ChemicalBook > CAS DataBase List > Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)
Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)
Reaction- Product Name
- Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)
- CAS No.
- 220114-01-2
- Chemical Name
- Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)
- Synonyms
- RuCl2[(S)-xylbinap][(S)-daipen];RuCl2[(S)-(DM-BINAP)][(S)-DAIPEN];Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II);Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(S)-xylbinap][(S)-daipen]
- CBNumber
- CB81181076
- Molecular Formula
- C71H74Cl2N2O2P2Ru
- Formula Weight
- 0
- MOL File
- 220114-01-2.mol
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Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) Property
- Melting point:
- 210-212 °C (decomp)
- storage temp.
- 2-8°C
- form
- Powder
- color
- orange
- Sensitive
- air sensitive
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 693227
- Product name
- RuCl2[(S)-(DM-BINAP)][(S)-DAIPEN]
- Packaging
- 100mg
- Price
- $60.4
- Updated
- 2023/01/07
TCI Chemical
- Product number
- R0132
- Product name
- RuCl2[(S)-xylbinap][(S)-daipen]
- Packaging
- 200mg
- Price
- $80
- Updated
- 2024/03/01
TCI Chemical
- Product number
- R0132
- Product name
- RuCl2[(S)-xylbinap][(S)-daipen]
- Packaging
- 1g
- Price
- $271
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 44-0213
- Product name
- Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(S)-xylbinap][(S)-daipen]
- Packaging
- 250mg
- Price
- $64
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 44-0213
- Product name
- Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(S)-xylbinap][(S)-daipen]
- Packaging
- 1g
- Price
- $190
- Updated
- 2024/03/01
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Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) Chemical Properties,Usage,Production
Reaction
Highly active catalyst for hydrogenation of simple ketones giving high enantioselectivity when sterically unsymmetrical ketones such as acetophenone, heteroaryl ketones, benzophenones, cyclopropyl ketones, and cyclohexyl ketones are substrates. Ee's are enhanced with XylBINAP relative to BINAP. The otherwise poorly bonded ketone is held in the transition state by hydrogen bonding to the protic bidentate amine.
Carbonyl groups are selectively reduced even when olefins exist in the same molecule.
In the presence of strong base, and catalyst, simple ketones, having substituents at the α-position, may be induced to undergo dynamic kinectic resolution during their hydrogenation to produce two chiral carbon centers in high yield.
Uses
Catalyst for:
- Preparation of cyclometalated ruthenium 1,1-dianisyl-2-isopropyl-1,2-ethylenediamine complexes via asymmetric hydrogenation of ketones
- Enantioselective hydrogenation of an α-alkoxy substituted ketone with chiral ruthenium (phosphinoferrocenyl)oxazoline complexes
- Nonclassical asymmeteric hydrogen transfer between alcohols and carbonyl compounds
- Asymmetric hydrogenation of amino and heteroaromatic ketones
- Pharmacologically active substituted oxazolidinone used as NPC1L1 ligand for inhibition of cholesterol absorption
Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) Preparation Products And Raw materials
Raw materials
Preparation Products
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Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) Suppliers
- Tel
- 03-36680489
- Fax
- 03-3668-0520
- Sales-JP@TCIchemicals.com
- Country
- Japan
- ProdList
- 28387
- Advantage
- 80
- Tel
- --
- Fax
- --
- finechemicals@takasago.com
- Country
- Japan
- ProdList
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220114-01-2, Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)Related Search:
(S)-Daipen
2,2-BIS(4-METHOXYLPHENYL)ETHYLAMINE
(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)
(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl
DICHLORO[(S)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(S)-1,1-BIS(P-METHOXYPHENYL)-2-ISOPROPYLETHANE-1,2-DIAMINE]RUTHENIUM(II)
(2S,3S)-(-)-2,3-BUTANEDIAMINE DIHYDROCHLORIDE
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
(S)-(-)-2-AMINO-3-METHYL-1,1-DIPHENYLBUTANE
2-(4-METHOXYPHENYL)-2-PHENYLETHYLAMINE HYDROCHLORIDE