5-FLUORO-M-XYLENE

Product Name: 5-FLUORO-M-XYLENE
CAS No.: 461-97-2
Chemical Name: 5-FLUORO-M-XYLENE
Synonyms: Fluoroxylene4;5-FLUORO-M-XYLENE;5-fluorometa xylene;5-Fluoro-m-xylene,97%;3,5-DIMETHYLFLUOROBENZENE;1-FLUORO-3,5-DIMETHYLBENZENE;1,3-dimethyl-5-fluorobenzene;3,5-Dimethylfluorobenzene98%;3,5-Dimethylfluorobenzene 98%;Benzene, 1-fluoro-3,5-dimethyl-
CBNumber: CB8100166
Molecular Formula: C8H9F
Formula Weight: 124.16
MOL File: 461-97-2.mol

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5-FLUORO-M-XYLENE Property

Boiling point:: 145 °C
Density: 0.98
refractive index: 1.475
Flash point:: 35°C
storage temp.: Sealed in dry,Room Temperature
form: liquid
color: Colourless to light yellow
BRN: 1926374
InChI: InChI=1S/C8H9F/c1-6-3-7(2)5-8(9)4-6/h3-5H,1-2H3
InChIKey: RCWIWNUVHNAUQC-UHFFFAOYSA-N
SMILES: C1(F)=CC(C)=CC(C)=C1
CAS DataBase Reference: 461-97-2(CAS DataBase Reference)
NIST Chemistry Reference: 5-Fluoro-m-xylene(461-97-2)

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Safety

Hazard Codes: F,Xi
Risk Statements: 10-36/37/38
Safety Statements: 16-33-36/37/39-26-23
RIDADR: 1993
Hazard Note: Flammable
HazardClass: 3
PackingGroup: III
HS Code: 29039990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H226Flammable liquid and vapour

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

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N-Bromosuccinimide Price

TRC

Product number: F593810
Product name: 5-Fluoro-m-xylene
Packaging: 25g
Price: $745
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0016295
Product name: 1-FLUORO-3,5-DIMETHYLBENZENE
Purity: 95.00%
Packaging: 5G
Price: $810.81
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0016295
Product name: 1-FLUORO-3,5-DIMETHYLBENZENE
Purity: 95.00%
Packaging: 25G
Price: $1264.73
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: HCH0016295
Product name: 1-FLUORO-3,5-DIMETHYLBENZENE
Purity: 95.00%
Packaging: 50G
Price: $2643.8
Updated: 2021/12/16

Frontier Specialty Chemicals

Product number: JK100082
Product name: 5-Fluoro-m-xylene
Purity: 99%
Packaging: 5g
Price: $145
Updated: 2021/12/16

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5-FLUORO-M-XYLENE Chemical Properties,Usage,Production

Chemical Properties

clear colorless to slightly yellow liquid

Uses

5-Fluoro-m-xylene is used in the synthesis of iminodiaziridines. Also used in the preparation of halogen-containing polyisophthalamides.

Synthesis

108-69-0

461-97-2

The general procedure for the synthesis of 3,5-dimethylfluorobenzene from 1-amino-3,5-xylene is as follows: 1. Continuous diazotization step: - Preparatory material A: 1-amino-3,5-xylene (100 mmol), fluoboric acid (120 mmol) and hydrochloric acid (180 mmol) were dissolved in 50 mL of water. - Prepare Material B: Dissolve sodium nitrite (105 mmol) in 50 mL of water. - Material A and Material B were each pumped through a T-fitting into a reaction tube at a flow rate of 4 mL/min at 25 °C. The mixture flowed through the outlet and was collected in a cooling vessel. Vigorous stirring was maintained. - The reaction mixture was cooled to -5 °C and the solid was collected by filtration. The solid was washed with methanol and subsequently dried under vacuum to give diazonium tetrafluoroborate. 2. Continuous fluorination step: - The diazonium tetrafluoroborate prepared above was suspended in 300 mL of co-solvent and introduced continuously into the reaction tube at a flow rate of 4 mL/min. - The reaction was maintained at the set temperature for 1 min, followed by cooling in the tandem tube. - The reaction solution was collected and washed with aqueous NaOH and water to give an almost colorless liquid of 3,5-dimethylfluorobenzene.

References

[1] Tetrahedron Letters, 2013, vol. 54, # 10, p. 1261 - 1263
[2] Chemistry - A European Journal, 2008, vol. 14, # 18, p. 5465 - 5481
[3] Journal of the American Chemical Society, 1994, vol. 116, # 4, p. 1324 - 1336
[4] Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1986, p. 169 - 174
[5] Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1984, # 3, p. 529 - 532

5-FLUORO-M-XYLENE Preparation Products And Raw materials

Raw materials

Preparation Products

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5-FLUORO-M-XYLENE Suppliers

Belgium 2 Canada 1 China 147 France 2 Germany 8 India 4 Italy 1 Switzerland 1 The Netherlands 1 United Kingdom 20 United States 35 Global 222

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View Lastest Price from 5-FLUORO-M-XYLENE manufacturers

Career Henan Chemical Co

Product: 5-FLUORO-M-XYLENE 461-97-2
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100kg
Release date: 2019-07-11

461-97-2, 5-FLUORO-M-XYLENERelated Search:

3-FLUORO-5-(TRIFLUOROMETHYL)BENZYL BROMIDE 3-FLUORO-5-(TRIFLUOROMETHYL)BENZONITRILE 3-FLUORO-5-(TRIFLUOROMETHYL)BENZALDEHYDE 3-Fluoro-5-(trifluoromethyl)benzoic acid 3'-FLUORO-5'-(TRIFLUOROMETHYL)PROPIOPHENONE 3'-FLUORO-5'-(TRIFLUOROMETHYL)ACETOPHENONE 1-Fluoro-3,5-dimethyl-2-nitrobenzene, 98% 3-FLUORO-5-(TRIFLUOROMETHYL)BENZAMIDE 3-FLUORO-5-(TRIFLUOROMETHYL)BENZYLAMINE 8-(CHLOROMETHYL)-6-FLUORO-4H-1,3-BENZODIOXINE 2,4,5,6-Tetrafluoroisophthalonitrile 3-FLUORO-5-(TRIFLUOROMETHYL)PHENYLACETONITRILE Flumequine 3-Fluoro-5-(trifluoroMethyl)phenylacetic acid 3-FLUORO-5-(TRIFLUOROMETHYL)BENZOPHENONE TETRAFLUOROISOPHTHALIC ACID 3-FLUORO-5-(TRIFLUOROMETHYL)BENZOYL CHLORIDE 5-FLUORO-M-XYLENE

3,5-DIMETHYLFLUOROBENZENE

5-FLUORO-M-XYLENE

1-FLUORO-3,5-DIMETHYLBENZENE

1,3-Dimethyl-5-fluorobenzene~3,5-Dimethylfluorobenzene

Fluoroxylene4

5-Fluoro-m-xylene,97%

5-Fluoro-m-xylene,1,3-Dimethyl-5-fluoroBenzene

1,3-dimethyl-5-fluorobenzene

3,5-Dimethylfluorobenzene 98%

3,5-Dimethylfluorobenzene98%

1,3-Dimethyl-5-fluorobenzene 98%

Benzene, 1-fluoro-3,5-dimethyl-

5-fluorometa xylene

461-97-2

C8H9F

Aromatic Halides (substituted)

Halogen toluene

john's