Reaction
ChemicalBook > CAS DataBase List > Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4

Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4

Reaction
Product Name
Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4
CAS No.
909389-99-7
Chemical Name
Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4
Synonyms
Rh2(S-PTAD)4;Rh2(S-PTAD)4;(2S)-2-(1-adamantyl)-2-(1,3-dioxoisoindol-2-yl)acetic acid,rhodium;Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II);Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4;Tetrakis[(S)-2-(1-adamantyl)-2-(1,3-dioxo-2-isoindolinyl)acetic Acid] Dirhodium(II)
CBNumber
CB81181142
Molecular Formula
C80H80N4O16Rh2
Formula Weight
1559.34
MOL File
909389-99-7.mol
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Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4 Property

Melting point:
>300°C
alpha 
+39.1 (c 0.2, CHCl3)
form 
Powder
color 
green
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Strem Chemicals
Product number
45-2071
Product name
Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II) Rh2(S-PTAD)4
Packaging
50mg
Price
$101
Updated
2024/03/01
Strem Chemicals
Product number
45-2071
Product name
Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II) Rh2(S-PTAD)4
Packaging
250mg
Price
$407
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
ING0013283
Product name
TETRA-KIS-[(S)-(+)-(1-ADAMANTYL)-(N-PHTHALIMIDO)ACETATO]DIRHODIUM-(II)
Purity
95.00%
Packaging
5MG
Price
$503.48
Updated
2021/12/16
Chemenu
Product number
CM102877
Product name
Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)
Purity
95%
Packaging
250mg
Price
$845
Updated
2021/12/16
Chemenu
Product number
CM102877
Product name
Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)
Purity
95%
Packaging
50mg
Price
$212
Updated
2021/12/16
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Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4 Chemical Properties,Usage,Production

Reaction

  1. Enantioselective reactions of carbenoids and olefins.
  2. Enantioselective C–H insertion reactions of carbenoids.
  3. Enantioselective oxygen transfer from diazosulfonylamidines. 

Uses

This chiral Rh(II) dimer was developed in the Davies lab to perform asymmetric carbene and nitrene reactions (C-H insertion, cyclopropanation, aziridination, C-H amination) with high regio- and stereocontrol.

Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4 Preparation Products And Raw materials

Raw materials

Preparation Products

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Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4 Suppliers

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909389-99-7, Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4Related Search:


  • Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)Rh2(S-PTAD)4
  • Rh<sub>2</sub>(S-PTAD)<sub>4</sub>
  • Tetrakis[(S)-(+)-(1-adamantyl)-(N-phthalimido)acetato]dirhodium(II)
  • Rh2(S-PTAD)4
  • (2S)-2-(1-adamantyl)-2-(1,3-dioxoisoindol-2-yl)acetic acid,rhodium
  • Tetrakis[(S)-2-(1-adamantyl)-2-(1,3-dioxo-2-isoindolinyl)acetic Acid] Dirhodium(II)
  • 909389-99-7
  • C80H80N4O16Rh2
  • organometallic complex
  • Rh