5-FLUORO-1,3-DIMETHYLURACIL

Product Name: 5-FLUORO-1,3-DIMETHYLURACIL
CAS No.: 3013-92-1
Chemical Name: 5-FLUORO-1,3-DIMETHYLURACIL
Synonyms: Fluorouracil-001;Fluorouracil Impurity 34;1,3-dimethyl-5-fluorouracil;5-FLUORO-1,3-DIMETHYLURACIL;5-Fluoro-1,3-dimethyluracil 99%;5-fluoro-1,3-dimethylpyrimidine-2,4-dione;5-fluoro-1,3-diMethylpyriMidine-2,4(1H,3H)-dione;2,4(1H,3H)-Pyrimidinedione,5-fluoro-1,3-dimethyl-;1,3-Dimethyl-5-fluorouracil, 2,4-Dihydroxy-1,3-dimethyl-5-fluoropyrimidine
CBNumber: CB8116404
Molecular Formula: C6H7FN2O2
Formula Weight: 158.13
MOL File: 3013-92-1.mol

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5-FLUORO-1,3-DIMETHYLURACIL Property

Melting point:: 132-134 °C(lit.)
Boiling point:: 182.5±50.0 °C(Predicted)
Density: 1.37±0.1 g/cm3(Predicted)
pka: -4.07±0.40(Predicted)
BRN: 880396
InChI: 1S/C6H7FN2O2/c1-8-3-4(7)5(10)9(2)6(8)11/h3H,1-2H3
InChIKey: DDEWVRFHURYTHA-UHFFFAOYSA-N
SMILES: CN1C=C(F)C(=O)N(C)C1=O

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Safety

Safety Statements: 22-24/25
WGK Germany: 3
Storage Class: 11 - Combustible Solids

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 406864
Product name: 5-Fluoro-1,3-dimethyluracil
Purity: 99%
Packaging: 10g
Price: $151
Updated: 2023/06/20

AK Scientific

Product number: 1409AQ
Product name: 5-Fluoro-1,3-dimethyluracil
Packaging: 10g
Price: $212
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: NUC0002048
Product name: 5-FLUORO-1,3-DIMETHYLURACIL
Purity: 95.00%
Packaging: 10G
Price: $1219.42
Updated: 2021/12/16

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5-FLUORO-1,3-DIMETHYLURACIL Chemical Properties,Usage,Production

Uses

5-Fluoro-1,3-dimethyluracil may be used as starting material in the following processes:

Regioselective synthesis of tetrahydronaphthocyclobuta[1,2-d]pyrimidinediones.
To synthesize 5-bis(ethoxycarbonyl)methyl-1,3-dimethyluracil.
To synthesize new highly conjugated propenylidene derivatives via aromatic Paterno-Buchi type cycloaddition with 1-methoxynaphthalene.

Synthesis Reference(s)

Tetrahedron, 46, p. 3093, 1990 DOI: 10.1016/S0040-4020(01)88400-3

General Description

Oxidation of 5-fluoro-1,3-dimethyluracil (5-FDMU) with m-chloroperbenzoic acid has been described. It is reported as antineoplastic drug. On photoirradiation, 5-fluoro-1,3-dimethyluracil yields the trans-anti cyclobutane dimer and the cis-syn cyclobutane dimer. UV irradiation of 5-FDMU and naphthalene in a protic medium affords 5-(1-naphthyl)uracil, while in aprotic media it undergoes stereoselective 1,4-cycloaddition reaction to give a barrelene derivative. The thermochemical parameters of 5-FDMU has been determined. It reacts with substituted benzenes in the presence of trifluoroacetic acid to generate 5-aryl-1,3-dimethyluracils via photosubstitution.

5-FLUORO-1,3-DIMETHYLURACIL Preparation Products And Raw materials

Raw materials

Preparation Products

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5-FLUORO-1,3-DIMETHYLURACIL Suppliers

China 23 Russia 1 Switzerland 1 United States 2 Global 27

Shanghai Hanhong Scientific Co.,Ltd.

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View Lastest Price from 5-FLUORO-1,3-DIMETHYLURACIL manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: Fluorouracil-001 3013-92-1
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20T
Release date: 2020-05-14

3013-92-1, 5-FLUORO-1,3-DIMETHYLURACILRelated Search:

5-fluoro-3-methyl-1H-pyrimidine-2,4-dione 1,3-Dimethyluracil 5-Fluoropyrimidine (5-FLUORO-2,6-DIOXO-3-TETRAHYDROFURAN-2-YL-3,6-DIHYDROPYRIMIDIN-1(2H)-YL)ACETIC ACID ETHYL [5-FLUORO-3-(4-METHOXY-3-NITROBENZYL)-2,6-DIOXO-3,6-DIHYDROPYRIMIDIN-1(2H)-YL]ACETATE 1-acetyl-3,2-toluyl-5-fluorouracil 5-FLUORO-1,3-DIMETHYLURACIL FD 1 3-ALLYL-5-FLUORO-1-(4-METHOXY-3-NITROBENZYL)PYRIMIDINE-2,4(1H,3H)-DIONE EMITEFUR

1,3-Dimethyl-5-fluorouracil, 2,4-Dihydroxy-1,3-dimethyl-5-fluoropyrimidine

5-fluoro-1,3-diMethylpyriMidine-2,4(1H,3H)-dione

5-FLUORO-1,3-DIMETHYLURACIL

1,3-dimethyl-5-fluorouracil

2,4(1H,3H)-Pyrimidinedione,5-fluoro-1,3-dimethyl-

Fluorouracil-001

5-Fluoro-1,3-dimethyluracil 99%

5-fluoro-1,3-dimethylpyrimidine-2,4-dione

Fluorouracil Impurity 34

3013-92-1

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