CIS-3-CARBOMETHOXYCYCLOPENTANE-1-CARBOXYLIC ACID
- Product Name
- CIS-3-CARBOMETHOXYCYCLOPENTANE-1-CARBOXYLIC ACID
- CAS No.
- 96382-85-3
- Chemical Name
- CIS-3-CARBOMETHOXYCYCLOPENTANE-1-CARBOXYLIC ACID
- Synonyms
- -rel-3-(Methoxycarbonyl);(1R,3S)-rel-3-(Methoxycarbonyl)cyclopen;CIS-3-CARBOMETHOXYCYCLOPENTANE-1-CARBOXYLIC ACID;cis-3-(methoxycarbonyl)cyclopentanecarboxylic acid;cis-3-(methoxycarbonyl)cyclopentane-1-carboxylic acid;cis-1,3-Cyclopentanedicarboxylic acid monomethyl ester;(1R,3S)-rel-3-(Methoxycarbonyl)cyclopentanecarboxylic acid;(1R,3S)-rel-1,3-Cyclopentanedicarboxylic acid 1-methyl ester;rel-(1S,3R)-3-(Methoxycarbonyl)cyclopentane-1-carboxylic acid;1,3-Cyclopentanedicarboxylic acid, 1-methyl ester, (1R,3S)-rel-
- CBNumber
- CB8116015
- Molecular Formula
- C8H12O4
- Formula Weight
- 172.18
- MOL File
- 96382-85-3.mol
CIS-3-CARBOMETHOXYCYCLOPENTANE-1-CARBOXYLIC ACID Property
- Boiling point:
- 286℃
- Density
- 1.242
- Flash point:
- 115℃
- storage temp.
- Storage temp. 2-8°C
- pka
- 4.51±0.40(Predicted)
- Appearance
- Colorless to light yellow Liquid
Safety
- HS Code
- 2917200090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
N-Bromosuccinimide Price
- Product number
- M341638
- Product name
- (1R,3S)-rel-3-(Methoxycarbonyl)cyclopentanecarboxylicacid
- Packaging
- 50mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- 086431
- Product name
- cis-3-Carbomethoxycyclopentane-1-carboxylic acid
- Purity
- 97%
- Packaging
- 1g
- Price
- $249
- Updated
- 2021/12/16
- Product number
- 086431
- Product name
- cis-3-Carbomethoxycyclopentane-1-carboxylic acid
- Purity
- 97%
- Packaging
- 2g
- Price
- $383
- Updated
- 2021/12/16
- Product number
- 18007
- Product name
- Cis-3-Carbomethoxycyclopentane-1-carboxylicacid
- Purity
- 97%
- Packaging
- 1g
- Price
- $383
- Updated
- 2021/12/16
- Product number
- 18007
- Product name
- Cis-3-Carbomethoxycyclopentane-1-carboxylicacid
- Purity
- 97%
- Packaging
- 2g
- Price
- $647
- Updated
- 2021/12/16
CIS-3-CARBOMETHOXYCYCLOPENTANE-1-CARBOXYLIC ACID Chemical Properties,Usage,Production
Synthesis
6054-16-6
124-41-4
84545-00-6
To a methanolic (35 mL) suspension of cis-1,3-cyclopentanedicarboxylic anhydride (3.0 g, 21 mmol) was added sodium methanolate (1.2 g, 21 mmol) in batches at room temperature. After 1 h of reaction, the resulting clarified solution was evaporated, alkalized with 1 M NaOH solution and washed twice with ethyl acetate (EtOAc). Subsequently, the aqueous layer was acidified with 1 N HCl to pH about 2 and extracted with dichloromethane (CH2Cl2, 3 x 25 mL). The organic phases were combined, dried over anhydrous sodium sulfate (Na2SO4) and evaporated to afford cis-3-(methoxycarbonyl)cyclopentanecarboxylic acid (2.7 g, 75%) as a clear oil. The product was characterized by 1H NMR (400 MHz, CDCl3): δ 3.70 (s, 3H), 2.76-2.94 (m, 2H), 2.28 (dt, J = 13.3, 8.0 Hz, 1H), 2.15 (dt, J = 13.3, 9.1 Hz, 1H), 1.89-2.07 (m, 4H). The mass spectrum (APCI+) showed a m/z of 173.2 (C8H12O4, [M+H]+).
References
[1] Patent: WO2015/166373, 2015, A1. Location in patent: Page/Page column 147; 148
CIS-3-CARBOMETHOXYCYCLOPENTANE-1-CARBOXYLIC ACID Preparation Products And Raw materials
Raw materials
Preparation Products
CIS-3-CARBOMETHOXYCYCLOPENTANE-1-CARBOXYLIC ACID Suppliers
- Tel
- 18210857532; 18210857532
- Fax
- 86-10-82849933
- jkinfo@jkchemical.com
- Country
- China
- ProdList
- 96815
- Advantage
- 76
- Tel
- 0519-85528066 13775048983
- Fax
- 0519-85528066
- sales@hopschem.com
- Country
- China
- ProdList
- 31553
- Advantage
- 55
- Tel
- 571-89925085
- Fax
- 0086-571-89925065
- sales@amadischem.com
- Country
- China
- ProdList
- 131957
- Advantage
- 58
- Tel
- 025-66113011 13155353615
- Fax
- (7)02557626880
- qzhang@aikonchem.com
- Country
- China
- ProdList
- 15394
- Advantage
- 58
- Tel
- +86-400-002-6226 +86-13028896684;
- sales@rrkchem.com
- Country
- China
- ProdList
- 57422
- Advantage
- 58
- Tel
- 028-84641798 18782128315
- 3302391190@qq.com
- Country
- China
- ProdList
- 9797
- Advantage
- 55
- Tel
- +8615866703830
- figo.gao@foxmail.com
- Country
- China
- ProdList
- 8497
- Advantage
- 58
- Tel
- +86-27-50766799 +8618062016861
- contact@labnetwork.com
- Country
- China
- ProdList
- 19987
- Advantage
- 58
- Tel
- 15990591583
- Fax
- qq: 1050376806 mailbox : sales@nbpharmabridge.com
- Country
- China
- ProdList
- 6109
- Advantage
- 58
- Tel
- 021-51698675
- sales@jiejiegroup.com
- Country
- China
- ProdList
- 8019
- Advantage
- 58