ChemicalBook > CAS DataBase List > PHENYLTHIOTRIMETHYLSILANE

PHENYLTHIOTRIMETHYLSILANE

Product Name
PHENYLTHIOTRIMETHYLSILANE
CAS No.
4551-15-9
Chemical Name
PHENYLTHIOTRIMETHYLSILANE
Synonyms
Trimethylsilylthiobenzene;PHENYLTHIOTRIMETHYLSILANE;TRIMETHYL(PHENYLTHIO)SILANE;S-(TRIMETHYLSILYL)THIOPHENOL;Phenylthiotrimethylsilane,95%;PHENYL TRIMETHYLSILYL SULFIDE;S-(TRIMETHYLSILYL)BENZENETHIOL;(Phenylthio)trimethylsilane>Trimethyl(phenylthio)silane 97%;Benzene, [(trimethylsilyl)thio]-
CBNumber
CB8179771
Molecular Formula
C9H14SSi
Formula Weight
182.36
MOL File
4551-15-9.mol
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PHENYLTHIOTRIMETHYLSILANE Property

Boiling point:
72 °C/8 mmHg (lit.)
Density 
0.963 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.532(lit.)
Flash point:
87 °F
storage temp. 
Flammables area
solubility 
sol organic solvents; incompatible with strong acids and strong oxidizing agents.
form 
clear liquid
color 
Colorless to Light yellow
Specific Gravity
0.963
Water Solubility 
Hydrolyzes in water.
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
Sensitive 
Moisture Sensitive
BRN 
1905944
CAS DataBase Reference
4551-15-9(CAS DataBase Reference)
EPA Substance Registry System
Silane, trimethyl(phenylthio)- (4551-15-9)
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Safety

Hazard Codes 
Xn
Risk Statements 
10-20-38
Safety Statements 
23-28
RIDADR 
UN 1993 3/PG 3
WGK Germany 
3
3-10-13-21
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H332Harmful if inhaled

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
226467
Product name
Trimethyl(phenylthio)silane
Purity
97%
Packaging
5g
Price
$112
Updated
2024/03/01
TCI Chemical
Product number
P1378
Product name
(Phenylthio)trimethylsilane
Purity
>95.0%(GC)
Packaging
5g
Price
$88
Updated
2024/03/01
TCI Chemical
Product number
P1378
Product name
(Phenylthio)trimethylsilane
Purity
>95.0%(GC)
Packaging
25g
Price
$347
Updated
2024/03/01
TRC
Product number
P399523
Product name
Phenylthiotrimethylsilane
Packaging
50mg
Price
$45
Updated
2021/12/16
TRC
Product number
P399523
Product name
Phenylthiotrimethylsilane
Packaging
500mg
Price
$75
Updated
2021/12/16
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PHENYLTHIOTRIMETHYLSILANE Chemical Properties,Usage,Production

Chemical Properties

clear colorless to light yellow liquid

Physical properties

bp 93–99 °C/12 mmHg; d 0.967 g cm?3.

Uses

(Phenylthio)trimethylsilane can be used in selective carbonyl protection; preparation of thioesters and cleavage of ethers.

Purification Methods

Phenylthio trimethylsilane (trimethyl phenylthio silane) [4551-15-9] M 182.4, b 95 -9 9o/12mm, d 4 0.97. Purification is as for phenyl trimethyl silylmethyl sulfide.

PHENYLTHIOTRIMETHYLSILANE Preparation Products And Raw materials

Raw materials

Preparation Products

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4551-15-9, PHENYLTHIOTRIMETHYLSILANERelated Search:


  • S-(TRIMETHYLSILYL)BENZENETHIOL
  • S-(TRIMETHYLSILYL)THIOPHENOL
  • PHENYLTHIOTRIMETHYLSILANE
  • PHENYL TRIMETHYLSILYL SULFIDE
  • TRIMETHYL(PHENYLTHIO)SILANE
  • Phenylthiotrimethylsilane(S-Trimethylsilylthiophenol)
  • (Phenylthio)trimethylsilane, Phenyl trimethylsilyl sulfide, S-(Trimethylsilyl)thiophenol
  • Trimethylsilylthiobenzene
  • Phenylthiotrimethylsilane,95%
  • Phenyl Trimethylsilyl Sulfide Trimethyl(phenylthio)silane S-(Trimethylsilyl)benzenethiol
  • Trimethyl(phenylthio)silane 97%
  • (Phenylthio)trimethylsilane&gt
  • Benzene, [(trimethylsilyl)thio]-
  • 4551-15-9
  • C6H5SSiCH33
  • C9H14SSi
  • Building Blocks
  • Sulfur Compounds
  • Organic Building Blocks
  • Protected Thiols/Mercaptans
  • Protection & Derivatization Reagents (for Synthesis)
  • Monoalkoxysilanes
  • Si-O Compounds
  • Si (Classes of Silicon Compounds)
  • Monoalkoxysilanes
  • Protection & Derivatization Reagents (for Synthesis)
  • Si (Classes of Silicon Compounds)
  • Si-O Compounds
  • Synthetic Organic Chemistry