4-Benzyloxybenzylamine
- Product Name
- 4-Benzyloxybenzylamine
- CAS No.
- 22171-15-9
- Chemical Name
- 4-Benzyloxybenzylamine
- Synonyms
- [4-(Benzyloxy)phenyl]methylamine;(4-(Benzyloxy)phenyl)methanamine;(4-phenylmethoxyphenyl)methanamine;Benzenemethanamine, 4-(phenylmethoxy)-;(4-phenylmethoxyphenyl)methylammonium chloride
- CBNumber
- CB81462256
- Molecular Formula
- C14H15NO
- Formula Weight
- 213.27
- MOL File
- 22171-15-9.mol
4-Benzyloxybenzylamine Property
- storage temp.
- 2-8°C, protect from light
- Appearance
- White to off-white Solid
Safety
- RIDADR
- UN3259
- HazardClass
- 8
- HS Code
- 2922390090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P337+P313IF eye irritation persists: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- B411098
- Product name
- [4-(Benzyloxy)benzyl]amine
- Packaging
- 100mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- FB66172
- Product name
- 4-Benzyloxybenzylamine
- Packaging
- 2g
- Price
- $72
- Updated
- 2021/12/16
- Product number
- 033932
- Product name
- 4-Benzyloxybenzylamine
- Purity
- 98%
- Packaging
- 250mg
- Price
- $19
- Updated
- 2021/12/16
- Product number
- 033932
- Product name
- 4-Benzyloxybenzylamine
- Purity
- 98%
- Packaging
- 5g
- Price
- $142
- Updated
- 2021/12/16
- Product number
- FB66172
- Product name
- 4-Benzyloxybenzylamine
- Packaging
- 10g
- Price
- $220
- Updated
- 2021/12/16
4-Benzyloxybenzylamine Chemical Properties,Usage,Production
Synthesis
154128-83-3
22171-15-9
Preparative Example 1. Synthesis of 4-benzyloxybenzylamine: Potassium phthalimide (20 g, 0.108 mol) was added to a solution of 4-benzyloxybenzyl chloride (25 g, 0.107 mol) in N,N-dimethylformamide (75 mL), and the reaction was stirred for 3 hours. After completion of the reaction, the reaction solution was cooled to room temperature and extracted with ethyl acetate and water by partition. The organic layer was washed with water and dried over anhydrous magnesium sulfate. The solvent was evaporated under reduced pressure to give 2-(4-benzyloxybenzyl)-isoindole-1,3-dione (37 g, quantitative yield) as a light brown solid. Subsequently, 2-(4-benzyloxybenzyl)-isoindole-1,3-dione (37 g, 0.107 mol) was dissolved in ethanol (1 L), hydrazine monohydrate (8.04 g, 0.161 mol) was added, and stirred at reflux for 8 hours. After completion of the reaction, it was cooled to room temperature, water was added and ethanol was removed by vacuum evaporation. The residue was extracted with ethyl acetate and water by partitioning, and the organic layer was washed sequentially with water, 2N aqueous sodium hydroxide solution and water, and dried with anhydrous magnesium sulfate. The solvent was removed by distillation under reduced pressure and the residue was purified by NH silica gel column chromatography (eluent: hexane/ethyl acetate=2:1, using Fuji Silysia NH silica gel) to afford the title compound 4-benzyloxybenzylamine (15 g, 64% yield) as a white solid.
References
[1] Patent: EP1782811, 2007, A1. Location in patent: Page/Page column 67
[2] Patent: EP1669348, 2006, A1. Location in patent: Page/Page column 76
4-Benzyloxybenzylamine Preparation Products And Raw materials
Raw materials
Preparation Products
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