ChemicalBook > CAS DataBase List > Methyl 3-methoxyacrylate

Methyl 3-methoxyacrylate

Product Name: Methyl 3-methoxyacrylate
CAS No.: 34846-90-7
Chemical Name: Methyl 3-methoxyacrylate
Synonyms: METHYL TRANS-3-METHOXYACRYLATE;MAME;3-METHOXYACRYLIC ACID METHYL ESTER;3-methoxyacrylate;Brivudine Impurity 8;trans-3-methoxyacryL;Ceftibuten intermediate;Methyle3-methoxyacrylate;METHYL 3-METHOXYACRYLATE;3-Methoxy Methyl acrylate
CBNumber: CB8119627
Molecular Formula: C5H8O3
Formula Weight: 116.12
MOL File: 34846-90-7.mol

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Methyl 3-methoxyacrylate Property

Melting point:: 3-4°C
Boiling point:: 56 °C18 mm Hg(lit.)
Density: 1.08 g/mL at 25 °C(lit.)
refractive index: n20/D 1.451(lit.)
Flash point:: 145 °F
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
Water Solubility: Soluble in water
form: Liquid
color: Clear colorless
InChI: InChI=1S/C5H8O3/c1-7-4-3-5(6)8-2/h3-4H,1-2H3
InChIKey: AUTCCPQKLPMHDN-UHFFFAOYSA-N
SMILES: C(OC)(=O)C=COC
CAS DataBase Reference: 34846-90-7(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 43-36/37/38
Safety Statements: 24-37-37/39-26
RIDADR: 3334
WGK Germany: 1
HS Code: 29189900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H227Combustible liquid

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical

Product number: M0995
Product name: Methyl 3-Methoxyacrylate
Purity: >95.0%(GC)
Packaging: 25mL
Price: $27
Updated: 2025/07/31

TCI Chemical

Product number: M0995
Product name: Methyl 3-Methoxyacrylate
Purity: >95.0%(GC)
Packaging: 500mL
Price: $205
Updated: 2025/07/31

TRC

Product number: M338608
Product name: Methyl 3-Methoxyacrylate
Packaging: 250mg
Price: $45
Updated: 2021/12/16

Ark Pharm

Product number: P000331649
Product name: Methyl 3-methoxyacrylate
Purity: 98%
Packaging: 10g
Price: $9
Updated: 2021/12/16

Ark Pharm

Product number: P000331649
Product name: Methyl 3-methoxyacrylate
Purity: 98%
Packaging: 500g
Price: $177
Updated: 2021/12/16

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Methyl 3-methoxyacrylate Chemical Properties,Usage,Production

Chemical Properties

CLEAR COLOURLESS LIQUID

Uses

Methyl trans-3-methoxyacrylate is a natural β-?methoxyacrylate which inhibits mitochondrial respiration and exhibits fungicidal activity.

Synthesis Reference(s)

The Journal of Organic Chemistry, 45, p. 48, 1980 DOI: 10.1021/jo01289a012
Tetrahedron Letters, 24, p. 5209, 1983 DOI: 10.1016/S0040-4039(00)88398-7

Synthesis

7424-91-1

34846-90-7

The composition of the raw materials of this embodiment: 560 g of methyl acrylate, 716 g of methanol, 2.24 g of cobalt oxide, 8.96 g of indium oxide, and 17.6 g of concentrated sulfuric acid; method of preparation: methyl acrylate, methanol, and a synthesis catalyst (cobalt oxide and indium oxide) were added into a reactor, and the temperature of the reaction solution was maintained at 50 °C with sufficient stirring. Nitrogen and oxygen were charged into the reactor, and the partial pressure of nitrogen and oxygen was controlled to be 0.4 MPa to start the reaction. The reaction lasted for 16 hours. The reaction was judged to be complete when the content of methyl acrylate in the reaction solution decreased to 3%, followed by the addition of etherified reaction product. The catalyst was recovered by filtration, and petroleum ether was added to the filtrate, which was homogeneously stirred and left to stratify. The upper layer was petroleum ether layer, and the petroleum ether was recovered by distillation at atmospheric pressure to obtain the intermediate 3,3-dimethoxypropanoic acid methyl ester 703 g. Methanol and methyl acrylate were recovered from the lower aqueous phase. Methyl 3,3-dimethoxypropionate was transferred to a cracking kettle and 17.6 g of concentrated sulfuric acid was slowly added and the temperature was raised to 190 °C for 20 h of cracking reaction. All the cracking products were collected to obtain 430 g of crude methyl 3-methoxyacrylate (MAME). The crude MAME was placed in a distillation vessel and the product was purified by vacuum distillation, resulting in 478 g of the target product, methyl 3-methoxyacrylate. In this embodiment, the yield based on methyl acrylate was 82.4% and the purity of the product was 95.8%.

References

[1] Patent: WO2009/56293, 2009, A1. Location in patent: Page/Page column 8-9
[2] Patent: CN105418421, 2016, A. Location in patent: Paragraph 0020; 0023
[3] Patent: WO2009/56293, 2009, A1. Location in patent: Page/Page column 8
[4] Patent: WO2009/56293, 2009, A1. Location in patent: Page/Page column 8
[5] Patent: WO2009/56293, 2009, A1. Location in patent: Page/Page column 8

Methyl 3-methoxyacrylate Preparation Products And Raw materials

Raw materials

Preparation Products

1-ISOPROPYL-5-HYDROXYPYRAZOL 1-TERT.BUTYL-5-HYDROXYPYRAZOL

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View Lastest Price from Methyl 3-methoxyacrylate manufacturers

Hebei Chuanghai Biotechnology Co., Ltd

Product: Methyl 3-methoxyacrylate 34846-90-7
Price: US $9.90/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 5tons
Release date: 2024-11-29

Chongqing Soarwin Technology Co., Ltd

Product: Methyl 3-methoxyacrylate 34846-90-7
Price: US $0.00-0.00/Kg
Min. Order: 1Kg
Purity: 99.99%
Supply Ability: 20 tons
Release date: 2025-04-15

Hebei Yanxi Chemical Co., Ltd.

Product: Methyl 3-methoxyacrylate 34846-90-7
Price: US $0.00/KG
Min. Order: 200KG
Purity: 98%
Supply Ability: 100MT/Month
Release date: 2024-04-08

34846-90-7, Methyl 3-methoxyacrylateRelated Search:

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34846-90-7

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C2 to C5

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