(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%

Reaction

Product Name: (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
CAS No.: 133545-24-1
Chemical Name: (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
Synonyms: SL-A102-1;(R)-p-Tol-MeOBIPHEP;(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl;(R)-(+)-2,2''-Bis(di-p-tolylphosphino)-6,6''-dimethoxy-1,1''-biphenyl;(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(4-methylphenyl)phosphine;(R)-(6,6'-dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(di-p-tolylphosphane);(R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(4-methylphenyl)phosphine];(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%;bis(4-methylphenyl)-[2-[2-(4-methylphenyl)phosphanylphenyl]phenyl]phosphane;(R)-(+)-2,2''-BIS(DI-P-TOLYLPHOSPHINO)-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%
CBNumber: CB81180978
Molecular Formula: C42H40O2P2
Formula Weight: 638.71
MOL File: 133545-24-1.mol

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(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Property

Boiling point:: 685.8±55.0 °C(Predicted)
form: solid
color: white to pale yellow

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Safety

WGK Germany: 3
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Strem Chemicals

Product number: 15-0156
Product name: (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Purity: min.97%
Packaging: 100mg
Price: $99
Updated: 2026/04/30

Strem Chemicals

Product number: 15-0156
Product name: (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Purity: min.97%
Packaging: 500mg
Price: $366
Updated: 2026/04/30

Strem Chemicals

Product number: 15-0156
Product name: (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Purity: min.97%
Packaging: 2g
Price: $1244
Updated: 2026/04/30

Strem Chemicals

Product number: 15-0156
Product name: (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Purity: min.97%
Packaging: 10g
Price: $4969
Updated: 2026/04/30

Strem Chemicals

Product number: 15-0156
Product name: (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Packaging: 100mg
Price: $96
Updated: 2024/03/01

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(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Chemical Properties,Usage,Production

Reaction

In many respects the catalytic profile of the MeOBIPHEP ligands is similar to that of other atropisomeric diphosphines such as binap and its many analogs. The nature of the PR2 group strongly influences the catalytic performance of the metal complexes. The rhodium and ruthenium MeO-BIPHEP catalysts are highly effective for the hydrogenation of various C=O, C=C and C=N bonds and several synthetically useful C-C coupling reactions.

Ru and Ir catalyzed dynamic kinetic resolution for the synthesis of hydroxy, amino acid derivatives.
Ru-catalyzed asymmetric hydrogenation of ketones and alkenes.
Ir catalyzed enantioselective hydrogenation of heteroaromatic compounds.
Conjugate addition using 2-heteroaryl titanates and zinc reagents.

Chemical Properties

Off-white powder

Uses

Atropisomeric MeOBIPHEP ligands

General Description

sold in collaboration with Solvias AG

(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Preparation Products And Raw materials

Raw materials

Preparation Products

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(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Suppliers

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133545-24-1, (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%Related Search:

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(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%

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(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl

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(R)-(+)-2,2''-Bis(di-p-tolylphosphino)-6,6''-dimethoxy-1,1''-biphenyl

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(R)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis[bis(4-methylphenyl)phosphine], CAS 133545-24-1

(R)-(6,6'-dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(di-p-tolylphosphane)

133545-24-1

C42H40O2P2

Chiral Phosphine

MeOBIPHEP Series