Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4
Reaction- Product Name
- Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4
- CAS No.
- 909389-99-7
- Chemical Name
- Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4
- Synonyms
- Rh2(S-PTAD)4;Rh2(S-PTAD)4;(2S)-2-(1-adamantyl)-2-(1,3-dioxoisoindol-2-yl)acetic acid,rhodium;Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II);Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4;Tetrakis[(S)-2-(1-adamantyl)-2-(1,3-dioxo-2-isoindolinyl)acetic Acid] Dirhodium(II)
- CBNumber
- CB81181142
- Molecular Formula
- C80H80N4O16Rh2
- Formula Weight
- 1559.34
- MOL File
- 909389-99-7.mol
Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4 Property
- Melting point:
- >300°C
- alpha
- +39.1 (c 0.2, CHCl3)
- form
- Powder
- color
- green
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
N-Bromosuccinimide Price
- Product number
- 45-2071
- Product name
- Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II) Rh2(S-PTAD)4
- Packaging
- 50mg
- Price
- $101
- Updated
- 2024/03/01
- Product number
- 45-2071
- Product name
- Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II) Rh2(S-PTAD)4
- Packaging
- 250mg
- Price
- $407
- Updated
- 2024/03/01
- Product number
- ING0013283
- Product name
- TETRA-KIS-[(S)-(+)-(1-ADAMANTYL)-(N-PHTHALIMIDO)ACETATO]DIRHODIUM-(II)
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $503.48
- Updated
- 2021/12/16
- Product number
- CM102877
- Product name
- Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)
- Purity
- 95%
- Packaging
- 250mg
- Price
- $845
- Updated
- 2021/12/16
- Product number
- CM102877
- Product name
- Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)
- Purity
- 95%
- Packaging
- 50mg
- Price
- $212
- Updated
- 2021/12/16
Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4 Chemical Properties,Usage,Production
Reaction
- Enantioselective reactions of carbenoids and olefins.
- Enantioselective C–H insertion reactions of carbenoids.
- Enantioselective oxygen transfer from diazosulfonylamidines.
Uses
This chiral Rh(II) dimer was developed in the Davies lab to perform asymmetric carbene and nitrene reactions (C-H insertion, cyclopropanation, aziridination, C-H amination) with high regio- and stereocontrol.
Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4 Preparation Products And Raw materials
Raw materials
Preparation Products
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