2-(2-Bromophenyl)-2-propanol
- Product Name
- 2-(2-Bromophenyl)-2-propanol
- CAS No.
- 7073-69-0
- Chemical Name
- 2-(2-Bromophenyl)-2-propanol
- Synonyms
- EOS-61013;2-(2-Bromophenyl)-2-propanol;2-(2-Bromophenyl)propan-2-ol 95+%;1-(2-bromophenyl)-1-methylethanol;Benzenemethanol,2-bromo-a,a-dimethyl-;Benzenemethanol, 2-bromo-α,α-dimethyl-
- CBNumber
- CB81240117
- Molecular Formula
- C9H11BrO
- Formula Weight
- 215.09
- MOL File
- 7073-69-0.mol
2-(2-Bromophenyl)-2-propanol Property
- Boiling point:
- 128-130 °C
- Density
- 1.403±0.06 g/cm3(Predicted)
- storage temp.
- 2-8°C
- pka
- 14.08±0.29(Predicted)
- form
- liquid
- color
- Yellow
- InChI
- InChI=1S/C9H11BrO/c1-9(2,11)7-5-3-4-6-8(7)10/h3-6,11H,1-2H3
- InChIKey
- TXQKNSQVEWHJAQ-UHFFFAOYSA-N
- SMILES
- C(C1C=CC=CC=1Br)(O)(C)C
Safety
- HS Code
- 2905599890
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H227Combustible liquid
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P363Wash contaminated clothing before reuse.
P370+P378In case of fire: Use … for extinction.
P403+P235Store in a well-ventilated place. Keep cool.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- B678435
- Product name
- 2-(2-Bromophenyl)propan-2-ol
- Packaging
- 50mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- 036136
- Product name
- 2-(2-Bromophenyl)propan-2-ol
- Purity
- 95%
- Packaging
- 5g
- Price
- $160
- Updated
- 2021/12/16
- Product number
- 2602-9-07
- Product name
- 2-(2-Bromophenyl)propan-2-ol
- Purity
- 95.0%
- Packaging
- 5G
- Price
- $376
- Updated
- 2021/12/16
- Product number
- HCH0125432
- Product name
- 2-(2-BROMOPHENYL)-2-PROPANOL
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $504.46
- Updated
- 2021/12/16
- Product number
- 2602-9-07
- Product name
- 2-(2-Bromophenyl)propan-2-ol
- Purity
- 95.0%
- Packaging
- 10g
- Price
- $680
- Updated
- 2021/12/16
2-(2-Bromophenyl)-2-propanol Chemical Properties,Usage,Production
Synthesis
917-64-6
6091-64-1
7073-69-0
To a solution of 26.50 g (0.14 mol) of ethyl 2-bromobenzoate (4a) dissolved in 35 mL of anhydrous diethyl ether at -5°C was slowly added methylmagnesium iodide Grignard's reagent prepared from 9.1 g (0.37 mol) of magnesium and 53.3 g (0.37 mol) of freshly distilled methyl iodide in 85 mL of anhydrous ether. Upon completion of the reaction, the reaction was quenched by the addition of 38% ammonium chloride solution (58 mL). The ether layer was separated by decantation and the remaining pasty precipitate was extracted with ether (3 x 35 mL). All ether layer extracts were combined and dried over anhydrous sodium sulfate, followed by evaporation of the solvent. The product 2-(2-bromophenyl)-2-propanol 19.40 g was obtained in 82% yield and 95% purity (GLC assay). Physical properties of the product: boiling point 99-100 °C (5 mmHg), d420=1.1576, nD20=1.5420; MRD measured value 46.43, calculated value 46.55. Comparison of literature data: melting point 23.7 °C, boiling point 79.2 °C (2.2 mmHg), nD20=1.5416. IR spectra characteristic absorption peaks (ν, cm-1) : 3460, 1175 (OH), 1370, 1385 [C(CH3)2], 690 (C-Cl).1H NMR spectral data (δ, ppm): 1.64s (6H, CH3), 2.46s (1H, OH), 6.9-7.7m (4H, Harom). Elemental analysis measured values (%): C 63.00, H 6.42, Cl 20.71; calculated values (%) for molecular formula C9H11ClO: C 63.35, H 6.50, Cl 20.78.
References
[1] Organic Letters, 2013, vol. 15, # 20, p. 5326 - 5329
[2] Russian Journal of Organic Chemistry, 2016, vol. 52, # 6, p. 806 - 812
[3] Zh. Org. Khim., 2016, vol. 52, # 6, p. 806 - 812,7
[4] Transactions of the Faraday Society, 1936, vol. 32, p. 1327,1328 Anm.
2-(2-Bromophenyl)-2-propanol Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-(2-Bromophenyl)-2-propanol manufacturers
- Product
- 2-(2-Bromophenyl)-2-propanol 7073-69-0
- Price
- US $0.00/KG
- Min. Order
- 25KG
- Purity
- 98%min
- Supply Ability
- 30tons/month
- Release date
- 2023-01-29
- Product
- 2-(2-Bromophenyl)propan-2-ol 7073-69-0
- Price
- US $0.00-0.00/KG
- Min. Order
- 1g
- Purity
- 98%min
- Supply Ability
- 100kgs/month
- Release date
- 2021-11-21
- Product
- 2-(2-Bromophenyl)-2-propanol 7073-69-0
- Price
- US $1.00/g
- Min. Order
- 1g
- Purity
- 99%
- Supply Ability
- g/kg/T
- Release date
- 2019-12-18