5-Methoxy-2-methyl benzeneboronic acid
- Product Name
- 5-Methoxy-2-methyl benzeneboronic acid
- CAS No.
- 617689-07-3
- Chemical Name
- 5-Methoxy-2-methyl benzeneboronic acid
- Synonyms
- (5-Methoxy-2-methylphenyl);2-Methyl-5-Methoxy-phenylboronic acid;5-Methoxy-2-methyl benzeneboronic acid;boronic acid, (5-methoxy-2-methylphenyl)-;Boronic acid, B-(5-methoxy-2-methylphenyl)-;(5-Methoxy-2-methylphenyl)boronic acid(contains varying amounts of Anhydride)
- CBNumber
- CB7969647
- Molecular Formula
- C8H11BO3
- Formula Weight
- 165.98
- MOL File
- Mol file
5-Methoxy-2-methyl benzeneboronic acid Property
- Boiling point:
- 334.9±52.0 °C(Predicted)
- Density
- 1.14±0.1 g/cm3(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- pka
- 8.18±0.58(Predicted)
- Appearance
- Light brown to brown Solid
Safety
- HS Code
- 2931900090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H303May be harmfulif swallowed
H320Causes eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P312Call a POISON CENTER or doctor/physician if you feel unwell.
P337+P313IF eye irritation persists: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- M341448
- Product name
- (5-Methoxy-2-methylphenyl)boronicAcid
- Packaging
- 500mg
- Price
- $285
- Updated
- 2021/12/16
- Product number
- 120045
- Product name
- (5-Methoxy-2-methylphenyl)boronic acid
- Purity
- 95+%
- Packaging
- 250mg
- Price
- $346
- Updated
- 2021/12/16
- Product number
- BOR0000717
- Product name
- 5-METHOXY-2-METHYLBENZENEBORONIC ACID
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $505.95
- Updated
- 2021/12/16
- Product number
- BOR0000717
- Product name
- 5-METHOXY-2-METHYLBENZENEBORONIC ACID
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $698.25
- Updated
- 2021/12/16
- Product number
- 120045
- Product name
- (5-Methoxy-2-methylphenyl)boronic acid
- Purity
- 95+%
- Packaging
- 1g
- Price
- $864
- Updated
- 2021/12/16
5-Methoxy-2-methyl benzeneboronic acid Chemical Properties,Usage,Production
Uses
(5-Methoxy-2-methylphenyl)boronic Acid is used in preparation of Phenyl-substituted Imidazopyridine Amides useful in the treatment of cardiovascular and other disorders.
Synthesis
36942-56-0
617689-07-3
The general procedure for the synthesis of 5-methoxy-2-methylphenylboronic acid from 3-bromo-4-methylanisole was as follows: 2.5 M n-butyllithium (nBuLi, 1.8 mL, 4.5 mmol) was added slowly and dropwise over a period of 5 min to 2-bromo-4-methoxy-1-methylbenzene (750 mg, 3.73 mmol) in an anhydrous tetrahydrofuran (THF,) at -78 °C. 30 mL) solution. The reaction mixture was stirred at -78 °C for 20 min before adding anhydrous trimethylborate (0.62 g, 6 mmol). The reaction mixture was warmed to room temperature and kept for 2 hours. The reaction was quenched by addition of 2N hydrochloric acid (HCl, 1 mL). THF was removed by distillation under reduced pressure. the crude product was diluted with 2N HCl (100 mL) and extracted with ethyl acetate (2 x 50 mL). The combined organic phases were dried with anhydrous sodium sulfate, filtered and concentrated under reduced pressure to give a light yellow solid product (0.43 g, 69% yield).
References
[1] Patent: US2005/245524, 2005, A1. Location in patent: Page/Page column 98-99
5-Methoxy-2-methyl benzeneboronic acid Preparation Products And Raw materials
Raw materials
Preparation Products
5-Methoxy-2-methyl benzeneboronic acid Suppliers
- Tel
- 400-0628126 15697568869;
- sales-team@aobchem.com.cn
- Country
- China
- ProdList
- 10000
- Advantage
- 58
- Tel
- 13526569071
- sales@leadmedpharm.com
- Country
- China
- ProdList
- 7892
- Advantage
- 64
- Tel
- 021-54306202 13764082696
- info@hanhongsci.com
- Country
- China
- ProdList
- 42934
- Advantage
- 64
- Tel
- 18270980682
- Fax
- 021 51613951
- mlcheng@sunwaypharm.cn
- Country
- China
- ProdList
- 8669
- Advantage
- 57
- Tel
- 150-2103-5486 18017383231
- Fax
- qq:2817624287
- 983544897@qq.com
- Country
- China
- ProdList
- 9342
- Advantage
- 55
- Tel
- 021-60343070
- Fax
- 021-35122006
- Country
- China
- ProdList
- 12740
- Advantage
- 55
- Tel
- 400-164-7117 13681763483
- Fax
- +86-21-61629029
- product02@bidepharm.com
- Country
- China
- ProdList
- 39966
- Advantage
- 60
- Tel
- 18681884732
- Fax
- 021-51632502
- 2245256225@qq.com
- Country
- China
- ProdList
- 1728
- Advantage
- 50
- Tel
- 18602194589
- lincy-110@163.com
- Country
- China
- ProdList
- 863
- Advantage
- 58
- Tel
- 010-010-15313962280 15313962280
- Fax
- 010-51669040
- 3004509780@qq.com
- Country
- China
- ProdList
- 824
- Advantage
- 55
- Tel
- 0371-86658258
- Fax
- 0371-60996044
- info@coreychem.com
- Country
- China
- ProdList
- 10453
- Advantage
- 58
- Tel
- 021-61312847; 18021002903
- Fax
- QQ:3008007432
- 3008007409@qq.com
- Country
- China
- ProdList
- 71826
- Advantage
- 60
- Tel
- 028-83379370 13880556291
- Fax
- 028-87747383
- tcy@tcypharm.com
- Country
- China
- ProdList
- 7218
- Advantage
- 58
- Tel
- 571-89925085
- Fax
- 0086-571-89925065
- sales@amadischem.com
- Country
- China
- ProdList
- 131957
- Advantage
- 58
- Tel
- 021-34053660
- Fax
- QQ:2881074831
- sale2@labgogo.com
- Country
- China
- ProdList
- 2018
- Advantage
- 58
- Tel
- 025-66096098 3165145969
- Fax
- QQ3165145969
- sales@accoronpharm.com
- Country
- China
- ProdList
- 3924
- Advantage
- 55
- Tel
- 400-711-5280 86-571-81025280
- Fax
- 86-571-85806285
- sales@molcore.com
- Country
- China
- ProdList
- 9967
- Advantage
- 58
- Tel
- +86-(0)57185586718; +8613336195806
- Fax
- +86-571-85864795
- sales@capot.com
- Country
- China
- ProdList
- 29735
- Advantage
- 60
- Tel
- 025-58859352 18068836627
- Fax
- (5)02557626880
- dt3@aikonchem.com
- Country
- China
- ProdList
- 15493
- Advantage
- 58
- Tel
- 400-6387771-6039 18920764717
- sales@heowns.com
- Country
- China
- ProdList
- 23771
- Advantage
- 60
- Tel
- 15958048562
- Fax
- -
- 2032153781@qq.com
- Country
- China
- ProdList
- 463
- Advantage
- 58
- Tel
- 025-87138562
- sales@popebiotech.com
- Country
- China
- ProdList
- 413
- Advantage
- 58
- Tel
- 4009004166/18616739031 18616739031
- 3007523370@qq.com
- Country
- China
- ProdList
- 52687
- Advantage
- 58
- Tel
- 021-33758897
- sales@scochem.com
- Country
- China
- ProdList
- 1596
- Advantage
- 58
- Tel
- +86-0571-88938639 +8617705817739
- Fax
- +86-571-88938652,+86-571- 88492614
- info@dycnchem.com
- Country
- China
- ProdList
- 52846
- Advantage
- 58
- Tel
- +86-0371-86658258 +8613203830695
- Fax
- 0086-371-86658258
- factory@coreychem.com
- Country
- China
- ProdList
- 29798
- Advantage
- 58
- Tel
- 0519-68985668 13685222090
- Fax
- qq735434464
- sales@kechem.cn
- Country
- China
- ProdList
- 26028
- Advantage
- 58
- Tel
- 021-58432009 400-005-6266
- Fax
- 021-58436166
- marketing@energy-chemical.com
- Country
- China
- ProdList
- 44918
- Advantage
- 58
- Tel
- 15662379806
- 845423637@qq.com
- Country
- China
- ProdList
- 1633
- Advantage
- 58
- Tel
- 400-8210725 4008210725
- malulu@leyan.com
- Country
- China
- ProdList
- 40000
- Advantage
- 58
- Tel
- 400-1647117 13681763483
- product02@bidepharm.com
- Country
- China
- ProdList
- 59936
- Advantage
- 58
- Tel
- 15870833005
- 2232044025@qq.com
- Country
- China
- ProdList
- 8206
- Advantage
- 58
- Tel
- 400-6005915
- sales@picasso-e.com
- Country
- China
- ProdList
- 39665
- Advantage
- 58
- Tel
- +86-0371-55074660
- Lingzhiyue@aliyun.com
- Country
- China
- ProdList
- 4739
- Advantage
- 58
- Tel
- 0371-53399770 18037166334
- 2853031800@qq.com
- Country
- China
- ProdList
- 5891
- Advantage
- 58
- Tel
- 13820634634 18622687818
- 405423999@qq.com
- Country
- China
- ProdList
- 3298
- Advantage
- 58
- Tel
- 15301358979
- 37303017@qq.com
- Country
- China
- ProdList
- 494
- Advantage
- 58
- Tel
- 010-50973130 17801761073
- Gsiyu@solarbio.com
- Country
- China
- ProdList
- 50751
- Advantage
- 58
- Tel
- 13818960522
- 525712405@qq.com
- Country
- China
- ProdList
- 220
- Advantage
- 58
- Tel
- 021-57520305 13795461237
- zhuruyan@jskchem.com
- Country
- China
- ProdList
- 49234
- Advantage
- 58
- Tel
- 4000255188
- marketing@pharmablock.com
- Country
- China
- ProdList
- 9126
- Advantage
- 58
- Tel
- 0635-893290 18663513896;
- 28698871@qq.com
- Country
- China
- ProdList
- 8022
- Advantage
- 58
- Tel
- 400-6206333 13167063860
- anhua.mao@aladdin-e.com
- Country
- China
- ProdList
- 48457
- Advantage
- 58
- Tel
- 86-13349903920 13349903920
- Fax
- -
- 869523959@qq.com
- Country
- China
- ProdList
- 9626
- Advantage
- 58
- Tel
- 029-029-81148929 17791530722
- 1049@dideu.com
- Country
- China
- ProdList
- 10011
- Advantage
- 58
- Tel
- 15866847540
- dengyt2000@163.com
- Country
- China
- ProdList
- 4100
- Advantage
- 58
- Tel
- 18317763565; 18317763565
- 18317763565@163.com
- Country
- China
- ProdList
- 9516
- Advantage
- 58
- Tel
- +86-512-68323658 +86-18168183658
- sales1@artkmedchem.com
- Country
- China
- ProdList
- 39002
- Advantage
- 58
- Tel
- +86-2552131256 +86-18251840740
- sales@bicbiotech.com
- Country
- China
- ProdList
- 5994
- Advantage
- 58
- Tel
- +86-571-87711850
- market18@leapchem.com
- Country
- China
- ProdList
- 43339
- Advantage
- 58
View Lastest Price from 5-Methoxy-2-methyl benzeneboronic acid manufacturers
- Product
- 5-Methoxy-2-methyl benzeneboronic acid 617689-07-3
- Price
- US $1.00/g
- Min. Order
- 1g
- Purity
- 99%
- Supply Ability
- 200kg
- Release date
- 2019-12-26