ChemicalBook > CAS DataBase List > 2-Pyridinemethanol,5-chloro-(9CI)

2-Pyridinemethanol,5-chloro-(9CI)

Product Name
2-Pyridinemethanol,5-chloro-(9CI)
CAS No.
209526-98-7
Chemical Name
2-Pyridinemethanol,5-chloro-(9CI)
Synonyms
(5-CHLOROPYRIDIN-2-YL)METHANOL;5-chloro-2-PyridineMethanol;(5-Chloro-2-pyridyl)methanol;2-Pyridinemethanol, 5-chloro-;2-Pyridinemethanol,5-chloro-(9CI);5-Chloro-2-(hydroxymethyl)pyridine;(5-Chloropyridin-2-yl)methanol, 5-Chloropicolinyl alcohol
CBNumber
CB81275106
Molecular Formula
C6H6ClNO
Formula Weight
143.57
MOL File
209526-98-7.mol
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2-Pyridinemethanol,5-chloro-(9CI) Property

Melting point:
45～47℃
Boiling point:
234.9±25.0 °C(Predicted)
Density 
1.324±0.06 g/cm3(Predicted)
storage temp. 
2-8°C
form 
solid
pka
13.12±0.10(Predicted)
color 
Grey
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Safety

HazardClass 
IRRITANT
HS Code 
2933399990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

TRC
Product number
B405160
Product name
(5-Chloropyridin-2-yl)methanol
Packaging
50mg
Price
$45
Updated
2021/12/16
TRC
Product number
B405160
Product name
(5-Chloropyridin-2-yl)methanol
Packaging
500mg
Price
$200
Updated
2021/12/16
SynQuest Laboratories
Product number
4H01-5-X2
Product name
5-Chloro-2-(hydroxymethyl)pyridine
Packaging
250mg
Price
$32
Updated
2021/12/16
Matrix Scientific
Product number
046962
Product name
(5-Chloro-2-pyridinyl)methanol
Purity
>95%
Packaging
500mg
Price
$45
Updated
2021/12/16
Matrix Scientific
Product number
046962
Product name
(5-Chloro-2-pyridinyl)methanol
Purity
>95%
Packaging
1g
Price
$69
Updated
2021/12/16
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2-Pyridinemethanol,5-chloro-(9CI) Chemical Properties,Usage,Production

Synthesis

132308-19-1

209526-98-7

General procedure for the synthesis of (5-chloro-2-pyridyl)methanol from methyl 5-chloropyridine-2-carboxylate: 1. Synthesis of intermediate 2: (5-chloro-2-pyridyl)methanol - Methyl 5-chloro-2-pyridinecarboxylate (43 g, 251 mmol) was dissolved in methanol (400 mL) at 0 °C. - NaBH4 (28.7 g, 754 mmol) was added to the above solution in small portions over about 30 min. - After addition, the reaction mixture was stirred at room temperature for 2 h. The completion of the reaction was confirmed by TLC analysis. - After completion of the reaction, the mixture was concentrated under reduced pressure and the residue was adjusted to pH 1 with 1N HCl. - The resulting solution was extracted with EtOAc (3 x 300 mL) and the organic layers were combined. - The organic layer was dried with Na2SO4 and the solvent was evaporated. - The residue was purified by silica gel column chromatography using 10:1 petroleum ether/EtOAc as eluent to afford the title compound (5-chloro-2-pyridyl)methanol (36 g, 99%). Product Characterization: 1H NMR (1H NMR). - Product characterization: 1H NMR (400 MHz, CDCl3) δ ppm 8.44 (d, J = 1.60 Hz, 1H), 7.62 (dd, J = 8.40, 2.40 Hz, 1H), 7.25 (d, J = 8.40 Hz, 1H), 4.69 (s, 2H), 3.83 (s, 1H).

References

[1] Patent: WO2009/76387, 2009, A1. Location in patent: Page/Page column 27
[2] Patent: WO2010/141538, 2010, A1. Location in patent: Page/Page column 18-19
[3] Patent: WO2010/141539, 2010, A1. Location in patent: Page/Page column 18-19
[4] Patent: WO2010/141545, 2010, A1. Location in patent: Page/Page column 19-20
[5] Patent: WO2010/141540, 2010, A1. Location in patent: Page/Page column 17-18

2-Pyridinemethanol,5-chloro-(9CI) Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Pyridinemethanol,5-chloro-(9CI) Suppliers

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View Lastest Price from 2-Pyridinemethanol,5-chloro-(9CI) manufacturers

Career Henan Chemical Co
Product
2-Pyridinemethanol,5-chloro-(9CI) 209526-98-7
Price
US $1.00/KG
Min. Order
1KG
Purity
97%-99.9%
Supply Ability
100kg
Release date
2019-12-20

209526-98-7, 2-Pyridinemethanol,5-chloro-(9CI)Related Search:

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  • 2-Pyridinemethanol,5-chloro-(9CI)
  • (5-CHLOROPYRIDIN-2-YL)METHANOL
  • 5-Chloro-2-(hydroxymethyl)pyridine
  • 5-chloro-2-PyridineMethanol
  • (5-Chloropyridin-2-yl)methanol, 5-Chloropicolinyl alcohol
  • (5-Chloro-2-pyridyl)methanol
  • 2-Pyridinemethanol, 5-chloro-
  • 209526-98-7
  • PYRIDINE