ChemicalBook > CAS DataBase List > 4-(6-Acryloyloxyhexyloxy)-benzoesure (4-cyanophenylester)

4-(6-Acryloyloxyhexyloxy)-benzoesure (4-cyanophenylester)

Product Name
4-(6-Acryloyloxyhexyloxy)-benzoesure (4-cyanophenylester)
CAS No.
83847-14-7
Chemical Name
4-(6-Acryloyloxyhexyloxy)-benzoesure (4-cyanophenylester)
Synonyms
RM23;VE6OPEPN;4-Cyanophenol 4-(6-acryloyloxyhexyloxy)benzoate;4-Cyanophenyl 4'-(6-acryloyloxyhexyloxy)benzoate;6-[4-(4-Cyanophenoxycarbonyl)phenoxy]hexyl acrylate;(4-cyanophenyl) 4-(6-prop-2-enoyloxyhexoxy)benzoate;4[4[6-Acryloxyhex-1-yl)oxyphenyl]carboxy-benzonitrile;4-Cyanophenyl 4-[[6-[(1-oxo-allyloxy)]hexyl]oxy]benzoate;4-(6-Acryloyloxyhexyloxy)-benzoesure (4-cyanophenylester);4-(6-acryloyloxyhexyloxy)-benzoic acid (4-cyanophenyl ester)
CBNumber
CB81448429
Molecular Formula
C23H23NO5
Formula Weight
393.43
MOL File
83847-14-7.mol
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4-(6-Acryloyloxyhexyloxy)-benzoesure (4-cyanophenylester) Property

Boiling point:
563.1±45.0 °C(Predicted)
Density 
1.19
vapor pressure 
0-0Pa at 25-50℃
storage temp. 
2-8°C, stored under nitrogen
form 
Solid:crystalline
Appearance
White to off-white Solid
InChI
InChI=1S/C23H23NO5/c1-2-22(25)28-16-6-4-3-5-15-27-20-13-9-19(10-14-20)23(26)29-21-11-7-18(17-24)8-12-21/h2,7-14H,1,3-6,15-16H2
InChIKey
LNEDNZUQKOGNLJ-UHFFFAOYSA-N
SMILES
C(OC1=CC=C(C#N)C=C1)(=O)C1=CC=C(OCCCCCCOC(=O)C=C)C=C1
LogP
4.5 at 40℃ and pH7
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Ambeed
Product number
A1442086
Product name
4-Cyanophenyl4-((6-(acryloyloxy)hexyl)oxy)benzoate
Purity
97%
Packaging
5g
Price
$41
Updated
2021/12/16
aablocks
Product number
AA00G3VU
Product name
4''-((6-(Acryloyloxy)hexyl)oxy)-4-cyano-[1,1''-biphenyl]-3-carboxylicacid
Purity
97%
Packaging
5g
Price
$86
Updated
2021/12/16
Ambeed
Product number
A1442086
Product name
4-Cyanophenyl4-((6-(acryloyloxy)hexyl)oxy)benzoate
Purity
97%
Packaging
25g
Price
$137
Updated
2021/12/16
aablocks
Product number
AA00G3VU
Product name
4''-((6-(Acryloyloxy)hexyl)oxy)-4-cyano-[1,1''-biphenyl]-3-carboxylicacid
Purity
97%
Packaging
25g
Price
$194
Updated
2021/12/16
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4-(6-Acryloyloxyhexyloxy)-benzoesure (4-cyanophenylester) Chemical Properties,Usage,Production

Uses

4-(6-Acryloyloxyhexyloxy)-benzoesure (4-cyanophenylester) can be used as an intermediate in organic synthesis, mainly used in laboratory research and development and in the process of chemical and pharmaceutical synthesis.

Synthesis


The target monomer was prepared by firstly converting the acid into the corresponding acid chloride, then condensing this withp-cyanophenol. The acid (17.32 g, 0.059 mol) was stirred with thionyl chloride (35.7 g, 0.3 mol) in the presence of DMF (2 drops) and 2,6-di-tert-butyl-4-methyl phenol (4.4 g, 0.02 mol). After ca. 25 min, by which time solution was achieved, the excess thionyl chloride was removed by rotary evaporation and high vacuum (1-2 h). The acid chloride residue was dis- solved in anhydrous chloroform (30 mL), then added slowly dropwise into a stirred solution of p-cyanophenol (7.03 g, 0.059 mol) and triethylamine (6.07 g, 0.06 mol) in chloroform (20 mL) at 0??C. After the addition the mixture was stirred at room temperature for 24 h and then chloroform (200 mL) added. This solution was washed with water (50 mL) followed by 2 N sodium hydroxide solution (3 x 50 mL) and water (2 x 50 mL). The organic layer was dried (MgSO,), evaporated, then subjected to flash chromatography, using dichloro- methane as both the solvent and the eluant. The monomer was finally recrystallized from isopropanol and shown to be pure by tlc. Yield: 16 g, 69%.

4-(6-Acryloyloxyhexyloxy)-benzoesure (4-cyanophenylester) Preparation Products And Raw materials

Raw materials

Preparation Products

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4-(6-Acryloyloxyhexyloxy)-benzoesure (4-cyanophenylester) Suppliers

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View Lastest Price from 4-(6-Acryloyloxyhexyloxy)-benzoesure (4-cyanophenylester) manufacturers

Shanghai Daken Advanced Materials Co.,Ltd
Product
4-cyanophenyl 4-((6-(acryloyloxy)hexyl)oxy)benzoate 83847-14-7
Price
US $0.00/KG
Min. Order
1KG
Purity
98.00%
Supply Ability
1000KG/month
Release date
2021-11-02
Shaanxi Dideu New Materials Co. Ltd
Product
4-(6-Acryloyloxyhexyloxy)-benzoesure (4-cyanophenylester) 83847-14-7
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10000KGS
Release date
2025-02-28
Kindchem(Nanjing)Co.,Ltd
Product
4-(6-Acryloyloxyhexyloxy)-benzoesure (4-cyanophenylester) 83847-14-7
Price
US $0.00-0.00/g
Min. Order
10g
Purity
0.95
Supply Ability
50kg
Release date
2023-08-02

83847-14-7, 4-(6-Acryloyloxyhexyloxy)-benzoesure (4-cyanophenylester)Related Search:


  • 4-(6-Acryloyloxyhexyloxy)-benzoesure (4-cyanophenylester)
  • 4-Cyanophenol 4-(6-acryloyloxyhexyloxy)benzoate
  • 4-Cyanophenyl 4'-(6-acryloyloxyhexyloxy)benzoate
  • Benzoic acid, 4-[[6-[(1-oxo-2-propenyl)oxy]hexyl]oxy]-, 4-cyanophenylester
  • (4-cyanophenyl) 4-(6-prop-2-enoyloxyhexoxy)benzoate
  • RM23
  • 6-[4-(4-Cyanophenoxycarbonyl)phenoxy]hexyl acrylate
  • Benzoic acid, 4-[[6-[(1-oxo-2-propen-1-yl)oxy]hexyl]oxy]-, 4-cyanophenyl ester
  • VE6OPEPN
  • 4[4[6-Acryloxyhex-1-yl)oxyphenyl]carboxy-benzonitrile
  • 4-Cyanophenyl 4-[[6-[(1-oxo-2-propen-1-yl)oxy]hexyl]oxy]benzoate
  • 4-(6-acryloyloxyhexyloxy)-benzoic acid (4-cyanophenyl ester)
  • 4-Cyanophenyl 4-[[6-[(1-oxo-allyloxy)]hexyl]oxy]benzoate
  • 83847-14-7
  • 83847-18-7