Materials Co. Ltd

Product: Methyl 2-bromomethyl-4-cyanobenzoate 165111-46-6
Price: US $0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1000kg
Release date: 2025-09-29

165111-46-6, Methyl 2-bromomethyl-4-cyanobenzoateRelated Search:

Methyl 4-cyanobenzoate bis(2-ethylhexyl) tetrabromophthalate

Methyl 2-bromomethyl-4-cyanobenzoate

Benzoic acid, 2-(bromomethyl)-4-cyano-, methyl ester

165111-46-6