((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE

ChemicalBook > CAS DataBase List > ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE

((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE

Reaction

Product Name: ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE
CAS No.: 192139-92-7
Chemical Name: ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE
Synonyms: RuCL;TsDPEN;RuCl[(R,R)-Tsdpen](p-cymene);RuCl(p-cymene)[(R,R)-Ts-DPEN];Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II);(R,R)-N-;R)-2-AMINO-1;[(R,R)-Tsdpen](p-cymene);RuCl (cymene)[(R,R)-TsDPEN];CHLORO{[(1R,2R)-(-)-2AMINO-1,2DIPHENY
CBNumber: CB81564668
Molecular Formula: C21H21ClN2O2RuS.C10H14
Formula Weight: 636.219
MOL File: 192139-92-7.mol

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((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Property

Melting point:: 215 °C
storage temp.: 2-8°C
solubility: Deuterated Chloroform, DMF
form: solid
color: yellow to dark brown
optical activity: [α]20/D 116°, c = 0.1 in chloroform
Sensitive: air sensitive
InChIKey: AZFNGPAYDKGCRB-MNPNNRAMNA-M
SMILES: C1=C(S(=O)(=O)N([C@H](C2=CC=CC=C2)[C@H](N)C2=CC=CC=C2)[Ru]Cl)C=CC(C)=C1.C1=CC(C)=CC=C1C(C)C |&1:6,13,r|

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Safety

WGK Germany: 3
HS Code: 28439000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 930008
Product name: RuCl(p-cymene)[(R,R)-Ts-DPEN]
Packaging: 250MG
Price: $67.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: 930008
Product name: RuCl(p-cymene)[(R,R)-Ts-DPEN]
Packaging: 1G
Price: $172
Updated: 2024/03/01

Sigma-Aldrich

Product number: 703907
Product name: RuCl(p-cymene)[(R,R)-Ts-DPEN]
Packaging: 100mg
Price: $28.2
Updated: 2024/03/01

Sigma-Aldrich

Product number: 703907
Product name: RuCl(p-cymene)[(R,R)-Ts-DPEN]
Packaging: 500mg
Price: $102
Updated: 2024/03/01

TCI Chemical

Product number: R0125
Product name: RuCl[(R,R)-Tsdpen](p-cymene)
Purity: >90%(HPLC)
Packaging: 200mg
Price: $49
Updated: 2024/03/01

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((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Chemical Properties,Usage,Production

Reaction

This catalyst has shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydoxy, siloxy, carbonyl, ester, amide or thioester.

Chemical Properties

Orange to brown powder

Uses

Phosphine cationic ruthenium catalysts used for enantioselective hydrogenation of:

Quinolines
N-Alkyl ketimines
Antitumor and antiproliferative derivatives of natural products isolated from bacteria
Hydroxy arylaldehydes via Rap-Stoermer-enantioselective transfer hydrogenation

Catalyst with improved performance modified via microenvironment engineering of nanocages

General Description

RuCl(p-cymene)[(R,R)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium.

((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE manufacturers

Hangzhou ICH Biofarm Co., Ltd

Product: RuCl[(R,R)-Tsdpen](p-cymene) 192139-92-7
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 99.0%min
Supply Ability: 800kg
Release date: 2023-06-09

Hangzhou ICH Biofarm Co., Ltd

Product: ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE 192139-92-7
Price: US $0.00/kg
Min. Order: 1kg
Purity: 98.00%
Supply Ability: 200kg
Release date: 2023-06-28

Career Henan Chemical Co

Product: ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE 192139-92-7
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 5kg
Release date: 2019-07-03

192139-92-7, ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDERelated Search:

Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl[(S,S)-FsDPEN](p-cymene) Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(S,S)-Tsdpen](mesitylene) tBuXPhos Pd G1 (S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II) (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE (R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE (1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II)

((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE

RuCl(p-cymene)[(R,R)-Ts-DPEN]

Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)

Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95% RuCl[(R,R)-Tsdpen](p-cymene)

Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95%

(1R,2R)-2-amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide

Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-<br />cymene)ruthenium(II), min. 95% RuCl[(R,R)-Tsdpen](p-cymene)

Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),95% RuCl[(R,R)-Tsdpen](p-cyMene)

((R,R)-2-aMino-1,2-diphenylethyl0[(4-tolyl)sulfonyl]aMino](p-cyMene)RutheniuM(II)chloride

Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II), Min. 95% C31H35ClN2O2RuS

Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),RuCl[(R,R)-Tsdpen](p-cyMene)

RutheniuM,[N-[(1R,2R)-2-(aMino-kN)-1,2-diphenylethyl]-4-MethylbenzenesulfonaMidato-kN]chloro[(1,2,3,4,5,6-h)-1-Methyl-4-(1-Methylethyl)benzene]-

[((R,R)-2-AMino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]aMido](chloro)(η6-p-cyMene)rutheniuM

TsDPEN

(R,R)-N-

RuCl[(R,R)-Tsdpen](p-cymene)

((R,r)-2-amino-1,2-diphenylethy)[(4-tolyl)sulfonyl]amido](pcymene)ruthenium(II)chloride

[N-[(1R,2R)-2-(Amino-KN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-KN]chloro[(1,2,3,4,5,6-η:)-1-methyl-

[RuCl(η6-p-cymene)(N-tosyl-1,2-diphenylethylenediamine)]

RuCl(p-cymene)[(R,R)-Ts-DPEN] Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)

Ruthenium,[N-[(1R,2R)-2-(amino-kN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-kN]chloro[(1,2,3,4,5,6-h)-1-methyl-4-(1-methylethyl)benzene]-,98%

[(R,R)-Tsdpen](p-cymene)

RuCL

Ruthenium, [N-[(1R,2R)-2-(amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-

[(R,R)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide]chloro(p-cymene)ruthenium(II)

Chloro(p-cymene)[(R,R)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II)

((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE ISO 9001：2015 REACH

RuCl (cymene)[(R,R)-TsDPEN]

2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE

R)-2-AMINO-1

((R,R)-2-amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](p...

[(1R,2R)-2-amino-1,2-diphenyl-ethyl]-(p-tolylsulfonyl)azanide

(R,R)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro

[((R,R)-2-Amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](chloro)( p -cymene)ruthenium(II)

[(1R,2R)-2-amiNA-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide

RuCl[(R,R)-Tsdpen](p-cymene)/Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)

CHLORO{[(1R,2R)-(-)-2AMINO-1,2DIPHENY

192139-92-7

C31H35ClN2O2RuS

organometallic complex